Lattice parameters values and phase diagram for the Cu2Zn1-zFezGeSe4 alloy system

X-ray powder diffraction and differential thermal analysis (DTA) measurements were made on polycrystalline samples of the Cu2Zn1-zFezGeSe4 alloy system. The diffraction patterns were used to show the equilibrium conditions and to estimate crystalline parameter values. It was found that, at room temp...

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Veröffentlicht in:Journal of alloys and compounds 2008-06, Vol.457 (1-2), p.221-224
Hauptverfasser: CALDERA, D, QUINTERO, M, BRICENO, J. M, FERNANDEZ, J. L, MOROCOIMA, M, QUINTERO, E, GRIMA, P, MARCHAN, N, MORENO, E, BOCARANDA, P, DELGADO, G. E, MORA, A. E
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container_end_page 224
container_issue 1-2
container_start_page 221
container_title Journal of alloys and compounds
container_volume 457
creator CALDERA, D
QUINTERO, M
BRICENO, J. M
FERNANDEZ, J. L
MOROCOIMA, M
QUINTERO, E
GRIMA, P
MARCHAN, N
MORENO, E
BOCARANDA, P
DELGADO, G. E
MORA, A. E
description X-ray powder diffraction and differential thermal analysis (DTA) measurements were made on polycrystalline samples of the Cu2Zn1-zFezGeSe4 alloy system. The diffraction patterns were used to show the equilibrium conditions and to estimate crystalline parameter values. It was found that, at room temperature, a single phase solid solution with the tetragonal stannite structure occurs across the whole composition range. The DTA thermograms were used to construct the phase diagram of the Cu2Zn1-zFezGeSe4 alloy system. It was confirmed that the Cu2ZnGeSe4 compound melts incongruently. It was observed that undercooling effects occur for samples with z > 0.9.
doi_str_mv 10.1016/j.jallcom.2007.03.033
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source ScienceDirect Journals (5 years ago - present)
subjects Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
title Lattice parameters values and phase diagram for the Cu2Zn1-zFezGeSe4 alloy system
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