Electrochemical synthesis and stability of the brown six-electron reduced β- and γ-12-tungstosilicates

The electrochemical synthesis in acid aqueous solution of the brown six-electron reduced beta- and gamma-12-tungstosilicates, abbreviated VI', is described. Their mechanism of formation has been deduced from controlled potential electrolyses and polarographic analysis of the transformations. Th...

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Veröffentlicht in:Comptes rendus. Chimie 2005-06, Vol.8 (6-7), p.1011-1016
Hauptverfasser: Canny, Jacqueline, Liu, Feng-Xian, Hervé, Gilbert
Format: Artikel
Sprache:eng
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