An iron-sulfur-tin cluster with amino-ligands and its reactions with thiols

The dinuclear complex Fe2(mu2-eta2-S2)(CO)6 (1) has been reacted with the bis(amino)stannylene Sn(mu-Nt-Bu)2SiMe2 (2) to form the new 1:1 complex Me2Si(mu-Nt-Bu)2SnFe2(mu3-S)2(CO)6 (4). The 'double-star'shape of its Fe2S2Sn central core (X-ray structure analysis, multinuclear NMR) contains...

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Veröffentlicht in:	Comptes rendus. Chimie 2005-01, Vol.8 (1), p.57-64
Hauptverfasser:	VEITH, Michael, AUVRAY, Nicolas, HUCH, Volker, BRAUNSTEIN, Pierre
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbonyl and nitrosyl compounds, and their complexes Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Kinetics and mechanism of reactions Physics Structure of solids and liquids crystallography Structure of specific crystalline solids
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