Synthetic 6FDA-ODA copolyimide membranes for gas separation and pervaporation: Correlation of separation properties with diamine monomers
Copolyimides were synthesized from 4,4′‐(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and 4‐aminophenyl ether (ODA) with 4‐aminophenyl sulfone (DDS), 4,4′‐methylenedianiline (MDA), 4,4′‐bis(3‐aminophenoxy)diphenyl sulfone (BADS), 4,4′‐bis(3‐aminophenoxy) benzophenone (BABP), and 2,6‐bis(3‐am...
Gespeichert in:
| Veröffentlicht in: | Polymer engineering and science 2008-04, Vol.48 (4), p.795-805 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 805 |
|---|---|
| container_issue | 4 |
| container_start_page | 795 |
| container_title | Polymer engineering and science |
| container_volume | 48 |
| creator | Xiao, Shude Feng, Xianshe Huang, Robert Y.M. |
| description | Copolyimides were synthesized from 4,4′‐(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and 4‐aminophenyl ether (ODA) with 4‐aminophenyl sulfone (DDS), 4,4′‐methylenedianiline (MDA), 4,4′‐bis(3‐aminophenoxy)diphenyl sulfone (BADS), 4,4′‐bis(3‐aminophenoxy) benzophenone (BABP), and 2,6‐bis(3‐aminophenoxyl) benzonitrile (DABN) as the third monomer. Surface free energies and interfacial free energies were calculated for comparison of the membrane hydrophilicity. Gas permeation was carried out with N2, O2, H2, He, and CO2, and the moiety contributions to membrane selectivity were calculated. DDS and BADS moieties contribute negatively to the selectivities toward O2/N2, H2/N2, and He/N2, and the DABN moiety is favorable for improving CO2/N2 selectivity. Water permeation and dehydration of isopropanol were performed, and the linear moiety contribution method was applied to study the effects of the monomer structures on the temperature and feed concentration dependencies of the permeation flux. The steric effects of DDS and BADS moieties, as well as the interactions of BABP and DABN moieties with water, account for the differences in pervaporation properties of the membranes. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers |
| doi_str_mv | 10.1002/pen.21007 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_miscellaneous_32688239</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A177908473</galeid><sourcerecordid>A177908473</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5067-162b924dbf773cfd72f6ef358a2fe2306d9f19bccec4856d5111575fb9e2e9fc3</originalsourceid><addsrcrecordid>eNp1ks1u1DAUhSMEEkNhwRtESCCxyNQ_ie2wG820paJqUcvP0nKc66lLYgc7Q5lH4K1xyVABGuSFrevvHF_bJ8ueYzTHCJHDAdycpBV_kM1wVYqCMFo-zGYIUVJQIcTj7EmMNyixtKpn2Y-rrRuvYbQ6Z8erRXGxWuTaD77b2t62kPfQN0E5iLnxIV-rmEcYVFCj9S5Xrs0HCN_U4KfKm3zpQ4Bu2vbmT3gIPrGjTVa3drzOW6t669IJ3vkeQnyaPTKqi_BsNx9kH4-PPizfFmcXJ6fLxVmhK8R4gRlpalK2jeGcatNyYhgYWglFDBCKWFsbXDdagy5FxdoKY1zxyjQ1EKiNpgfZq8k3NfR1A3GUvY0aui7d0m-ipIQJQWidwBf_gDd-E1zqTRIsWClqxhJUTNBadSCtM34MSq_BQVCdd2BsKi8w5zUSJaeJn-_h02iht3qv4PVfgsSM8H1cq02M8vTqci-rg48xgJFDsL0KW4mRvIuHTPGQv-KR2Je726moVWfSJ2sb7wUk5YOU1Z3n4cTdpsa2_zeU74_OfzvvnsTG1Om9QoUvknHKK_n5_ESuKKk_XWIq39Gf5AnYgA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>218648966</pqid></control><display><type>article</type><title>Synthetic 6FDA-ODA copolyimide membranes for gas separation and pervaporation: Correlation of separation properties with diamine monomers</title><source>Wiley Online Library All Journals</source><creator>Xiao, Shude ; Feng, Xianshe ; Huang, Robert Y.M.</creator><creatorcontrib>Xiao, Shude ; Feng, Xianshe ; Huang, Robert Y.M.</creatorcontrib><description>Copolyimides were synthesized from 4,4′‐(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and 4‐aminophenyl ether (ODA) with 4‐aminophenyl sulfone (DDS), 4,4′‐methylenedianiline (MDA), 4,4′‐bis(3‐aminophenoxy)diphenyl sulfone (BADS), 4,4′‐bis(3‐aminophenoxy) benzophenone (BABP), and 2,6‐bis(3‐aminophenoxyl) benzonitrile (DABN) as the third monomer. Surface free energies and interfacial free energies were calculated for comparison of the membrane hydrophilicity. Gas permeation was carried out with N2, O2, H2, He, and CO2, and the moiety contributions to membrane selectivity were calculated. DDS and BADS moieties contribute negatively to the selectivities toward O2/N2, H2/N2, and He/N2, and the DABN moiety is favorable for improving CO2/N2 selectivity. Water permeation and dehydration of isopropanol were performed, and the linear moiety contribution method was applied to study the effects of the monomer structures on the temperature and feed concentration dependencies of the permeation flux. The steric effects of DDS and BADS moieties, as well as the interactions of BABP and DABN moieties with water, account for the differences in pervaporation properties of the membranes. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers</description><identifier>ISSN: 0032-3888</identifier><identifier>EISSN: 1548-2634</identifier><identifier>DOI: 10.1002/pen.21007</identifier><identifier>CODEN: PYESAZ</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Carbon dioxide ; Chemical compounds ; Copolymers ; Exact sciences and technology ; Exchange resins and membranes ; Forms of application and semi-finished materials ; Materials ; Membranes (Technology) ; Molecular structure ; Nitriles ; Polymer industry, paints, wood ; Polymer processing ; Production processes ; Properties ; Technology of polymers</subject><ispartof>Polymer engineering and science, 2008-04, Vol.48 (4), p.795-805</ispartof><rights>Copyright © 2008 Society of Plastics Engineers</rights><rights>2008 INIST-CNRS</rights><rights>COPYRIGHT 2008 Society of Plastics Engineers, Inc.</rights><rights>Copyright Society of Plastics Engineers Apr 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5067-162b924dbf773cfd72f6ef358a2fe2306d9f19bccec4856d5111575fb9e2e9fc3</citedby><cites>FETCH-LOGICAL-c5067-162b924dbf773cfd72f6ef358a2fe2306d9f19bccec4856d5111575fb9e2e9fc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpen.21007$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpen.21007$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27923,27924,45573,45574</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20232453$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Xiao, Shude</creatorcontrib><creatorcontrib>Feng, Xianshe</creatorcontrib><creatorcontrib>Huang, Robert Y.M.</creatorcontrib><title>Synthetic 6FDA-ODA copolyimide membranes for gas separation and pervaporation: Correlation of separation properties with diamine monomers</title><title>Polymer engineering and science</title><addtitle>Polym Eng Sci</addtitle><description>Copolyimides were synthesized from 4,4′‐(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and 4‐aminophenyl ether (ODA) with 4‐aminophenyl sulfone (DDS), 4,4′‐methylenedianiline (MDA), 4,4′‐bis(3‐aminophenoxy)diphenyl sulfone (BADS), 4,4′‐bis(3‐aminophenoxy) benzophenone (BABP), and 2,6‐bis(3‐aminophenoxyl) benzonitrile (DABN) as the third monomer. Surface free energies and interfacial free energies were calculated for comparison of the membrane hydrophilicity. Gas permeation was carried out with N2, O2, H2, He, and CO2, and the moiety contributions to membrane selectivity were calculated. DDS and BADS moieties contribute negatively to the selectivities toward O2/N2, H2/N2, and He/N2, and the DABN moiety is favorable for improving CO2/N2 selectivity. Water permeation and dehydration of isopropanol were performed, and the linear moiety contribution method was applied to study the effects of the monomer structures on the temperature and feed concentration dependencies of the permeation flux. The steric effects of DDS and BADS moieties, as well as the interactions of BABP and DABN moieties with water, account for the differences in pervaporation properties of the membranes. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers</description><subject>Applied sciences</subject><subject>Carbon dioxide</subject><subject>Chemical compounds</subject><subject>Copolymers</subject><subject>Exact sciences and technology</subject><subject>Exchange resins and membranes</subject><subject>Forms of application and semi-finished materials</subject><subject>Materials</subject><subject>Membranes (Technology)</subject><subject>Molecular structure</subject><subject>Nitriles</subject><subject>Polymer industry, paints, wood</subject><subject>Polymer processing</subject><subject>Production processes</subject><subject>Properties</subject><subject>Technology of polymers</subject><issn>0032-3888</issn><issn>1548-2634</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNp1ks1u1DAUhSMEEkNhwRtESCCxyNQ_ie2wG820paJqUcvP0nKc66lLYgc7Q5lH4K1xyVABGuSFrevvHF_bJ8ueYzTHCJHDAdycpBV_kM1wVYqCMFo-zGYIUVJQIcTj7EmMNyixtKpn2Y-rrRuvYbQ6Z8erRXGxWuTaD77b2t62kPfQN0E5iLnxIV-rmEcYVFCj9S5Xrs0HCN_U4KfKm3zpQ4Bu2vbmT3gIPrGjTVa3drzOW6t669IJ3vkeQnyaPTKqi_BsNx9kH4-PPizfFmcXJ6fLxVmhK8R4gRlpalK2jeGcatNyYhgYWglFDBCKWFsbXDdagy5FxdoKY1zxyjQ1EKiNpgfZq8k3NfR1A3GUvY0aui7d0m-ipIQJQWidwBf_gDd-E1zqTRIsWClqxhJUTNBadSCtM34MSq_BQVCdd2BsKi8w5zUSJaeJn-_h02iht3qv4PVfgsSM8H1cq02M8vTqci-rg48xgJFDsL0KW4mRvIuHTPGQv-KR2Je726moVWfSJ2sb7wUk5YOU1Z3n4cTdpsa2_zeU74_OfzvvnsTG1Om9QoUvknHKK_n5_ESuKKk_XWIq39Gf5AnYgA</recordid><startdate>200804</startdate><enddate>200804</enddate><creator>Xiao, Shude</creator><creator>Feng, Xianshe</creator><creator>Huang, Robert Y.M.</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley Subscription Services</general><general>Society of Plastics Engineers, Inc</general><general>Blackwell Publishing Ltd</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>3V.</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8AF</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L6V</scope><scope>M2O</scope><scope>M2P</scope><scope>M7S</scope><scope>MBDVC</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>Q9U</scope><scope>S0X</scope></search><sort><creationdate>200804</creationdate><title>Synthetic 6FDA-ODA copolyimide membranes for gas separation and pervaporation: Correlation of separation properties with diamine monomers</title><author>Xiao, Shude ; Feng, Xianshe ; Huang, Robert Y.M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5067-162b924dbf773cfd72f6ef358a2fe2306d9f19bccec4856d5111575fb9e2e9fc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Applied sciences</topic><topic>Carbon dioxide</topic><topic>Chemical compounds</topic><topic>Copolymers</topic><topic>Exact sciences and technology</topic><topic>Exchange resins and membranes</topic><topic>Forms of application and semi-finished materials</topic><topic>Materials</topic><topic>Membranes (Technology)</topic><topic>Molecular structure</topic><topic>Nitriles</topic><topic>Polymer industry, paints, wood</topic><topic>Polymer processing</topic><topic>Production processes</topic><topic>Properties</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xiao, Shude</creatorcontrib><creatorcontrib>Feng, Xianshe</creatorcontrib><creatorcontrib>Huang, Robert Y.M.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>STEM Database</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Research Library</collection><collection>Science Database</collection><collection>Engineering Database</collection><collection>Research Library (Corporate)</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>ProQuest Central Basic</collection><collection>SIRS Editorial</collection><jtitle>Polymer engineering and science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xiao, Shude</au><au>Feng, Xianshe</au><au>Huang, Robert Y.M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthetic 6FDA-ODA copolyimide membranes for gas separation and pervaporation: Correlation of separation properties with diamine monomers</atitle><jtitle>Polymer engineering and science</jtitle><addtitle>Polym Eng Sci</addtitle><date>2008-04</date><risdate>2008</risdate><volume>48</volume><issue>4</issue><spage>795</spage><epage>805</epage><pages>795-805</pages><issn>0032-3888</issn><eissn>1548-2634</eissn><coden>PYESAZ</coden><abstract>Copolyimides were synthesized from 4,4′‐(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and 4‐aminophenyl ether (ODA) with 4‐aminophenyl sulfone (DDS), 4,4′‐methylenedianiline (MDA), 4,4′‐bis(3‐aminophenoxy)diphenyl sulfone (BADS), 4,4′‐bis(3‐aminophenoxy) benzophenone (BABP), and 2,6‐bis(3‐aminophenoxyl) benzonitrile (DABN) as the third monomer. Surface free energies and interfacial free energies were calculated for comparison of the membrane hydrophilicity. Gas permeation was carried out with N2, O2, H2, He, and CO2, and the moiety contributions to membrane selectivity were calculated. DDS and BADS moieties contribute negatively to the selectivities toward O2/N2, H2/N2, and He/N2, and the DABN moiety is favorable for improving CO2/N2 selectivity. Water permeation and dehydration of isopropanol were performed, and the linear moiety contribution method was applied to study the effects of the monomer structures on the temperature and feed concentration dependencies of the permeation flux. The steric effects of DDS and BADS moieties, as well as the interactions of BABP and DABN moieties with water, account for the differences in pervaporation properties of the membranes. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/pen.21007</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0032-3888 |
| ispartof | Polymer engineering and science, 2008-04, Vol.48 (4), p.795-805 |
| issn | 0032-3888 1548-2634 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_32688239 |
| source | Wiley Online Library All Journals |
| subjects | Applied sciences Carbon dioxide Chemical compounds Copolymers Exact sciences and technology Exchange resins and membranes Forms of application and semi-finished materials Materials Membranes (Technology) Molecular structure Nitriles Polymer industry, paints, wood Polymer processing Production processes Properties Technology of polymers |
| title | Synthetic 6FDA-ODA copolyimide membranes for gas separation and pervaporation: Correlation of separation properties with diamine monomers |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T06%3A54%3A21IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthetic%206FDA-ODA%20copolyimide%20membranes%20for%20gas%20separation%20and%20pervaporation:%20Correlation%20of%20separation%20properties%20with%20diamine%20monomers&rft.jtitle=Polymer%20engineering%20and%20science&rft.au=Xiao,%20Shude&rft.date=2008-04&rft.volume=48&rft.issue=4&rft.spage=795&rft.epage=805&rft.pages=795-805&rft.issn=0032-3888&rft.eissn=1548-2634&rft.coden=PYESAZ&rft_id=info:doi/10.1002/pen.21007&rft_dat=%3Cgale_proqu%3EA177908473%3C/gale_proqu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=218648966&rft_id=info:pmid/&rft_galeid=A177908473&rfr_iscdi=true |