Molecular relaxation behavior of fatty acid-based vinyl ester resins
The experimental characterization of the time-dependent properties of fatty acid-based vinyl ester resins with reduced styrene content and emissions was conducted and compared with that of various commercial vinyl ester (VE) resins. Constant heating rate and isothermal, multifrequency sweep experime...
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Veröffentlicht in: | Journal of applied polymer science 2008-06, Vol.108 (6), p.3495-3506 |
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creator | Boyd, Steven E La Scala, John J Palmese, Guiseppe R |
description | The experimental characterization of the time-dependent properties of fatty acid-based vinyl ester resins with reduced styrene content and emissions was conducted and compared with that of various commercial vinyl ester (VE) resins. Constant heating rate and isothermal, multifrequency sweep experiments were conducted over a wide temperature range using dynamic mechanical analysis. Storage and loss modulus master-curves were formed using time-temperature superposition (TTSP) and analyzed to quantify the molecular relaxation behavior using accepted techniques and theories. Special attention was focused on determining the effect of reducing styrene weight percent on the derived viscoelastic properties. The fatty acid-based VE resins were found to have similar or slightly inferior thermomechanical properties and a more pronounced viscoelastic response compared with the commercial resins. However, the research definitively demonstrates that the evaluated fatty acid VE resins are a viable replacement to commercial resins in certain applications with concomitant attractive environmental benefits. |
doi_str_mv | 10.1002/app.27957 |
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Constant heating rate and isothermal, multifrequency sweep experiments were conducted over a wide temperature range using dynamic mechanical analysis. Storage and loss modulus master-curves were formed using time-temperature superposition (TTSP) and analyzed to quantify the molecular relaxation behavior using accepted techniques and theories. Special attention was focused on determining the effect of reducing styrene weight percent on the derived viscoelastic properties. The fatty acid-based VE resins were found to have similar or slightly inferior thermomechanical properties and a more pronounced viscoelastic response compared with the commercial resins. However, the research definitively demonstrates that the evaluated fatty acid VE resins are a viable replacement to commercial resins in certain applications with concomitant attractive environmental benefits.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.27957</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Chemical properties ; Exact sciences and technology ; fatty acid vinyl esters ; Polymer industry, paints, wood ; Properties and testing ; relaxation ; styrene replacements/alternatives ; Technology of polymers ; thermal properties ; viscoelastic properties</subject><ispartof>Journal of applied polymer science, 2008-06, Vol.108 (6), p.3495-3506</ispartof><rights>Copyright © 2008 Wiley Periodicals, Inc.</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3927-f80dc4746410df66fe3c1c19bf0fdde7c8df08cbbf85c0e7f9b22ea160bedaf3</citedby><cites>FETCH-LOGICAL-c3927-f80dc4746410df66fe3c1c19bf0fdde7c8df08cbbf85c0e7f9b22ea160bedaf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.27957$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.27957$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20309539$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Boyd, Steven E</creatorcontrib><creatorcontrib>La Scala, John J</creatorcontrib><creatorcontrib>Palmese, Guiseppe R</creatorcontrib><title>Molecular relaxation behavior of fatty acid-based vinyl ester resins</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The experimental characterization of the time-dependent properties of fatty acid-based vinyl ester resins with reduced styrene content and emissions was conducted and compared with that of various commercial vinyl ester (VE) resins. Constant heating rate and isothermal, multifrequency sweep experiments were conducted over a wide temperature range using dynamic mechanical analysis. Storage and loss modulus master-curves were formed using time-temperature superposition (TTSP) and analyzed to quantify the molecular relaxation behavior using accepted techniques and theories. Special attention was focused on determining the effect of reducing styrene weight percent on the derived viscoelastic properties. The fatty acid-based VE resins were found to have similar or slightly inferior thermomechanical properties and a more pronounced viscoelastic response compared with the commercial resins. However, the research definitively demonstrates that the evaluated fatty acid VE resins are a viable replacement to commercial resins in certain applications with concomitant attractive environmental benefits.</description><subject>Applied sciences</subject><subject>Chemical properties</subject><subject>Exact sciences and technology</subject><subject>fatty acid vinyl esters</subject><subject>Polymer industry, paints, wood</subject><subject>Properties and testing</subject><subject>relaxation</subject><subject>styrene replacements/alternatives</subject><subject>Technology of polymers</subject><subject>thermal properties</subject><subject>viscoelastic properties</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp1kU1P3DAQhq2qSN1CD_0FzQWkHgJjO_HHEW3bLQjoSt2qR2vi2MXUJFt7l7L_voZQbpzmMM_zavQOIe8pHFMAdoLr9TGTupWvyIyClnUjmHpNZmVHa6V1-4a8zfkGgNIWxIx8uhyjs9uIqUou4j1uwjhUnbvGuzCmavSVx81mV6ENfd1hdn11F4ZdrFzeuAcnhyEfkD2PMbt3T3OfrL58Xs2_1hffFmfz04vacs1k7RX0tpGNaCj0XgjvuKWW6s6D73snreo9KNt1XrUWnPS6Y8whFdC5Hj3fJ0dT7DqNf7blAHMbsnUx4uDGbTacA1WiYQX8OIE2jTkn5806hVtMO0PBPNRkSk3msabCHj6FYrYYfcLBhvwsMOCgW64LdzJxf0N0u5cDzely-T-5noxQqrp_NjD9NkJy2ZqfVwszp-divlouzKrwHybe42jwVypX_PjOgHIApcq7NP8HaUCQPA</recordid><startdate>20080615</startdate><enddate>20080615</enddate><creator>Boyd, Steven E</creator><creator>La Scala, John J</creator><creator>Palmese, Guiseppe R</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20080615</creationdate><title>Molecular relaxation behavior of fatty acid-based vinyl ester resins</title><author>Boyd, Steven E ; La Scala, John J ; Palmese, Guiseppe R</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3927-f80dc4746410df66fe3c1c19bf0fdde7c8df08cbbf85c0e7f9b22ea160bedaf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Applied sciences</topic><topic>Chemical properties</topic><topic>Exact sciences and technology</topic><topic>fatty acid vinyl esters</topic><topic>Polymer industry, paints, wood</topic><topic>Properties and testing</topic><topic>relaxation</topic><topic>styrene replacements/alternatives</topic><topic>Technology of polymers</topic><topic>thermal properties</topic><topic>viscoelastic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Boyd, Steven E</creatorcontrib><creatorcontrib>La Scala, John J</creatorcontrib><creatorcontrib>Palmese, Guiseppe R</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Boyd, Steven E</au><au>La Scala, John J</au><au>Palmese, Guiseppe R</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Molecular relaxation behavior of fatty acid-based vinyl ester resins</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2008-06-15</date><risdate>2008</risdate><volume>108</volume><issue>6</issue><spage>3495</spage><epage>3506</epage><pages>3495-3506</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The experimental characterization of the time-dependent properties of fatty acid-based vinyl ester resins with reduced styrene content and emissions was conducted and compared with that of various commercial vinyl ester (VE) resins. Constant heating rate and isothermal, multifrequency sweep experiments were conducted over a wide temperature range using dynamic mechanical analysis. Storage and loss modulus master-curves were formed using time-temperature superposition (TTSP) and analyzed to quantify the molecular relaxation behavior using accepted techniques and theories. Special attention was focused on determining the effect of reducing styrene weight percent on the derived viscoelastic properties. The fatty acid-based VE resins were found to have similar or slightly inferior thermomechanical properties and a more pronounced viscoelastic response compared with the commercial resins. However, the research definitively demonstrates that the evaluated fatty acid VE resins are a viable replacement to commercial resins in certain applications with concomitant attractive environmental benefits.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.27957</doi><tpages>12</tpages></addata></record> |
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subjects | Applied sciences Chemical properties Exact sciences and technology fatty acid vinyl esters Polymer industry, paints, wood Properties and testing relaxation styrene replacements/alternatives Technology of polymers thermal properties viscoelastic properties |
title | Molecular relaxation behavior of fatty acid-based vinyl ester resins |
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