A new multivalent cluster: synthesis, electrochemistry, solid state structure and computational studies on the iron-nickel mixed-metal nitride anions [Fe6Ni6N2(CO)24] (n=2-4)

The three clusters [Fe6Ni6N2(CO)24]n- (n=2-4) have been isolated, and their solid-state structures determined. The clusters are composed by three face-sharing octahedra, with the external ones filled by two interstitial nitride. The addition of electrons brings about swelling of the central, empty o...

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Veröffentlicht in:	Comptes rendus. Chimie 2005-11, Vol.8 (11-12), p.1850-1855
Hauptverfasser:	Pergola, Roberto Della, Bruschi, Maurizio, de Biani, Fabrizia Fabrizi, Fumagalli, Alessandro, Garlaschelli, Luigi, Laschi, Franco, Manassero, Maurio, Sansoni, Mirella, Zanello, Piero
Format:	Artikel
Sprache:	eng ; fre
Online-Zugang:	Volltext
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