Raman scattering features of lead pyroantimonate compounds. Part I: XRD and Raman characterization of Pb2Sb2O7 doped with tin and zinc
Yellow pyroantimonates PbSb, PbSbSn and PbSbZn were synthesized by solid‐state reactions at high temperature and characterized by X‐ray diffraction and Raman spectroscopy. The lattice size of cubic pyrochlores increases with Sn and Zn doping and with Pb overstoichiometry, indicating the replace...
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| Veröffentlicht in: | Journal of Raman spectroscopy 2009-01, Vol.40 (1), p.107-111 |
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| container_title | Journal of Raman spectroscopy |
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| creator | Rosi, F. Manuali, V. Miliani, C. Brunetti, B. G. Sgamellotti, A. Grygar, T. Hradil, D. |
| description | Yellow pyroantimonates PbSb, PbSbSn and PbSbZn were synthesized by solid‐state reactions at high temperature and characterized by X‐ray diffraction and Raman spectroscopy. The lattice size of cubic pyrochlores increases with Sn and Zn doping and with Pb overstoichiometry, indicating the replacement of Sb5+ by the larger cations. This fact permits the understanding of the corresponding Raman spectral modifications as a consequence of the changes in the local symmetry of the SbO polyhedra, justifying the exploitation of Raman spectroscopy to noninvasively identify structural modifications of pyroantimonate pigments in artworks. Copyright © 2008 John Wiley & Sons, Ltd.
Reference lead antimonate pigments were synthesized following historical recipes and then characterized by X‐ray powder diffraction with Rietveld refinement, obtaining the crystallographic structures and lattice parameters. The structural information was used to interpret the modification induced by Sn and Zn doping on Raman scattering signatures of the corresponding pyrochlore structures. |
| doi_str_mv | 10.1002/jrs.2092 |
| format | Article |
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Reference lead antimonate pigments were synthesized following historical recipes and then characterized by X‐ray powder diffraction with Rietveld refinement, obtaining the crystallographic structures and lattice parameters. The structural information was used to interpret the modification induced by Sn and Zn doping on Raman scattering signatures of the corresponding pyrochlore structures.</description><identifier>ISSN: 0377-0486</identifier><identifier>EISSN: 1097-4555</identifier><identifier>DOI: 10.1002/jrs.2092</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>Cations ; Cubic lattice ; cubic pyrochlores ; Diffraction ; Doping ; lead antimonate yellow ; Naples yellow ; Polyhedrons ; Raman spectroscopy ; Tin ; XRD ; Zinc</subject><ispartof>Journal of Raman spectroscopy, 2009-01, Vol.40 (1), p.107-111</ispartof><rights>Copyright © 2008 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fjrs.2092$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fjrs.2092$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Rosi, F.</creatorcontrib><creatorcontrib>Manuali, V.</creatorcontrib><creatorcontrib>Miliani, C.</creatorcontrib><creatorcontrib>Brunetti, B. G.</creatorcontrib><creatorcontrib>Sgamellotti, A.</creatorcontrib><creatorcontrib>Grygar, T.</creatorcontrib><creatorcontrib>Hradil, D.</creatorcontrib><title>Raman scattering features of lead pyroantimonate compounds. Part I: XRD and Raman characterization of Pb2Sb2O7 doped with tin and zinc</title><title>Journal of Raman spectroscopy</title><addtitle>J. Raman Spectrosc</addtitle><description>Yellow pyroantimonates PbSb, PbSbSn and PbSbZn were synthesized by solid‐state reactions at high temperature and characterized by X‐ray diffraction and Raman spectroscopy. The lattice size of cubic pyrochlores increases with Sn and Zn doping and with Pb overstoichiometry, indicating the replacement of Sb5+ by the larger cations. This fact permits the understanding of the corresponding Raman spectral modifications as a consequence of the changes in the local symmetry of the SbO polyhedra, justifying the exploitation of Raman spectroscopy to noninvasively identify structural modifications of pyroantimonate pigments in artworks. Copyright © 2008 John Wiley & Sons, Ltd.
Reference lead antimonate pigments were synthesized following historical recipes and then characterized by X‐ray powder diffraction with Rietveld refinement, obtaining the crystallographic structures and lattice parameters. The structural information was used to interpret the modification induced by Sn and Zn doping on Raman scattering signatures of the corresponding pyrochlore structures.</description><subject>Cations</subject><subject>Cubic lattice</subject><subject>cubic pyrochlores</subject><subject>Diffraction</subject><subject>Doping</subject><subject>lead antimonate yellow</subject><subject>Naples yellow</subject><subject>Polyhedrons</subject><subject>Raman spectroscopy</subject><subject>Tin</subject><subject>XRD</subject><subject>Zinc</subject><issn>0377-0486</issn><issn>1097-4555</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp9kU1v1DAQhiMEEktB4if4hLhk64_ETrihQj_oalttK8HNmjgT6pLYwfaq3f4AfjdJF9FbT3N4n3mkmTfL3jO6ZJTyw9sQl5zW_EW2YLRWeVGW5ctsQYVSOS0q-Tp7E-MtpbSuJVtkfzYwgCPRQEoYrPtJOoS0DRiJ70iP0JJxFzy4ZAfvICExfhj91rVxSS4hJHL2ifzYfCHgWrJ3mRsIYGbbAyTr3Sy6bPhVwy8Uaf2ILbmz6YYk6x63Hqwzb7NXHfQR3_2bB9n18dfro9N8dXFydvR5lVtelzxHOV0AsjUci45RhTXjhWGVRKVkhbJRpWxaYKxqpkRhIaZEmI52krFSiIPsw147Bv97izHpwUaDfQ8O_TZqwatKiLKewI_PgoxLqaaXytmZ79E72-NOj8EOEHaaUT33oac-9NyH_ra5mucTb2PC-_88hF96Vpb6-_pEr4rT4zU_F3ot_gKrlY5C</recordid><startdate>200901</startdate><enddate>200901</enddate><creator>Rosi, F.</creator><creator>Manuali, V.</creator><creator>Miliani, C.</creator><creator>Brunetti, B. G.</creator><creator>Sgamellotti, A.</creator><creator>Grygar, T.</creator><creator>Hradil, D.</creator><general>John Wiley & Sons, Ltd</general><scope>BSCLL</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>200901</creationdate><title>Raman scattering features of lead pyroantimonate compounds. Part I: XRD and Raman characterization of Pb2Sb2O7 doped with tin and zinc</title><author>Rosi, F. ; Manuali, V. ; Miliani, C. ; Brunetti, B. G. ; Sgamellotti, A. ; Grygar, T. ; Hradil, D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i2952-e6486a6dc2e4f107e9124c186e7768e6b756bda118b9127e436e73cf0f611533</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Cations</topic><topic>Cubic lattice</topic><topic>cubic pyrochlores</topic><topic>Diffraction</topic><topic>Doping</topic><topic>lead antimonate yellow</topic><topic>Naples yellow</topic><topic>Polyhedrons</topic><topic>Raman spectroscopy</topic><topic>Tin</topic><topic>XRD</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rosi, F.</creatorcontrib><creatorcontrib>Manuali, V.</creatorcontrib><creatorcontrib>Miliani, C.</creatorcontrib><creatorcontrib>Brunetti, B. G.</creatorcontrib><creatorcontrib>Sgamellotti, A.</creatorcontrib><creatorcontrib>Grygar, T.</creatorcontrib><creatorcontrib>Hradil, D.</creatorcontrib><collection>Istex</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of Raman spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rosi, F.</au><au>Manuali, V.</au><au>Miliani, C.</au><au>Brunetti, B. G.</au><au>Sgamellotti, A.</au><au>Grygar, T.</au><au>Hradil, D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Raman scattering features of lead pyroantimonate compounds. Part I: XRD and Raman characterization of Pb2Sb2O7 doped with tin and zinc</atitle><jtitle>Journal of Raman spectroscopy</jtitle><addtitle>J. Raman Spectrosc</addtitle><date>2009-01</date><risdate>2009</risdate><volume>40</volume><issue>1</issue><spage>107</spage><epage>111</epage><pages>107-111</pages><issn>0377-0486</issn><eissn>1097-4555</eissn><abstract>Yellow pyroantimonates PbSb, PbSbSn and PbSbZn were synthesized by solid‐state reactions at high temperature and characterized by X‐ray diffraction and Raman spectroscopy. The lattice size of cubic pyrochlores increases with Sn and Zn doping and with Pb overstoichiometry, indicating the replacement of Sb5+ by the larger cations. This fact permits the understanding of the corresponding Raman spectral modifications as a consequence of the changes in the local symmetry of the SbO polyhedra, justifying the exploitation of Raman spectroscopy to noninvasively identify structural modifications of pyroantimonate pigments in artworks. Copyright © 2008 John Wiley & Sons, Ltd.
Reference lead antimonate pigments were synthesized following historical recipes and then characterized by X‐ray powder diffraction with Rietveld refinement, obtaining the crystallographic structures and lattice parameters. The structural information was used to interpret the modification induced by Sn and Zn doping on Raman scattering signatures of the corresponding pyrochlore structures.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/jrs.2092</doi><tpages>5</tpages></addata></record> |
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| source | Wiley Journals |
| subjects | Cations Cubic lattice cubic pyrochlores Diffraction Doping lead antimonate yellow Naples yellow Polyhedrons Raman spectroscopy Tin XRD Zinc |
| title | Raman scattering features of lead pyroantimonate compounds. Part I: XRD and Raman characterization of Pb2Sb2O7 doped with tin and zinc |
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