A novel two-dimensional framework solid composed of nanosized molybdenum-oxide molecules: synthesis and characterization of [{Gd(H2O)5}4{Mo36(NO)4O108(H2O)16}]34H2O

A novel two-dimensional framework solid composed of nanosized molybdenum-oxide molecules: synthesis and characterization of [{Gd(H2O)5}4{Mo36(NO)4O108(H2O)16}]34H2O

Reaction of the ammonium salt of keplerate, [{(MoVI)MoVI5O21(H2O)6}12{MoV2O4CH3COO)}30]42- with Gd(NO3)3 leads to complex transformations with [{Gd(H2O)5}4{Mo36(NO)4O108(H2O)16}]*34H2O (1) as final product. According to X-ray structural data it contains anions [Mo36(NO)4O108(H2O)16]12-, cross-linked...

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Veröffentlicht in:Comptes rendus. Chimie 2005-11, Vol.8 (11-12), p.1922-1926
Hauptverfasser: Izarova, Natalia V, Sokolov, Maxim N, Dolgushin, Fedor M, Antipin, Mikhail Yu, Fenske, Dieter, Fedin, Vladimir P
Format: Artikel
Sprache:eng ; fre
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Zusammenfassung:Reaction of the ammonium salt of keplerate, [{(MoVI)MoVI5O21(H2O)6}12{MoV2O4CH3COO)}30]42- with Gd(NO3)3 leads to complex transformations with [{Gd(H2O)5}4{Mo36(NO)4O108(H2O)16}]*34H2O (1) as final product. According to X-ray structural data it contains anions [Mo36(NO)4O108(H2O)16]12-, cross-linked into a neutral 2D-framework by Gd3+ ions.
ISSN:1631-0748
DOI:10.1016/j.crci.2005.02.025