Mechanism of the coupled 24-electron reduction and transformations among the “blues”, the “browns” and the “reds” of ammonium metatungstate

The complete mechanistic pathway for the 24-electron redox behavior of the metatungstate anion has been determined through the simulation of cyclic voltammetry data in low pH electrolytes. After the electrochemical reduction by up to four electrons, forming the “tungsten-blues”, coupled chemical and...

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Veröffentlicht in:	Electrochimica acta 2008-02, Vol.53 (6), p.2994-3001
Hauptverfasser:	Smith, Sean P.E., Christian, Joel B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Cyclic voltammetry Electrochemistry Exact sciences and technology General and physical chemistry Isopoly Kinetics and mechanism of reactions Polyoxometalates POM Simulation Tungsten oxide
Online-Zugang:	Volltext
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