Effect of Cr on the corrosion resistance of Cu–6Ni–4Sn alloys

The corrosion characteristics of Cu–6% Ni–4% Sn– x% Cr alloys in an acid-chloride solution (0.1 M H 2SO 4 + 0.0056 M NaCl) at pH 1.2, were studied as a function of the chromium content. Three kinds of Cu–6% Ni–4% Sn– x% Cr alloys were prepared by melting and casting, followed by thermomechanical tre...

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Veröffentlicht in:Journal of alloys and compounds 2008-05, Vol.455 (1), p.358-363
Hauptverfasser: Jeon, W.S., Shur, C.C., Kim, J.G., Han, S.Z., Kim, Y.S.
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container_end_page 363
container_issue 1
container_start_page 358
container_title Journal of alloys and compounds
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creator Jeon, W.S.
Shur, C.C.
Kim, J.G.
Han, S.Z.
Kim, Y.S.
description The corrosion characteristics of Cu–6% Ni–4% Sn– x% Cr alloys in an acid-chloride solution (0.1 M H 2SO 4 + 0.0056 M NaCl) at pH 1.2, were studied as a function of the chromium content. Three kinds of Cu–6% Ni–4% Sn– x% Cr alloys were prepared by melting and casting, followed by thermomechanical treatments. The corrosion behavior of the Cu–6% Ni–4% Sn– x% Cr alloys was investigated using electrochemical corrosion test and surface analyses (optical microscopy, electron probe microanalysis and scanning electron microscopy). The addition of Cr was found to prevent the localized corrosion behavior, which is caused by the decreased Sn-rich precipitates in Cu–6% Ni–4% Sn– x% Cr alloys. These precipitates induced galvanic corrosion due to the difference of the chemical composition.
doi_str_mv 10.1016/j.jallcom.2007.01.139
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subjects Acid-chloride solution
Applied sciences
Corrosion
Corrosion mechanisms
Cu–Ni–Sn alloy
Exact sciences and technology
Galvanic effect
Localized corrosion
Metals. Metallurgy
Sn-rich precipitate
title Effect of Cr on the corrosion resistance of Cu–6Ni–4Sn alloys
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