Lattice parameters values and phase diagram for the Cu2Zn1-zFezGeSe4 alloy system
X-ray powder diffraction and differential thermal analysis (DTA) measurements were made on polycrystalline samples of the Cu2Zn1-zFezGeSe4 alloy system. The diffraction patterns were used to show the equilibrium conditions and to estimate crystalline parameter values. It was found that, at room temp...
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Veröffentlicht in: | Journal of alloys and compounds 2008-06, Vol.457 (1-2), p.221-224 |
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creator | CALDERA, D QUINTERO, M BRICENO, J. M FERNANDEZ, J. L MOROCOIMA, M QUINTERO, E GRIMA, P MARCHAN, N MORENO, E BOCARANDA, P DELGADO, G. E MORA, A. E |
description | X-ray powder diffraction and differential thermal analysis (DTA) measurements were made on polycrystalline samples of the Cu2Zn1-zFezGeSe4 alloy system. The diffraction patterns were used to show the equilibrium conditions and to estimate crystalline parameter values. It was found that, at room temperature, a single phase solid solution with the tetragonal stannite structure occurs across the whole composition range. The DTA thermograms were used to construct the phase diagram of the Cu2Zn1-zFezGeSe4 alloy system. It was confirmed that the Cu2ZnGeSe4 compound melts incongruently. It was observed that undercooling effects occur for samples with z > 0.9. |
doi_str_mv | 10.1016/j.jallcom.2007.03.033 |
format | Article |
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M ; FERNANDEZ, J. L ; MOROCOIMA, M ; QUINTERO, E ; GRIMA, P ; MARCHAN, N ; MORENO, E ; BOCARANDA, P ; DELGADO, G. E ; MORA, A. E</creator><creatorcontrib>CALDERA, D ; QUINTERO, M ; BRICENO, J. M ; FERNANDEZ, J. L ; MOROCOIMA, M ; QUINTERO, E ; GRIMA, P ; MARCHAN, N ; MORENO, E ; BOCARANDA, P ; DELGADO, G. E ; MORA, A. E</creatorcontrib><description>X-ray powder diffraction and differential thermal analysis (DTA) measurements were made on polycrystalline samples of the Cu2Zn1-zFezGeSe4 alloy system. The diffraction patterns were used to show the equilibrium conditions and to estimate crystalline parameter values. It was found that, at room temperature, a single phase solid solution with the tetragonal stannite structure occurs across the whole composition range. The DTA thermograms were used to construct the phase diagram of the Cu2Zn1-zFezGeSe4 alloy system. It was confirmed that the Cu2ZnGeSe4 compound melts incongruently. 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The DTA thermograms were used to construct the phase diagram of the Cu2Zn1-zFezGeSe4 alloy system. It was confirmed that the Cu2ZnGeSe4 compound melts incongruently. 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source | ScienceDirect Journals (5 years ago - present) |
subjects | Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Inorganic compounds Physics Structure of solids and liquids crystallography Structure of specific crystalline solids |
title | Lattice parameters values and phase diagram for the Cu2Zn1-zFezGeSe4 alloy system |
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