Fluorous miniemulsions: A powerful tool to control morphology in metallocene-catalyzed propene polymerization
The nonaqueous miniemulsion polymerization of liquid propene using highly water sensitive metallocene catalysts is presented. In the emulsion perfluoromethylcyclohexane is applied as continuous phase in which the monomer is polymerized to high molecular weights. The droplets are stabilized by specia...
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| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2009-03, Vol.47 (6), p.1724-1730 |
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| container_end_page | 1730 |
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| container_issue | 6 |
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| container_title | Journal of polymer science. Part A, Polymer chemistry |
| container_volume | 47 |
| creator | Nenov, Svetlin Hoffmann, Michael S Steffen, Werner Klapper, Markus Müllen, Klaus |
| description | The nonaqueous miniemulsion polymerization of liquid propene using highly water sensitive metallocene catalysts is presented. In the emulsion perfluoromethylcyclohexane is applied as continuous phase in which the monomer is polymerized to high molecular weights. The droplets are stabilized by specially designed of hydrocarbon/perfluorinated block copolymers. This technique offers the possibility to generate polyolefin nanoparticles with a narrow size distribution and diameters below 100 nm. [Color figure can be viewed in the online issue, which is available at www.interscience.wiley.com.] |
| doi_str_mv | 10.1002/pola.23242 |
| format | Article |
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In the emulsion perfluoromethylcyclohexane is applied as continuous phase in which the monomer is polymerized to high molecular weights. The droplets are stabilized by specially designed of hydrocarbon/perfluorinated block copolymers. This technique offers the possibility to generate polyolefin nanoparticles with a narrow size distribution and diameters below 100 nm. 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[Color figure can be viewed in the online issue, which is available at www.interscience.wiley.com.]</description><subject>Applied sciences</subject><subject>emulsion polymerization</subject><subject>Exact sciences and technology</subject><subject>fluorous emulsifiers</subject><subject>metallocene catalysts</subject><subject>nonaqueous</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>polyolefins</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0887-624X</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp9kE9v1DAQxS0EEkvhwhcgFzggpfi_E26rim4rLVskqMrNctxJMThxsBOV9NPXIaVHLvbI_r03Mw-h1wQfE4zphyF4c0wZ5fQJ2hBc1yUWpHqKNriqVCkp__4cvUjpJ8b5T1Qb1J36KcQwpaJzvYNu8smFPn0stsUQbiG2ky_GEJajsKEfYy67EIcfwYebuXB90cFovA8WeiityfV8B9fFEMOQX7KJnzuI7s6M2fcletYan-DVw32ELk8_fTs5K_cXu_OT7b60jEpa1hVrMTdKWsIEb4UklaAtloBBNkCEVExlRijeNFwCpY0QTc1Mg6ki_LpmR-jd6pvH-D1BGnXnkgXvTQ95V80YUQpXPIPvV9DGkFKEVg_RdSbOmmC9JKqXRPXfRDP89sHVJGt8G01vXXpUUEKk4tXSnazcrfMw_8dRf7nYb_95l6vGpRH-PGpM_KWXbYW-Ouz04ezz_rC7OuiFf7PyrQna3MQ8x-VXignDRNSyUpLdA7xxoAg</recordid><startdate>20090315</startdate><enddate>20090315</enddate><creator>Nenov, Svetlin</creator><creator>Hoffmann, Michael S</creator><creator>Steffen, Werner</creator><creator>Klapper, Markus</creator><creator>Müllen, Klaus</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20090315</creationdate><title>Fluorous miniemulsions: A powerful tool to control morphology in metallocene-catalyzed propene polymerization</title><author>Nenov, Svetlin ; Hoffmann, Michael S ; Steffen, Werner ; Klapper, Markus ; Müllen, Klaus</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3262-983f04a76c1354f561852f06e0e6be156737983574bb46e22b55b93ab02714d93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>emulsion polymerization</topic><topic>Exact sciences and technology</topic><topic>fluorous emulsifiers</topic><topic>metallocene catalysts</topic><topic>nonaqueous</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>polyolefins</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>online_resources</toplevel><creatorcontrib>Nenov, Svetlin</creatorcontrib><creatorcontrib>Hoffmann, Michael S</creatorcontrib><creatorcontrib>Steffen, Werner</creatorcontrib><creatorcontrib>Klapper, Markus</creatorcontrib><creatorcontrib>Müllen, Klaus</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer science. 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| ispartof | Journal of polymer science. Part A, Polymer chemistry, 2009-03, Vol.47 (6), p.1724-1730 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences emulsion polymerization Exact sciences and technology fluorous emulsifiers metallocene catalysts nonaqueous Organic polymers Physicochemistry of polymers Polymerization polyolefins Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Fluorous miniemulsions: A powerful tool to control morphology in metallocene-catalyzed propene polymerization |
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