Correlation of milling time on formation of TiCoSb phase by mechanical alloying

Nanocrystalline TiCoSb powder was synthesized by mechanical alloying from elemental Ti, Co and Sb powders. The samples milled at different times were characterized by X-ray diffractometer (XRD) and scanning electron microscopy (SEM). The synthesized powder shows a half-Heusler phase in MgAgAs struct...

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Veröffentlicht in:Journal of alloys and compounds 2008-08, Vol.462 (1), p.267-270
Hauptverfasser: Amornpitoksuk, P., Suwanboon, S.
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Suwanboon, S.
description Nanocrystalline TiCoSb powder was synthesized by mechanical alloying from elemental Ti, Co and Sb powders. The samples milled at different times were characterized by X-ray diffractometer (XRD) and scanning electron microscopy (SEM). The synthesized powder shows a half-Heusler phase in MgAgAs structure after 6 h of milling. The crystallite sizes decrease with increasing milling time. The minimum crystallite size is about 31.7 nm after 40 h of milling. The magnetic properties of this sample give evidence of the existence of ferromagnetic clusters as a secondary phase.
doi_str_mv 10.1016/j.jallcom.2007.08.009
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subjects Amorphous materials
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Magnetic properties and materials
Magnetic properties of nanostructures
Materials science
Mechanical alloying
Nanocrystalline materials
Nanoscale materials and structures: fabrication and characterization
Physics
Scanning electron microscopy
title Correlation of milling time on formation of TiCoSb phase by mechanical alloying
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