BaNb2O6 at Room Temperature by Ball Milling Method: Structural, Optical, Morphology, and Electrochemistry Properties

Materials that depend on high temperature, pressure, or long periods of crystallization in the obtention of the pure phase have been the focus of several studies due to the economic and ecological aspects. The high-energy ball milling method (HEBM) has been adopted to synthesize different materials...

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Veröffentlicht in:Industrial & engineering chemistry research 2024-11, Vol.63 (46), p.20020-20033
Hauptverfasser: Nascimento, José Fábio de Lima, Leyet Ruiz, Yurimiler, da Cunha Mendes, Otoniel, Batista, Francisco Marcos Costa, Cabot, Andreu, Matos, José Milton Elias de, Ferreira, Robson Dantas, Botelho do Nascimento, Marcus Valério, Saraiva, Libertalamar Bilhalva, Quaresma, João Nazareno Nonato, Nobre, Francisco Xavier
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container_end_page 20033
container_issue 46
container_start_page 20020
container_title Industrial & engineering chemistry research
container_volume 63
creator Nascimento, José Fábio de Lima
Leyet Ruiz, Yurimiler
da Cunha Mendes, Otoniel
Batista, Francisco Marcos Costa
Cabot, Andreu
Matos, José Milton Elias de
Ferreira, Robson Dantas
Botelho do Nascimento, Marcus Valério
Saraiva, Libertalamar Bilhalva
Quaresma, João Nazareno Nonato
Nobre, Francisco Xavier
description Materials that depend on high temperature, pressure, or long periods of crystallization in the obtention of the pure phase have been the focus of several studies due to the economic and ecological aspects. The high-energy ball milling method (HEBM) has been adopted to synthesize different materials using solid-state reactions. In this study, bare barium niobate was efficiently synthesized at room temperature using the HEBM. The materials synthesized at different synthesis times were characterized by X-ray diffraction (XRD) and Rietveld refinement, which confirms the orthorhombic structure for BaNb2O6, with a high crystallinity degree at 3 h (BaNb_3) and 4 h (BaNb_4) of synthesis. The main vibrational modes of the structure were identified by Raman spectroscopy. In contrast, band-gap values between 3.77 and 3.84 eV were obtained by diffuse reflectance spectroscopy for the samples BaNb_3 and BaNb_4, respectively. The electrochemical experiments using the modified glassy carbon electrode (GCE) with BaNb_3 sample as a working electrode show the almost reversible profile for the cyclic voltammetry curves in potassium ferrocyanide in the scanning speed range of 1 to 100 mV s–1. Moreover, the flat band energy (E fb) indicates the p-type semiconductor characteristic for BaNb2O6, and a specific capacitance of 3375.66 mF cm–2, suggesting an interesting material for composition n–p heterojunctions.
doi_str_mv 10.1021/acs.iecr.4c02578
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The high-energy ball milling method (HEBM) has been adopted to synthesize different materials using solid-state reactions. In this study, bare barium niobate was efficiently synthesized at room temperature using the HEBM. The materials synthesized at different synthesis times were characterized by X-ray diffraction (XRD) and Rietveld refinement, which confirms the orthorhombic structure for BaNb2O6, with a high crystallinity degree at 3 h (BaNb_3) and 4 h (BaNb_4) of synthesis. The main vibrational modes of the structure were identified by Raman spectroscopy. In contrast, band-gap values between 3.77 and 3.84 eV were obtained by diffuse reflectance spectroscopy for the samples BaNb_3 and BaNb_4, respectively. The electrochemical experiments using the modified glassy carbon electrode (GCE) with BaNb_3 sample as a working electrode show the almost reversible profile for the cyclic voltammetry curves in potassium ferrocyanide in the scanning speed range of 1 to 100 mV s–1. 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The electrochemical experiments using the modified glassy carbon electrode (GCE) with BaNb_3 sample as a working electrode show the almost reversible profile for the cyclic voltammetry curves in potassium ferrocyanide in the scanning speed range of 1 to 100 mV s–1. 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Eng. Chem. Res</addtitle><date>2024-11-08</date><risdate>2024</risdate><volume>63</volume><issue>46</issue><spage>20020</spage><epage>20033</epage><pages>20020-20033</pages><issn>0888-5885</issn><issn>1520-5045</issn><eissn>1520-5045</eissn><abstract>Materials that depend on high temperature, pressure, or long periods of crystallization in the obtention of the pure phase have been the focus of several studies due to the economic and ecological aspects. The high-energy ball milling method (HEBM) has been adopted to synthesize different materials using solid-state reactions. In this study, bare barium niobate was efficiently synthesized at room temperature using the HEBM. The materials synthesized at different synthesis times were characterized by X-ray diffraction (XRD) and Rietveld refinement, which confirms the orthorhombic structure for BaNb2O6, with a high crystallinity degree at 3 h (BaNb_3) and 4 h (BaNb_4) of synthesis. 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subjects ambient temperature
Applied Chemistry
barium
capacitance
crystal structure
crystallization
electrochemistry
energy
glassy carbon electrode
potassium
Raman spectroscopy
reflectance spectroscopy
semiconductors
voltammetry
X-ray diffraction
title BaNb2O6 at Room Temperature by Ball Milling Method: Structural, Optical, Morphology, and Electrochemistry Properties
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