Adsorption of star polymers studied by a new numerical mean field theory
We present a systematic theoretical investigation of star-like polymers of various architectures near adsorbing surface, using a new numerical self-consistent mean field theory. The comparison of the experimentally reported adsorption profiles with the predictions of our method shows excellent agree...
Gespeichert in:
| Veröffentlicht in: | Polymer (Guilford) 2008-07, Vol.49 (16), p.3601-3609 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3609 |
|---|---|
| container_issue | 16 |
| container_start_page | 3601 |
| container_title | Polymer (Guilford) |
| container_volume | 49 |
| creator | Kritikos, Georgios Terzis, Andreas F. |
| description | We present a systematic theoretical investigation of star-like polymers of various architectures near adsorbing surface, using a new numerical self-consistent mean field theory. The comparison of the experimentally reported adsorption profiles with the predictions of our method shows excellent agreement. The study of the structural properties of the formed brushes indicates that as the number of branches is increased the number of adsorbed polymers is significantly reduced. Mixtures of different kinds of star polymers show interesting behaviors as the more branched polymers try to develop in the outer region of brush. We also estimate the forces obtained when curved surfaces come close as a function of the distance between the surfaces.
[Display omitted] |
| doi_str_mv | 10.1016/j.polymer.2008.05.042 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_32865902</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0032386108004904</els_id><sourcerecordid>32865902</sourcerecordid><originalsourceid>FETCH-LOGICAL-c370t-42544b8d752ac44cac992e046bc63be1779d586d9c621d9b0c2141828653ce773</originalsourceid><addsrcrecordid>eNqFkE-L2zAQxUXZQrNpP0JBl-3N3tFf26clhN1NIbCX9ixkaUwVHCuV7JZ8-yok7LWnYYbfe8N7hHxlUDNg-vFQn-J4PmKqOUBbg6pB8g9kxdpGVJx37I6sAASvRKvZJ3Kf8wEAuOJyRXYbn2M6zSFONA40zzbRm1su2-IDetqfqaUT_qXTUu7B2ZEe0U50CDh6Ov_CmM6fycfBjhm_3Oaa_Hx5_rHdVfu31-_bzb5yooG5klxJ2be-Udw6KZ11XccRpO6dFj2ypum8arXvnObMdz04ziRreauVcNg0Yk2-XX1PKf5eMM_mGLLDcbQTxiUbcUE74AVUV9ClmHPCwZxSONp0NgzMpTdzMLek5tKbAWVKb0X3cHtgc0k6JDu5kN_FHJRotG4L93TlsKT9E4pLdgEnhz4kdLPxMfzn0z-Z-YXj</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>32865902</pqid></control><display><type>article</type><title>Adsorption of star polymers studied by a new numerical mean field theory</title><source>Elsevier ScienceDirect Journals</source><creator>Kritikos, Georgios ; Terzis, Andreas F.</creator><creatorcontrib>Kritikos, Georgios ; Terzis, Andreas F.</creatorcontrib><description>We present a systematic theoretical investigation of star-like polymers of various architectures near adsorbing surface, using a new numerical self-consistent mean field theory. The comparison of the experimentally reported adsorption profiles with the predictions of our method shows excellent agreement. The study of the structural properties of the formed brushes indicates that as the number of branches is increased the number of adsorbed polymers is significantly reduced. Mixtures of different kinds of star polymers show interesting behaviors as the more branched polymers try to develop in the outer region of brush. We also estimate the forces obtained when curved surfaces come close as a function of the distance between the surfaces.
[Display omitted]</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/j.polymer.2008.05.042</identifier><identifier>CODEN: POLMAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polymer brush ; Properties and characterization ; Self-consistent mean field method ; Solution and gel properties ; Star polymers</subject><ispartof>Polymer (Guilford), 2008-07, Vol.49 (16), p.3601-3609</ispartof><rights>2008 Elsevier Ltd</rights><rights>2008 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c370t-42544b8d752ac44cac992e046bc63be1779d586d9c621d9b0c2141828653ce773</citedby><cites>FETCH-LOGICAL-c370t-42544b8d752ac44cac992e046bc63be1779d586d9c621d9b0c2141828653ce773</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0032386108004904$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20537668$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kritikos, Georgios</creatorcontrib><creatorcontrib>Terzis, Andreas F.</creatorcontrib><title>Adsorption of star polymers studied by a new numerical mean field theory</title><title>Polymer (Guilford)</title><description>We present a systematic theoretical investigation of star-like polymers of various architectures near adsorbing surface, using a new numerical self-consistent mean field theory. The comparison of the experimentally reported adsorption profiles with the predictions of our method shows excellent agreement. The study of the structural properties of the formed brushes indicates that as the number of branches is increased the number of adsorbed polymers is significantly reduced. Mixtures of different kinds of star polymers show interesting behaviors as the more branched polymers try to develop in the outer region of brush. We also estimate the forces obtained when curved surfaces come close as a function of the distance between the surfaces.
[Display omitted]</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymer brush</subject><subject>Properties and characterization</subject><subject>Self-consistent mean field method</subject><subject>Solution and gel properties</subject><subject>Star polymers</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkE-L2zAQxUXZQrNpP0JBl-3N3tFf26clhN1NIbCX9ixkaUwVHCuV7JZ8-yok7LWnYYbfe8N7hHxlUDNg-vFQn-J4PmKqOUBbg6pB8g9kxdpGVJx37I6sAASvRKvZJ3Kf8wEAuOJyRXYbn2M6zSFONA40zzbRm1su2-IDetqfqaUT_qXTUu7B2ZEe0U50CDh6Ov_CmM6fycfBjhm_3Oaa_Hx5_rHdVfu31-_bzb5yooG5klxJ2be-Udw6KZ11XccRpO6dFj2ypum8arXvnObMdz04ziRreauVcNg0Yk2-XX1PKf5eMM_mGLLDcbQTxiUbcUE74AVUV9ClmHPCwZxSONp0NgzMpTdzMLek5tKbAWVKb0X3cHtgc0k6JDu5kN_FHJRotG4L93TlsKT9E4pLdgEnhz4kdLPxMfzn0z-Z-YXj</recordid><startdate>20080728</startdate><enddate>20080728</enddate><creator>Kritikos, Georgios</creator><creator>Terzis, Andreas F.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope></search><sort><creationdate>20080728</creationdate><title>Adsorption of star polymers studied by a new numerical mean field theory</title><author>Kritikos, Georgios ; Terzis, Andreas F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c370t-42544b8d752ac44cac992e046bc63be1779d586d9c621d9b0c2141828653ce773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymer brush</topic><topic>Properties and characterization</topic><topic>Self-consistent mean field method</topic><topic>Solution and gel properties</topic><topic>Star polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kritikos, Georgios</creatorcontrib><creatorcontrib>Terzis, Andreas F.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kritikos, Georgios</au><au>Terzis, Andreas F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption of star polymers studied by a new numerical mean field theory</atitle><jtitle>Polymer (Guilford)</jtitle><date>2008-07-28</date><risdate>2008</risdate><volume>49</volume><issue>16</issue><spage>3601</spage><epage>3609</epage><pages>3601-3609</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>We present a systematic theoretical investigation of star-like polymers of various architectures near adsorbing surface, using a new numerical self-consistent mean field theory. The comparison of the experimentally reported adsorption profiles with the predictions of our method shows excellent agreement. The study of the structural properties of the formed brushes indicates that as the number of branches is increased the number of adsorbed polymers is significantly reduced. Mixtures of different kinds of star polymers show interesting behaviors as the more branched polymers try to develop in the outer region of brush. We also estimate the forces obtained when curved surfaces come close as a function of the distance between the surfaces.
[Display omitted]</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymer.2008.05.042</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0032-3861 |
| ispartof | Polymer (Guilford), 2008-07, Vol.49 (16), p.3601-3609 |
| issn | 0032-3861 1873-2291 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_32865902 |
| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymer brush Properties and characterization Self-consistent mean field method Solution and gel properties Star polymers |
| title | Adsorption of star polymers studied by a new numerical mean field theory |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-26T13%3A00%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Adsorption%20of%20star%20polymers%20studied%20by%20a%20new%20numerical%20mean%20field%20theory&rft.jtitle=Polymer%20(Guilford)&rft.au=Kritikos,%20Georgios&rft.date=2008-07-28&rft.volume=49&rft.issue=16&rft.spage=3601&rft.epage=3609&rft.pages=3601-3609&rft.issn=0032-3861&rft.eissn=1873-2291&rft.coden=POLMAG&rft_id=info:doi/10.1016/j.polymer.2008.05.042&rft_dat=%3Cproquest_cross%3E32865902%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=32865902&rft_id=info:pmid/&rft_els_id=S0032386108004904&rfr_iscdi=true |