Breakdown of the Kasha-Vavilov's rule in low-symmetry porphyrazines: Ultrafast intersystem crossing via high vibronic state

Recently (Photochem Photobiol. 2023;100:1277-1289. doi:10.1111/php.13898), we described the anti-Kasha effect in tribenzo-6H-1,4-diazepinoporphyrazins with C symmetry, where the ultrafast spin changes successfully compete with the internal conversion. In this study, we show the presence of this effe...

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Veröffentlicht in:	Photochemistry and photobiology 2025-01
Hauptverfasser:	Tarakanov, Pavel A, Kozlov, Alexei V, Simakov, Anton O, Goryachev, Nikolay S, Pushkarev, Victor E
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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