Electrophosphorescence from iridium complex-doped mesogen-jacketed polymers

A mesogen-jacketed polymer P-Ct {poly{2,5-bis[(5-tert-butylphenyl)-1,3,4-oxadiazole]styrene}} has been investigated as a host material for IrMDPP [Ir(III)bis(5-methyl-2,3-diphenylpyrazine) (acetyl acetonate)] doped polymer electrophosphorescent device. It was found that the device with P-Ct was more...

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Veröffentlicht in:Polymer (Guilford) 2008-01, Vol.49 (2), p.455-460
Hauptverfasser: Wang, Ping, Chuai, Yutao, Chai, Chunpeng, Wang, Fuzhi, Zhang, Guolin, Ge, Guoping, Fan, Xinghe, Guo, Haiqing, Zou, Dechun, Zhou, Qifeng
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container_end_page 460
container_issue 2
container_start_page 455
container_title Polymer (Guilford)
container_volume 49
creator Wang, Ping
Chuai, Yutao
Chai, Chunpeng
Wang, Fuzhi
Zhang, Guolin
Ge, Guoping
Fan, Xinghe
Guo, Haiqing
Zou, Dechun
Zhou, Qifeng
description A mesogen-jacketed polymer P-Ct {poly{2,5-bis[(5-tert-butylphenyl)-1,3,4-oxadiazole]styrene}} has been investigated as a host material for IrMDPP [Ir(III)bis(5-methyl-2,3-diphenylpyrazine) (acetyl acetonate)] doped polymer electrophosphorescent device. It was found that the device with P-Ct was more efficient than that with PVK. The maximum luminance and external luminous efficiency can reach 3702cd/m2 and 0.83cd/A, respectively, which were higher than those of device with PVK (1999cd/m2 and 0.68cd/A), which can be partly explained by the more balanced carrier injection and transportation and longer lifetime of excitons in P-Ct–TPD–IrMDPP. It was also found that as the IrMDPP content increased in P-Ct–TPD, the EL spectra color shifts from green-yellow to yellow-orange and were different from PL spectra, which was partly due to the dominating role of direct charge-trapping and recombination in the EL process over the energy-transfer routes.
doi_str_mv 10.1016/j.polymer.2007.11.047
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It was found that the device with P-Ct was more efficient than that with PVK. The maximum luminance and external luminous efficiency can reach 3702cd/m2 and 0.83cd/A, respectively, which were higher than those of device with PVK (1999cd/m2 and 0.68cd/A), which can be partly explained by the more balanced carrier injection and transportation and longer lifetime of excitons in P-Ct–TPD–IrMDPP. It was also found that as the IrMDPP content increased in P-Ct–TPD, the EL spectra color shifts from green-yellow to yellow-orange and were different from PL spectra, which was partly due to the dominating role of direct charge-trapping and recombination in the EL process over the energy-transfer routes.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/j.polymer.2007.11.047</identifier><identifier>CODEN: POLMAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Electrical, magnetic and optical properties ; Electronics ; Electrophosphorescence ; Exact sciences and technology ; Iridium complex ; Mesogen-jacketed polymers ; Optoelectronic devices ; Organic polymers ; Physicochemistry of polymers ; Properties and characterization ; Semiconductor electronics. Microelectronics. Optoelectronics. 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It was also found that as the IrMDPP content increased in P-Ct–TPD, the EL spectra color shifts from green-yellow to yellow-orange and were different from PL spectra, which was partly due to the dominating role of direct charge-trapping and recombination in the EL process over the energy-transfer routes.</description><subject>Applied sciences</subject><subject>Electrical, magnetic and optical properties</subject><subject>Electronics</subject><subject>Electrophosphorescence</subject><subject>Exact sciences and technology</subject><subject>Iridium complex</subject><subject>Mesogen-jacketed polymers</subject><subject>Optoelectronic devices</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Semiconductor electronics. Microelectronics. Optoelectronics. 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subjects Applied sciences
Electrical, magnetic and optical properties
Electronics
Electrophosphorescence
Exact sciences and technology
Iridium complex
Mesogen-jacketed polymers
Optoelectronic devices
Organic polymers
Physicochemistry of polymers
Properties and characterization
Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices
title Electrophosphorescence from iridium complex-doped mesogen-jacketed polymers
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