Structure of waxy crude oil emulsion gels

The phase separation of paraffinic solids from crude oil constitutes a major operating issue for the petroleum industry, in view of the fact that the association of wax crystals into a disordered spanning network can lead to severe flow assurance problems. Although the presence of water in crude oil...

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Veröffentlicht in:Journal of non-Newtonian fluid mechanics 2008-02, Vol.149 (1), p.34-39
Hauptverfasser: Visintin, Ruben F.G., Lockhart, Thomas P., Lapasin, Romano, D’Antona, Paolo
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container_end_page 39
container_issue 1
container_start_page 34
container_title Journal of non-Newtonian fluid mechanics
container_volume 149
creator Visintin, Ruben F.G.
Lockhart, Thomas P.
Lapasin, Romano
D’Antona, Paolo
description The phase separation of paraffinic solids from crude oil constitutes a major operating issue for the petroleum industry, in view of the fact that the association of wax crystals into a disordered spanning network can lead to severe flow assurance problems. Although the presence of water in crude oil is quite common, its impact on waxy crude oil gelation and rheology has not received much more attention in the literature. In this study, we show that the presence of water above a threshold value can greatly enhance gel formation, changing both the pour point temperature and the yield strength. The rheological characteristics of crude oils are examined both above and below the gel point and a qualitative interpretation of the structure of waxy crude oil gels in the presence of water is proposed. The results suggest that the impact of emulsified water on pour point and gel rheology needs to be added to the standard tests conducted on crude oils during field development studies, particularly for those offshore developments with multiphase production.
doi_str_mv 10.1016/j.jnnfm.2007.07.008
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source Elsevier ScienceDirect Journals
subjects Applied sciences
Crude oil, natural gas and petroleum products
Crude oil, natural gas, oil shales producing equipements and methods
Emulsion
Energy
Exact sciences and technology
Fuels
Gel
Processing of crude oil and oils from shales and tar sands. Processes. Equipment. Refinery and treatment units
Prospecting and production of crude oil, natural gas, oil shales and tar sands
Rheology
Waxy crude oil
title Structure of waxy crude oil emulsion gels
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