Production of activated carbons from coffee endocarp by CO2 and steam activation

In this work the use of coffee endocarp as precursor for the production of activated carbons by steam and CO2 was studied. Activation by both methods produces activated carbons with small external areas and microporous structures having very similar mean pore widths. The activation produces mainly p...

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Veröffentlicht in:Fuel processing technology 2008-03, Vol.89 (3), p.262-268
Hauptverfasser: VALENTE NABAIS, Joao M, NUNES, Pedro, CARROTT, Peter J. M, RIBEIRO CARROTT, M. Manuela L, MACIAS GARCIA, A, DIAZ-DIEZ, M. A
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container_end_page 268
container_issue 3
container_start_page 262
container_title Fuel processing technology
container_volume 89
creator VALENTE NABAIS, Joao M
NUNES, Pedro
CARROTT, Peter J. M
RIBEIRO CARROTT, M. Manuela L
MACIAS GARCIA, A
DIAZ-DIEZ, M. A
description In this work the use of coffee endocarp as precursor for the production of activated carbons by steam and CO2 was studied. Activation by both methods produces activated carbons with small external areas and microporous structures having very similar mean pore widths. The activation produces mainly primary micropores and only a small volume of larger micropores. The CO2 activation leads to samples with higher BET surface areas and pore volumes when compared with samples produced by steam activation and with similar burn-off value. All the activated carbons produced have basic characteristics with point of zero charge between 10 and 12. By FTIR it was possible to identify the formation on the activated carbon's surface of several functional groups, namely ether, quinones, lactones, ketones, hydroxyls (free and phenol); pyrones and Si-H bonds.
doi_str_mv 10.1016/j.fuproc.2007.11.030
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subjects Applied sciences
Biomass
Energy
Exact sciences and technology
Natural energy
title Production of activated carbons from coffee endocarp by CO2 and steam activation
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