Self-assembly of a silver nanoparticles modified electrode and its electrocatalysis on neutral red

Silver nanoparticles (AgNP) were synthesized with NaBH 4 as reducing agent and oleate as stabilizer. AgNP and L-cysteine (L-cys) were co-deposited on a gold electrode surface to fabricate the AgNP/L-cys modified electrode (AgNP/L-cys/Au). First, we prepared the L-cysteine self-assembled film modifie...

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Veröffentlicht in:Mikrochimica acta (1966) 2009-01, Vol.164 (1-2), p.149-155
Hauptverfasser: Wang, Guangfeng, Wang, Wen, Wu, Jianfeng, Liu, Hongying, Jiao, Shoufeng, Fang, Bin
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container_issue 1-2
container_start_page 149
container_title Mikrochimica acta (1966)
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creator Wang, Guangfeng
Wang, Wen
Wu, Jianfeng
Liu, Hongying
Jiao, Shoufeng
Fang, Bin
description Silver nanoparticles (AgNP) were synthesized with NaBH 4 as reducing agent and oleate as stabilizer. AgNP and L-cysteine (L-cys) were co-deposited on a gold electrode surface to fabricate the AgNP/L-cys modified electrode (AgNP/L-cys/Au). First, we prepared the L-cysteine self-assembled film modified gold electrode through S-Au bond, then it was rinsed into the Ag colloid solution to prepare the Ag nanoparticles/L-cysteine modified electrode through interaction of the silver surface and the carboxylate and amino groups of L-cysteine. After the self-assembled electrode was prepared, the electrochemical behavior of the modified electrode was investigated. The electrochemical response of neutral red (NR) on the modified electrode was investigated. The electrochemical response of cyclic voltammetry and determination by differential pulse voltammetry of neutral red on the modified electrode were reported. We also observed that the modified electrode catalyzes the redox process of neutral red, which provided another way of applying Ag nanoparticles in composite neutral red-AgNP films.
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subjects Analytical Chemistry
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Electrochemical methods
Exact sciences and technology
Microengineering
Nanochemistry
Nanotechnology
Original Paper
title Self-assembly of a silver nanoparticles modified electrode and its electrocatalysis on neutral red
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