Correlation between Functionated Structure and Nanomechanical Property Profiles of Silsesquioxane Films and Bulks
Three silsesquioxane (SSO) building blocks based on [3-(methacryloxy)propyl]trimethoxysilane (MPMS), [(3-glycidoxy)propyl] trimethoxysilane (GPMS), (vinyl)trimethoxysilane (VMS) and modified with 15 wt-% tetraethoxysilane (TEOS) were prepared using hydrolytic condensation. The hardness, elastic modu...
Gespeichert in:
| Veröffentlicht in: | Macromolecular symposia 2008-06, Vol.267 (1), p.79-84 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 84 |
|---|---|
| container_issue | 1 |
| container_start_page | 79 |
| container_title | Macromolecular symposia |
| container_volume | 267 |
| creator | Hu, Lijiang Wang, Di Lu, Zushun Song, Yanwei Song, Changmei |
| description | Three silsesquioxane (SSO) building blocks based on [3-(methacryloxy)propyl]trimethoxysilane (MPMS), [(3-glycidoxy)propyl] trimethoxysilane (GPMS), (vinyl)trimethoxysilane (VMS) and modified with 15 wt-% tetraethoxysilane (TEOS) were prepared using hydrolytic condensation. The hardness, elastic modulus and harmonic contact stiffness for three films [f-MTSSO (film-MPMS-TEOS-SSO), f-GTSSO and f-VTSSO] and bulks (b-MTSSO, b-GTSSO and b-VTSSO) derived from the three SSOs were tested by instrument-indentation testing. Different profiles of nanomechanical properties of the films can be attributed to a different functionality and the functionated structure of the different SSOs. The f-MTSSO shows better mechanical properties which are higher than the other two films containing more OH or OCH₃ groups. For the f-GTSSO with a bulky organic substituent, the unsatisfactory properties resulting from ring opening during hydrolytic condensation and an incomplete crosslinking network are discussed. However, the nanomechanical properties of the three bulks are very different from the corresponding nanomechanical properties of their films: b-VTSSO possesses the best nanomechanical properties (note: not b-MTSSO) among three bulks due to the differences in reaction conditions and chain less flexibility which are also discussed. |
| doi_str_mv | 10.1002/masy.200850714 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_32815351</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1266744240</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4854-b43ed9849db868c202f36ed008627b6d9d960d3f6477ac7a979d392931bbac773</originalsourceid><addsrcrecordid>eNqFkk1v1DAQhiMEUkvptVd8AXHJMv6IHR_Lii2gZVu0VIiT5TgOmCbxrp2o3X-PQ6oVJzh5bD3vzDszzrILDAsMQN52Oh4WBKAsQGD2JDvFBcE5lQBPUwyE5JhyOMmex_gLAKQU-DTbL30IttWD8z2q7HBvbY9WY2-mBz3YGm2HMJphDBbpvkYb3fvOmp-6d0a36Cb4nQ3DYQoa19qIfIO2ro027kfnH3Rv0cq1Xfwjfje2d_FF9qzRCTh_PM-y29X7r8sP-fr66uPycp0bVhYsrxi1tSyZrKuSl4YAaSi3dWqPE1HxWtaSQ00bzoTQRmgpZE0lkRRXVboLepa9nvPugt-PNg6qc9HYtk2e_BgVJSUuaIET-OafICacC8YIg4QuZtQEH2OwjdoF1-lwUBjUtAQ1LUEdl5AErx5z65jm1QTdGxePKpI4wthkVs7cfRri4T9Z1efL7fe_a-Sz1sXBPhy1OtwpLqgo1LfNlfpC1zefViVWm8S_nPlGe6V_hOTndksA0_QncOpU0t-LTLI3</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1266744240</pqid></control><display><type>article</type><title>Correlation between Functionated Structure and Nanomechanical Property Profiles of Silsesquioxane Films and Bulks</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Hu, Lijiang ; Wang, Di ; Lu, Zushun ; Song, Yanwei ; Song, Changmei</creator><creatorcontrib>Hu, Lijiang ; Wang, Di ; Lu, Zushun ; Song, Yanwei ; Song, Changmei</creatorcontrib><description>Three silsesquioxane (SSO) building blocks based on [3-(methacryloxy)propyl]trimethoxysilane (MPMS), [(3-glycidoxy)propyl] trimethoxysilane (GPMS), (vinyl)trimethoxysilane (VMS) and modified with 15 wt-% tetraethoxysilane (TEOS) were prepared using hydrolytic condensation. The hardness, elastic modulus and harmonic contact stiffness for three films [f-MTSSO (film-MPMS-TEOS-SSO), f-GTSSO and f-VTSSO] and bulks (b-MTSSO, b-GTSSO and b-VTSSO) derived from the three SSOs were tested by instrument-indentation testing. Different profiles of nanomechanical properties of the films can be attributed to a different functionality and the functionated structure of the different SSOs. The f-MTSSO shows better mechanical properties which are higher than the other two films containing more OH or OCH₃ groups. For the f-GTSSO with a bulky organic substituent, the unsatisfactory properties resulting from ring opening during hydrolytic condensation and an incomplete crosslinking network are discussed. However, the nanomechanical properties of the three bulks are very different from the corresponding nanomechanical properties of their films: b-VTSSO possesses the best nanomechanical properties (note: not b-MTSSO) among three bulks due to the differences in reaction conditions and chain less flexibility which are also discussed.</description><identifier>ISSN: 1022-1360</identifier><identifier>EISSN: 1521-3900</identifier><identifier>DOI: 10.1002/masy.200850714</identifier><language>eng</language><publisher>Weinheim: Wiley-VCH Verlag</publisher><subject>Applied sciences ; Condensing ; Crosslinking ; elastic modulus ; Exact sciences and technology ; hardness ; harmonic contact stiffness ; Inorganic and organomineral polymers ; Nanocomposites ; nanoindentation ; Nanomaterials ; Nanostructure ; Networks ; Physicochemistry of polymers ; Properties and characterization ; Ring opening ; silsesquioxane ; thin film and bulk ; Ultrasonic testing</subject><ispartof>Macromolecular symposia, 2008-06, Vol.267 (1), p.79-84</ispartof><rights>Copyright © 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2008 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4854-b43ed9849db868c202f36ed008627b6d9d960d3f6477ac7a979d392931bbac773</citedby><cites>FETCH-LOGICAL-c4854-b43ed9849db868c202f36ed008627b6d9d960d3f6477ac7a979d392931bbac773</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmasy.200850714$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmasy.200850714$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>309,310,314,777,781,786,787,1412,23911,23912,25121,27905,27906,45555,45556</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20852447$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Hu, Lijiang</creatorcontrib><creatorcontrib>Wang, Di</creatorcontrib><creatorcontrib>Lu, Zushun</creatorcontrib><creatorcontrib>Song, Yanwei</creatorcontrib><creatorcontrib>Song, Changmei</creatorcontrib><title>Correlation between Functionated Structure and Nanomechanical Property Profiles of Silsesquioxane Films and Bulks</title><title>Macromolecular symposia</title><addtitle>Macromol. Symp</addtitle><description>Three silsesquioxane (SSO) building blocks based on [3-(methacryloxy)propyl]trimethoxysilane (MPMS), [(3-glycidoxy)propyl] trimethoxysilane (GPMS), (vinyl)trimethoxysilane (VMS) and modified with 15 wt-% tetraethoxysilane (TEOS) were prepared using hydrolytic condensation. The hardness, elastic modulus and harmonic contact stiffness for three films [f-MTSSO (film-MPMS-TEOS-SSO), f-GTSSO and f-VTSSO] and bulks (b-MTSSO, b-GTSSO and b-VTSSO) derived from the three SSOs were tested by instrument-indentation testing. Different profiles of nanomechanical properties of the films can be attributed to a different functionality and the functionated structure of the different SSOs. The f-MTSSO shows better mechanical properties which are higher than the other two films containing more OH or OCH₃ groups. For the f-GTSSO with a bulky organic substituent, the unsatisfactory properties resulting from ring opening during hydrolytic condensation and an incomplete crosslinking network are discussed. However, the nanomechanical properties of the three bulks are very different from the corresponding nanomechanical properties of their films: b-VTSSO possesses the best nanomechanical properties (note: not b-MTSSO) among three bulks due to the differences in reaction conditions and chain less flexibility which are also discussed.</description><subject>Applied sciences</subject><subject>Condensing</subject><subject>Crosslinking</subject><subject>elastic modulus</subject><subject>Exact sciences and technology</subject><subject>hardness</subject><subject>harmonic contact stiffness</subject><subject>Inorganic and organomineral polymers</subject><subject>Nanocomposites</subject><subject>nanoindentation</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Networks</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Ring opening</subject><subject>silsesquioxane</subject><subject>thin film and bulk</subject><subject>Ultrasonic testing</subject><issn>1022-1360</issn><issn>1521-3900</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkk1v1DAQhiMEUkvptVd8AXHJMv6IHR_Lii2gZVu0VIiT5TgOmCbxrp2o3X-PQ6oVJzh5bD3vzDszzrILDAsMQN52Oh4WBKAsQGD2JDvFBcE5lQBPUwyE5JhyOMmex_gLAKQU-DTbL30IttWD8z2q7HBvbY9WY2-mBz3YGm2HMJphDBbpvkYb3fvOmp-6d0a36Cb4nQ3DYQoa19qIfIO2ro027kfnH3Rv0cq1Xfwjfje2d_FF9qzRCTh_PM-y29X7r8sP-fr66uPycp0bVhYsrxi1tSyZrKuSl4YAaSi3dWqPE1HxWtaSQ00bzoTQRmgpZE0lkRRXVboLepa9nvPugt-PNg6qc9HYtk2e_BgVJSUuaIET-OafICacC8YIg4QuZtQEH2OwjdoF1-lwUBjUtAQ1LUEdl5AErx5z65jm1QTdGxePKpI4wthkVs7cfRri4T9Z1efL7fe_a-Sz1sXBPhy1OtwpLqgo1LfNlfpC1zefViVWm8S_nPlGe6V_hOTndksA0_QncOpU0t-LTLI3</recordid><startdate>200806</startdate><enddate>200806</enddate><creator>Hu, Lijiang</creator><creator>Wang, Di</creator><creator>Lu, Zushun</creator><creator>Song, Yanwei</creator><creator>Song, Changmei</creator><general>Wiley-VCH Verlag</general><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley-VCH</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>200806</creationdate><title>Correlation between Functionated Structure and Nanomechanical Property Profiles of Silsesquioxane Films and Bulks</title><author>Hu, Lijiang ; Wang, Di ; Lu, Zushun ; Song, Yanwei ; Song, Changmei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4854-b43ed9849db868c202f36ed008627b6d9d960d3f6477ac7a979d392931bbac773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Applied sciences</topic><topic>Condensing</topic><topic>Crosslinking</topic><topic>elastic modulus</topic><topic>Exact sciences and technology</topic><topic>hardness</topic><topic>harmonic contact stiffness</topic><topic>Inorganic and organomineral polymers</topic><topic>Nanocomposites</topic><topic>nanoindentation</topic><topic>Nanomaterials</topic><topic>Nanostructure</topic><topic>Networks</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><topic>Ring opening</topic><topic>silsesquioxane</topic><topic>thin film and bulk</topic><topic>Ultrasonic testing</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hu, Lijiang</creatorcontrib><creatorcontrib>Wang, Di</creatorcontrib><creatorcontrib>Lu, Zushun</creatorcontrib><creatorcontrib>Song, Yanwei</creatorcontrib><creatorcontrib>Song, Changmei</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Macromolecular symposia</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hu, Lijiang</au><au>Wang, Di</au><au>Lu, Zushun</au><au>Song, Yanwei</au><au>Song, Changmei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Correlation between Functionated Structure and Nanomechanical Property Profiles of Silsesquioxane Films and Bulks</atitle><jtitle>Macromolecular symposia</jtitle><addtitle>Macromol. Symp</addtitle><date>2008-06</date><risdate>2008</risdate><volume>267</volume><issue>1</issue><spage>79</spage><epage>84</epage><pages>79-84</pages><issn>1022-1360</issn><eissn>1521-3900</eissn><abstract>Three silsesquioxane (SSO) building blocks based on [3-(methacryloxy)propyl]trimethoxysilane (MPMS), [(3-glycidoxy)propyl] trimethoxysilane (GPMS), (vinyl)trimethoxysilane (VMS) and modified with 15 wt-% tetraethoxysilane (TEOS) were prepared using hydrolytic condensation. The hardness, elastic modulus and harmonic contact stiffness for three films [f-MTSSO (film-MPMS-TEOS-SSO), f-GTSSO and f-VTSSO] and bulks (b-MTSSO, b-GTSSO and b-VTSSO) derived from the three SSOs were tested by instrument-indentation testing. Different profiles of nanomechanical properties of the films can be attributed to a different functionality and the functionated structure of the different SSOs. The f-MTSSO shows better mechanical properties which are higher than the other two films containing more OH or OCH₃ groups. For the f-GTSSO with a bulky organic substituent, the unsatisfactory properties resulting from ring opening during hydrolytic condensation and an incomplete crosslinking network are discussed. However, the nanomechanical properties of the three bulks are very different from the corresponding nanomechanical properties of their films: b-VTSSO possesses the best nanomechanical properties (note: not b-MTSSO) among three bulks due to the differences in reaction conditions and chain less flexibility which are also discussed.</abstract><cop>Weinheim</cop><pub>Wiley-VCH Verlag</pub><doi>10.1002/masy.200850714</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1022-1360 |
| ispartof | Macromolecular symposia, 2008-06, Vol.267 (1), p.79-84 |
| issn | 1022-1360 1521-3900 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_32815351 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences Condensing Crosslinking elastic modulus Exact sciences and technology hardness harmonic contact stiffness Inorganic and organomineral polymers Nanocomposites nanoindentation Nanomaterials Nanostructure Networks Physicochemistry of polymers Properties and characterization Ring opening silsesquioxane thin film and bulk Ultrasonic testing |
| title | Correlation between Functionated Structure and Nanomechanical Property Profiles of Silsesquioxane Films and Bulks |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-20T00%3A58%3A14IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Correlation%20between%20Functionated%20Structure%20and%20Nanomechanical%20Property%20Profiles%20of%20Silsesquioxane%20Films%20and%20Bulks&rft.jtitle=Macromolecular%20symposia&rft.au=Hu,%20Lijiang&rft.date=2008-06&rft.volume=267&rft.issue=1&rft.spage=79&rft.epage=84&rft.pages=79-84&rft.issn=1022-1360&rft.eissn=1521-3900&rft_id=info:doi/10.1002/masy.200850714&rft_dat=%3Cproquest_cross%3E1266744240%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1266744240&rft_id=info:pmid/&rfr_iscdi=true |