Atom transfer radical polymerization of methyl methacrylate catalyzed by ion exchange resin immobilized Co(II) hybrid catalyst
Ion exchange resin immobilized Co(II) catalyst with a small amount of soluble CuCl₂/Me₆TREN catalyst was successfully applied to atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) in DMF. Using this catalyst, a high conversion of MMA (>90%) was achieved. And poly(methyl meth...
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| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2008-02, Vol.46 (4), p.1416-1426 |
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| container_end_page | 1426 |
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| container_issue | 4 |
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| container_title | Journal of polymer science. Part A, Polymer chemistry |
| container_volume | 46 |
| creator | Huang, Zhong Xi Zhang, Yong Ming Li, Hong Luan, Ying Hao Liu, Yan Gang |
| description | Ion exchange resin immobilized Co(II) catalyst with a small amount of soluble CuCl₂/Me₆TREN catalyst was successfully applied to atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) in DMF. Using this catalyst, a high conversion of MMA (>90%) was achieved. And poly(methyl methacrylate) (PMMA) with predicted molecular weight and narrow molecular weight distribution (Mw/Mn = 1.09-1.42) was obtained. The immobilized catalyst can be easily separated from the polymerization system by simple centrifugation after polymerization, resulting in the concentration of transition metal residues in polymer product was as low as 10 ppm. Both main catalytic activity and good controllability over the polymerization were retained by the recycled catalyst without any regeneration process. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1416-1426, 2008 |
| doi_str_mv | 10.1002/pola.22481 |
| format | Article |
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Using this catalyst, a high conversion of MMA (>90%) was achieved. And poly(methyl methacrylate) (PMMA) with predicted molecular weight and narrow molecular weight distribution (Mw/Mn = 1.09-1.42) was obtained. The immobilized catalyst can be easily separated from the polymerization system by simple centrifugation after polymerization, resulting in the concentration of transition metal residues in polymer product was as low as 10 ppm. Both main catalytic activity and good controllability over the polymerization were retained by the recycled catalyst without any regeneration process. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1416-1426, 2008</description><identifier>ISSN: 0887-624X</identifier><identifier>EISSN: 1099-0518</identifier><identifier>DOI: 10.1002/pola.22481</identifier><identifier>CODEN: JPLCAT</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; atom transfer radical polymerization (ATRP) ; cobalt catalyst ; controlled radical polymerization (CRP) ; Exact sciences and technology ; Exchange resins and membranes ; Forms of application and semi-finished materials ; immobilized catalyst ; ion exchange resin ; living polymerization ; Organic polymers ; Physicochemistry of polymers ; Polymer industry, paints, wood ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Properties and characterization ; radical polymerization ; Special properties (catalyst, reagent or carrier) ; Technology of polymers</subject><ispartof>Journal of polymer science. 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Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><description>Ion exchange resin immobilized Co(II) catalyst with a small amount of soluble CuCl₂/Me₆TREN catalyst was successfully applied to atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) in DMF. Using this catalyst, a high conversion of MMA (>90%) was achieved. And poly(methyl methacrylate) (PMMA) with predicted molecular weight and narrow molecular weight distribution (Mw/Mn = 1.09-1.42) was obtained. The immobilized catalyst can be easily separated from the polymerization system by simple centrifugation after polymerization, resulting in the concentration of transition metal residues in polymer product was as low as 10 ppm. Both main catalytic activity and good controllability over the polymerization were retained by the recycled catalyst without any regeneration process. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1416-1426, 2008</description><subject>Applied sciences</subject><subject>atom transfer radical polymerization (ATRP)</subject><subject>cobalt catalyst</subject><subject>controlled radical polymerization (CRP)</subject><subject>Exact sciences and technology</subject><subject>Exchange resins and membranes</subject><subject>Forms of application and semi-finished materials</subject><subject>immobilized catalyst</subject><subject>ion exchange resin</subject><subject>living polymerization</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymer industry, paints, wood</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Properties and characterization</subject><subject>radical polymerization</subject><subject>Special properties (catalyst, reagent or carrier)</subject><subject>Technology of polymers</subject><issn>0887-624X</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kF1rFDEUhoNYcG298Q-YG6UKU_MxH5nLZdHtwmr92FLxJiSZM91oZrImU-z0wt9utrP2UjhwOOR5H8KL0HNKzigh7O3OO3XGWC7oIzSjpK4zUlDxGM2IEFVWsvzbE_Q0xh-EpLdCzNCf-eA7PATVxxYCDqqxRjmcPGMHwd6pwfoe-xZ3MGxHd7-UCaNTA2CjBuXGO2iwHvGeg1uzVf014ADR9th2ndfW2T2x8Ker1Wu8HXWwzSEZhxN01CoX4dlhH6PL9-82i_NsfbFcLebrzPC6pJmuDW8LpuqqpBRYw5ucUsYFaEKgLArScG0417mo08Vp3orcGA2M6kbwNMfo1eTdBf_rBuIgOxsNOKd68DdRclonH-UJfDOBJvgYA7RyF2ynwigpkfuK5b5ieV9xgl8erCqm1trUorHxIcFSyxWt6sTRifttHYz_McpPF-v5P3c2ZWwc4PYho8JPWVa8KuTVx6X8fLX5cr75vpQfEv9i4lvlpboO6R-XXxmhnBCRF4JU_C-WjqYZ</recordid><startdate>20080215</startdate><enddate>20080215</enddate><creator>Huang, Zhong Xi</creator><creator>Zhang, Yong Ming</creator><creator>Li, Hong</creator><creator>Luan, Ying Hao</creator><creator>Liu, Yan Gang</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20080215</creationdate><title>Atom transfer radical polymerization of methyl methacrylate catalyzed by ion exchange resin immobilized Co(II) hybrid catalyst</title><author>Huang, Zhong Xi ; Zhang, Yong Ming ; Li, Hong ; Luan, Ying Hao ; Liu, Yan Gang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3961-b9c3f52a97611e2d3d411238eb00e6550d3bc33b489655314f84ccbe21bd83d83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Applied sciences</topic><topic>atom transfer radical polymerization (ATRP)</topic><topic>cobalt catalyst</topic><topic>controlled radical polymerization (CRP)</topic><topic>Exact sciences and technology</topic><topic>Exchange resins and membranes</topic><topic>Forms of application and semi-finished materials</topic><topic>immobilized catalyst</topic><topic>ion exchange resin</topic><topic>living polymerization</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymer industry, paints, wood</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Properties and characterization</topic><topic>radical polymerization</topic><topic>Special properties (catalyst, reagent or carrier)</topic><topic>Technology of polymers</topic><toplevel>online_resources</toplevel><creatorcontrib>Huang, Zhong Xi</creatorcontrib><creatorcontrib>Zhang, Yong Ming</creatorcontrib><creatorcontrib>Li, Hong</creatorcontrib><creatorcontrib>Luan, Ying Hao</creatorcontrib><creatorcontrib>Liu, Yan Gang</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Zhong Xi</au><au>Zhang, Yong Ming</au><au>Li, Hong</au><au>Luan, Ying Hao</au><au>Liu, Yan Gang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Atom transfer radical polymerization of methyl methacrylate catalyzed by ion exchange resin immobilized Co(II) hybrid catalyst</atitle><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><date>2008-02-15</date><risdate>2008</risdate><volume>46</volume><issue>4</issue><spage>1416</spage><epage>1426</epage><pages>1416-1426</pages><issn>0887-624X</issn><eissn>1099-0518</eissn><coden>JPLCAT</coden><abstract>Ion exchange resin immobilized Co(II) catalyst with a small amount of soluble CuCl₂/Me₆TREN catalyst was successfully applied to atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) in DMF. Using this catalyst, a high conversion of MMA (>90%) was achieved. And poly(methyl methacrylate) (PMMA) with predicted molecular weight and narrow molecular weight distribution (Mw/Mn = 1.09-1.42) was obtained. The immobilized catalyst can be easily separated from the polymerization system by simple centrifugation after polymerization, resulting in the concentration of transition metal residues in polymer product was as low as 10 ppm. Both main catalytic activity and good controllability over the polymerization were retained by the recycled catalyst without any regeneration process. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1416-1426, 2008</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/pola.22481</doi><tpages>11</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences atom transfer radical polymerization (ATRP) cobalt catalyst controlled radical polymerization (CRP) Exact sciences and technology Exchange resins and membranes Forms of application and semi-finished materials immobilized catalyst ion exchange resin living polymerization Organic polymers Physicochemistry of polymers Polymer industry, paints, wood Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Properties and characterization radical polymerization Special properties (catalyst, reagent or carrier) Technology of polymers |
| title | Atom transfer radical polymerization of methyl methacrylate catalyzed by ion exchange resin immobilized Co(II) hybrid catalyst |
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