Bis-Cycloruthenated Complexes in Visible Light-Induced C–H Alkylation with Epoxides

Bis-cycloruthenated complexes (BCRCs) of the type [Ru­(N^C)2L2] are proposed to be key reactive intermediates in the Ru­(II)-catalyzed directed C–H functionalization of arenes. While the exceptional ground state reactivity of BCRCs toward a number of electrophiles has been explored, their reactivity...

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Veröffentlicht in:Journal of the American Chemical Society 2025-02, Vol.147 (6), p.5035-5042
Hauptverfasser: Bentley, Kurt, Hareram, Mishra Deepak, Wang, Gang-Wei, Millman, Alexander A. V., Perez-Ortega, Ignacio, Nichols, Luke M., Bories, Cassandre C., Walker, Lauren E., Woodward, Adam W., Golovanov, Alexander P., Natrajan, Louise S., Larrosa, Igor
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Sprache:eng
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