Catalytic deoxygenation of unsaturated renewable feedstocks for production of diesel fuel hydrocarbons
The liquid-phase deoxygenation reaction of unsaturated renewables has been investigated in a semi-batch reactor. The reactants examined were the monounsaturated fatty acid, oleic acid, the diunsaturated fatty acid, linoleic acid and the monounsaturated fatty acid ester, methyl oleate. The reactions...
Gespeichert in:
| Veröffentlicht in: | Fuel (Guildford) 2008-05, Vol.87 (6), p.933-945 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 945 |
|---|---|
| container_issue | 6 |
| container_start_page | 933 |
| container_title | Fuel (Guildford) |
| container_volume | 87 |
| creator | Snåre, M. Kubičková, I. Mäki-Arvela, P. Chichova, D. Eränen, K. Murzin, D.Yu |
| description | The liquid-phase deoxygenation reaction of unsaturated renewables has been investigated in a semi-batch reactor. The reactants examined were the monounsaturated fatty acid, oleic acid, the diunsaturated fatty acid, linoleic acid and the monounsaturated fatty acid ester, methyl oleate. The reactions were carried out over a Pd/C catalyst under constant pressure and temperature in the following domain, 15–27
bar and 300–360
°C, respectively. The influence of carrier gas was additionally investigated. The impact as solvent (mesitylene) was studied as well and reaction pathways were proposed. Furthermore, continuous deoxygenation experiments were conducted, facilitating understanding of the catalyst stability and catalyst deactivation. The deoxygenation catalyst was characterized by physisorption, temperature programmed desorption (TPD), thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). |
| doi_str_mv | 10.1016/j.fuel.2007.06.006 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_31981817</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0016236107002840</els_id><sourcerecordid>31981817</sourcerecordid><originalsourceid>FETCH-LOGICAL-c458t-32d9afa78748cfee821dbe8f8a7ac6ce51cc434165ee5ec0de0aa709d761b6dc3</originalsourceid><addsrcrecordid>eNqFkD1vFDEQhi1EJI6EP0DlBrpd7P2wfVIadEoIUiQaUltz4zH42KwT20ty_x6fLqFMqmme92Nexj5K0Uoh1Zdd6xea2k4I3QrVCqHesJU0um-0HPu3bCUq1XS9ku_Y-5x3ooJmHFbMb6DAtC8BuaP4uP9FM5QQZx49X-YMZUlQyPFEMz3AdiLuiVwuEf9k7mPidym6BZ8lLlCmiR_K8N97lyJC2sY5n7ETD1OmD0_3lN1cXvzcXDXXP75933y9bnAYTWn6zq3BgzZ6MFiDTCfdlow3oAEV0igRh36QaiQaCYUjAaDF2mklt8phf8o-H31rrfuFcrG3ISNNE8wUl2x7uTbSSP0qKAfRyRpVwe4IYoo5J_L2LoVbSHsrhT1sb3f28K49bG-FsnX7Kvr05A4ZYfIJZgz5v7KiptNdX7nzI0d1k7-Bks0YaEZyIREW62J4KeYflmOdpQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>14021434</pqid></control><display><type>article</type><title>Catalytic deoxygenation of unsaturated renewable feedstocks for production of diesel fuel hydrocarbons</title><source>Elsevier ScienceDirect Journals</source><creator>Snåre, M. ; Kubičková, I. ; Mäki-Arvela, P. ; Chichova, D. ; Eränen, K. ; Murzin, D.Yu</creator><creatorcontrib>Snåre, M. ; Kubičková, I. ; Mäki-Arvela, P. ; Chichova, D. ; Eränen, K. ; Murzin, D.Yu</creatorcontrib><description>The liquid-phase deoxygenation reaction of unsaturated renewables has been investigated in a semi-batch reactor. The reactants examined were the monounsaturated fatty acid, oleic acid, the diunsaturated fatty acid, linoleic acid and the monounsaturated fatty acid ester, methyl oleate. The reactions were carried out over a Pd/C catalyst under constant pressure and temperature in the following domain, 15–27
bar and 300–360
°C, respectively. The influence of carrier gas was additionally investigated. The impact as solvent (mesitylene) was studied as well and reaction pathways were proposed. Furthermore, continuous deoxygenation experiments were conducted, facilitating understanding of the catalyst stability and catalyst deactivation. The deoxygenation catalyst was characterized by physisorption, temperature programmed desorption (TPD), thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM).</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/j.fuel.2007.06.006</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Biomass ; Deoxygenation ; Diesel ; Energy ; Exact sciences and technology ; Natural energy ; Renewables</subject><ispartof>Fuel (Guildford), 2008-05, Vol.87 (6), p.933-945</ispartof><rights>2007 Elsevier Ltd</rights><rights>2008 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c458t-32d9afa78748cfee821dbe8f8a7ac6ce51cc434165ee5ec0de0aa709d761b6dc3</citedby><cites>FETCH-LOGICAL-c458t-32d9afa78748cfee821dbe8f8a7ac6ce51cc434165ee5ec0de0aa709d761b6dc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0016236107002840$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20082723$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Snåre, M.</creatorcontrib><creatorcontrib>Kubičková, I.</creatorcontrib><creatorcontrib>Mäki-Arvela, P.</creatorcontrib><creatorcontrib>Chichova, D.</creatorcontrib><creatorcontrib>Eränen, K.</creatorcontrib><creatorcontrib>Murzin, D.Yu</creatorcontrib><title>Catalytic deoxygenation of unsaturated renewable feedstocks for production of diesel fuel hydrocarbons</title><title>Fuel (Guildford)</title><description>The liquid-phase deoxygenation reaction of unsaturated renewables has been investigated in a semi-batch reactor. The reactants examined were the monounsaturated fatty acid, oleic acid, the diunsaturated fatty acid, linoleic acid and the monounsaturated fatty acid ester, methyl oleate. The reactions were carried out over a Pd/C catalyst under constant pressure and temperature in the following domain, 15–27
bar and 300–360
°C, respectively. The influence of carrier gas was additionally investigated. The impact as solvent (mesitylene) was studied as well and reaction pathways were proposed. Furthermore, continuous deoxygenation experiments were conducted, facilitating understanding of the catalyst stability and catalyst deactivation. The deoxygenation catalyst was characterized by physisorption, temperature programmed desorption (TPD), thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM).</description><subject>Applied sciences</subject><subject>Biomass</subject><subject>Deoxygenation</subject><subject>Diesel</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Natural energy</subject><subject>Renewables</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkD1vFDEQhi1EJI6EP0DlBrpd7P2wfVIadEoIUiQaUltz4zH42KwT20ty_x6fLqFMqmme92Nexj5K0Uoh1Zdd6xea2k4I3QrVCqHesJU0um-0HPu3bCUq1XS9ku_Y-5x3ooJmHFbMb6DAtC8BuaP4uP9FM5QQZx49X-YMZUlQyPFEMz3AdiLuiVwuEf9k7mPidym6BZ8lLlCmiR_K8N97lyJC2sY5n7ETD1OmD0_3lN1cXvzcXDXXP75933y9bnAYTWn6zq3BgzZ6MFiDTCfdlow3oAEV0igRh36QaiQaCYUjAaDF2mklt8phf8o-H31rrfuFcrG3ISNNE8wUl2x7uTbSSP0qKAfRyRpVwe4IYoo5J_L2LoVbSHsrhT1sb3f28K49bG-FsnX7Kvr05A4ZYfIJZgz5v7KiptNdX7nzI0d1k7-Bks0YaEZyIREW62J4KeYflmOdpQ</recordid><startdate>20080501</startdate><enddate>20080501</enddate><creator>Snåre, M.</creator><creator>Kubičková, I.</creator><creator>Mäki-Arvela, P.</creator><creator>Chichova, D.</creator><creator>Eränen, K.</creator><creator>Murzin, D.Yu</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7TB</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20080501</creationdate><title>Catalytic deoxygenation of unsaturated renewable feedstocks for production of diesel fuel hydrocarbons</title><author>Snåre, M. ; Kubičková, I. ; Mäki-Arvela, P. ; Chichova, D. ; Eränen, K. ; Murzin, D.Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c458t-32d9afa78748cfee821dbe8f8a7ac6ce51cc434165ee5ec0de0aa709d761b6dc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Applied sciences</topic><topic>Biomass</topic><topic>Deoxygenation</topic><topic>Diesel</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Natural energy</topic><topic>Renewables</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Snåre, M.</creatorcontrib><creatorcontrib>Kubičková, I.</creatorcontrib><creatorcontrib>Mäki-Arvela, P.</creatorcontrib><creatorcontrib>Chichova, D.</creatorcontrib><creatorcontrib>Eränen, K.</creatorcontrib><creatorcontrib>Murzin, D.Yu</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Fuel (Guildford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Snåre, M.</au><au>Kubičková, I.</au><au>Mäki-Arvela, P.</au><au>Chichova, D.</au><au>Eränen, K.</au><au>Murzin, D.Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic deoxygenation of unsaturated renewable feedstocks for production of diesel fuel hydrocarbons</atitle><jtitle>Fuel (Guildford)</jtitle><date>2008-05-01</date><risdate>2008</risdate><volume>87</volume><issue>6</issue><spage>933</spage><epage>945</epage><pages>933-945</pages><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>The liquid-phase deoxygenation reaction of unsaturated renewables has been investigated in a semi-batch reactor. The reactants examined were the monounsaturated fatty acid, oleic acid, the diunsaturated fatty acid, linoleic acid and the monounsaturated fatty acid ester, methyl oleate. The reactions were carried out over a Pd/C catalyst under constant pressure and temperature in the following domain, 15–27
bar and 300–360
°C, respectively. The influence of carrier gas was additionally investigated. The impact as solvent (mesitylene) was studied as well and reaction pathways were proposed. Furthermore, continuous deoxygenation experiments were conducted, facilitating understanding of the catalyst stability and catalyst deactivation. The deoxygenation catalyst was characterized by physisorption, temperature programmed desorption (TPD), thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM).</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.fuel.2007.06.006</doi><tpages>13</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0016-2361 |
| ispartof | Fuel (Guildford), 2008-05, Vol.87 (6), p.933-945 |
| issn | 0016-2361 1873-7153 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_31981817 |
| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Biomass Deoxygenation Diesel Energy Exact sciences and technology Natural energy Renewables |
| title | Catalytic deoxygenation of unsaturated renewable feedstocks for production of diesel fuel hydrocarbons |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T14%3A50%3A35IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Catalytic%20deoxygenation%20of%20unsaturated%20renewable%20feedstocks%20for%20production%20of%20diesel%20fuel%20hydrocarbons&rft.jtitle=Fuel%20(Guildford)&rft.au=Sn%C3%A5re,%20M.&rft.date=2008-05-01&rft.volume=87&rft.issue=6&rft.spage=933&rft.epage=945&rft.pages=933-945&rft.issn=0016-2361&rft.eissn=1873-7153&rft_id=info:doi/10.1016/j.fuel.2007.06.006&rft_dat=%3Cproquest_cross%3E31981817%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=14021434&rft_id=info:pmid/&rft_els_id=S0016236107002840&rfr_iscdi=true |