BaNb2O6 at Room Temperature by Ball Milling Method: Structural, Optical, Morphology, and Electrochemistry Properties
Materials that depend on high temperature, pressure, or long periods of crystallization in the obtention of the pure phase have been the focus of several studies due to the economic and ecological aspects. The high-energy ball milling method (HEBM) has been adopted to synthesize different materials...
Gespeichert in:
Veröffentlicht in: | Industrial & engineering chemistry research 2024-11, Vol.63 (46), p.20020-20033 |
---|---|
Hauptverfasser: | , , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 20033 |
---|---|
container_issue | 46 |
container_start_page | 20020 |
container_title | Industrial & engineering chemistry research |
container_volume | 63 |
creator | Nascimento, José Fábio de Lima Leyet Ruiz, Yurimiler da Cunha Mendes, Otoniel Batista, Francisco Marcos Costa Cabot, Andreu Matos, José Milton Elias de Ferreira, Robson Dantas Botelho do Nascimento, Marcus Valério Saraiva, Libertalamar Bilhalva Quaresma, João Nazareno Nonato Nobre, Francisco Xavier |
description | Materials that depend on high temperature, pressure, or long periods of crystallization in the obtention of the pure phase have been the focus of several studies due to the economic and ecological aspects. The high-energy ball milling method (HEBM) has been adopted to synthesize different materials using solid-state reactions. In this study, bare barium niobate was efficiently synthesized at room temperature using the HEBM. The materials synthesized at different synthesis times were characterized by X-ray diffraction (XRD) and Rietveld refinement, which confirms the orthorhombic structure for BaNb2O6, with a high crystallinity degree at 3 h (BaNb_3) and 4 h (BaNb_4) of synthesis. The main vibrational modes of the structure were identified by Raman spectroscopy. In contrast, band-gap values between 3.77 and 3.84 eV were obtained by diffuse reflectance spectroscopy for the samples BaNb_3 and BaNb_4, respectively. The electrochemical experiments using the modified glassy carbon electrode (GCE) with BaNb_3 sample as a working electrode show the almost reversible profile for the cyclic voltammetry curves in potassium ferrocyanide in the scanning speed range of 1 to 100 mV s–1. Moreover, the flat band energy (E fb) indicates the p-type semiconductor characteristic for BaNb2O6, and a specific capacitance of 3375.66 mF cm–2, suggesting an interesting material for composition n–p heterojunctions. |
doi_str_mv | 10.1021/acs.iecr.4c02578 |
format | Article |
fullrecord | <record><control><sourceid>proquest_acs_j</sourceid><recordid>TN_cdi_proquest_miscellaneous_3154179252</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3154179252</sourcerecordid><originalsourceid>FETCH-LOGICAL-a197t-d8e22f24fdbd10398a770ebda398b95a9d5abcd69f296954710cf454c87843413</originalsourceid><addsrcrecordid>eNotkM9PwyAYhonRxDm9e-ToYZ1AYQVvbpk_ks0ZneeGAt26sFKBHvbfS-NO35svT968eQC4x2iKEcGPUoVpY5SfUoUIK_gFGGFGUMYQZZdghDjnGeOcXYObEA4IIcYoHYE4lx8V2cygjPDLuSPcmmNnvIy9N7A6wbm0Fq4ba5t2B9cm7p1-gt_R9yoR0k7gpouNGsLa-W7vrNudJlC2Gi6tUdE7tTfHJkR_gp_epebYmHALrmppg7k73zH4eVluF2_ZavP6vnheZRKLImaaG0JqQmtdaYxywWVRIFNpmWIlmBSayUrpmaiJmAlGC4xUTRlVvOA0pzgfg4f_3s67396EWKYpylgrW-P6UOaYUVwIwkhCJ_9o8lgeXO_bNKzEqBzklsNzkFue5eZ_uf9vYA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3154179252</pqid></control><display><type>article</type><title>BaNb2O6 at Room Temperature by Ball Milling Method: Structural, Optical, Morphology, and Electrochemistry Properties</title><source>ACS Publications</source><creator>Nascimento, José Fábio de Lima ; Leyet Ruiz, Yurimiler ; da Cunha Mendes, Otoniel ; Batista, Francisco Marcos Costa ; Cabot, Andreu ; Matos, José Milton Elias de ; Ferreira, Robson Dantas ; Botelho do Nascimento, Marcus Valério ; Saraiva, Libertalamar Bilhalva ; Quaresma, João Nazareno Nonato ; Nobre, Francisco Xavier</creator><creatorcontrib>Nascimento, José Fábio de Lima ; Leyet Ruiz, Yurimiler ; da Cunha Mendes, Otoniel ; Batista, Francisco Marcos Costa ; Cabot, Andreu ; Matos, José Milton Elias de ; Ferreira, Robson Dantas ; Botelho do Nascimento, Marcus Valério ; Saraiva, Libertalamar Bilhalva ; Quaresma, João Nazareno Nonato ; Nobre, Francisco Xavier</creatorcontrib><description>Materials that depend on high temperature, pressure, or long periods of crystallization in the obtention of the pure phase have been the focus of several studies due to the economic and ecological aspects. The high-energy ball milling method (HEBM) has been adopted to synthesize different materials using solid-state reactions. In this study, bare barium niobate was efficiently synthesized at room temperature using the HEBM. The materials synthesized at different synthesis times were characterized by X-ray diffraction (XRD) and Rietveld refinement, which confirms the orthorhombic structure for BaNb2O6, with a high crystallinity degree at 3 h (BaNb_3) and 4 h (BaNb_4) of synthesis. The main vibrational modes of the structure were identified by Raman spectroscopy. In contrast, band-gap values between 3.77 and 3.84 eV were obtained by diffuse reflectance spectroscopy for the samples BaNb_3 and BaNb_4, respectively. The electrochemical experiments using the modified glassy carbon electrode (GCE) with BaNb_3 sample as a working electrode show the almost reversible profile for the cyclic voltammetry curves in potassium ferrocyanide in the scanning speed range of 1 to 100 mV s–1. Moreover, the flat band energy (E fb) indicates the p-type semiconductor characteristic for BaNb2O6, and a specific capacitance of 3375.66 mF cm–2, suggesting an interesting material for composition n–p heterojunctions.</description><identifier>ISSN: 0888-5885</identifier><identifier>ISSN: 1520-5045</identifier><identifier>EISSN: 1520-5045</identifier><identifier>DOI: 10.1021/acs.iecr.4c02578</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>ambient temperature ; Applied Chemistry ; barium ; capacitance ; crystal structure ; crystallization ; electrochemistry ; energy ; glassy carbon electrode ; potassium ; Raman spectroscopy ; reflectance spectroscopy ; semiconductors ; voltammetry ; X-ray diffraction</subject><ispartof>Industrial & engineering chemistry research, 2024-11, Vol.63 (46), p.20020-20033</ispartof><rights>2024 The Authors. Published by American Chemical Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0003-3476-399X ; 0000-0002-5774-5391 ; 0000-0002-7533-3251 ; 0000-0002-5376-5643 ; 0000-0002-0883-3651 ; 0000-0001-9365-7498</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.iecr.4c02578$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.iecr.4c02578$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Nascimento, José Fábio de Lima</creatorcontrib><creatorcontrib>Leyet Ruiz, Yurimiler</creatorcontrib><creatorcontrib>da Cunha Mendes, Otoniel</creatorcontrib><creatorcontrib>Batista, Francisco Marcos Costa</creatorcontrib><creatorcontrib>Cabot, Andreu</creatorcontrib><creatorcontrib>Matos, José Milton Elias de</creatorcontrib><creatorcontrib>Ferreira, Robson Dantas</creatorcontrib><creatorcontrib>Botelho do Nascimento, Marcus Valério</creatorcontrib><creatorcontrib>Saraiva, Libertalamar Bilhalva</creatorcontrib><creatorcontrib>Quaresma, João Nazareno Nonato</creatorcontrib><creatorcontrib>Nobre, Francisco Xavier</creatorcontrib><title>BaNb2O6 at Room Temperature by Ball Milling Method: Structural, Optical, Morphology, and Electrochemistry Properties</title><title>Industrial & engineering chemistry research</title><addtitle>Ind. Eng. Chem. Res</addtitle><description>Materials that depend on high temperature, pressure, or long periods of crystallization in the obtention of the pure phase have been the focus of several studies due to the economic and ecological aspects. The high-energy ball milling method (HEBM) has been adopted to synthesize different materials using solid-state reactions. In this study, bare barium niobate was efficiently synthesized at room temperature using the HEBM. The materials synthesized at different synthesis times were characterized by X-ray diffraction (XRD) and Rietveld refinement, which confirms the orthorhombic structure for BaNb2O6, with a high crystallinity degree at 3 h (BaNb_3) and 4 h (BaNb_4) of synthesis. The main vibrational modes of the structure were identified by Raman spectroscopy. In contrast, band-gap values between 3.77 and 3.84 eV were obtained by diffuse reflectance spectroscopy for the samples BaNb_3 and BaNb_4, respectively. The electrochemical experiments using the modified glassy carbon electrode (GCE) with BaNb_3 sample as a working electrode show the almost reversible profile for the cyclic voltammetry curves in potassium ferrocyanide in the scanning speed range of 1 to 100 mV s–1. Moreover, the flat band energy (E fb) indicates the p-type semiconductor characteristic for BaNb2O6, and a specific capacitance of 3375.66 mF cm–2, suggesting an interesting material for composition n–p heterojunctions.</description><subject>ambient temperature</subject><subject>Applied Chemistry</subject><subject>barium</subject><subject>capacitance</subject><subject>crystal structure</subject><subject>crystallization</subject><subject>electrochemistry</subject><subject>energy</subject><subject>glassy carbon electrode</subject><subject>potassium</subject><subject>Raman spectroscopy</subject><subject>reflectance spectroscopy</subject><subject>semiconductors</subject><subject>voltammetry</subject><subject>X-ray diffraction</subject><issn>0888-5885</issn><issn>1520-5045</issn><issn>1520-5045</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNotkM9PwyAYhonRxDm9e-ToYZ1AYQVvbpk_ks0ZneeGAt26sFKBHvbfS-NO35svT968eQC4x2iKEcGPUoVpY5SfUoUIK_gFGGFGUMYQZZdghDjnGeOcXYObEA4IIcYoHYE4lx8V2cygjPDLuSPcmmNnvIy9N7A6wbm0Fq4ba5t2B9cm7p1-gt_R9yoR0k7gpouNGsLa-W7vrNudJlC2Gi6tUdE7tTfHJkR_gp_epebYmHALrmppg7k73zH4eVluF2_ZavP6vnheZRKLImaaG0JqQmtdaYxywWVRIFNpmWIlmBSayUrpmaiJmAlGC4xUTRlVvOA0pzgfg4f_3s67396EWKYpylgrW-P6UOaYUVwIwkhCJ_9o8lgeXO_bNKzEqBzklsNzkFue5eZ_uf9vYA</recordid><startdate>20241108</startdate><enddate>20241108</enddate><creator>Nascimento, José Fábio de Lima</creator><creator>Leyet Ruiz, Yurimiler</creator><creator>da Cunha Mendes, Otoniel</creator><creator>Batista, Francisco Marcos Costa</creator><creator>Cabot, Andreu</creator><creator>Matos, José Milton Elias de</creator><creator>Ferreira, Robson Dantas</creator><creator>Botelho do Nascimento, Marcus Valério</creator><creator>Saraiva, Libertalamar Bilhalva</creator><creator>Quaresma, João Nazareno Nonato</creator><creator>Nobre, Francisco Xavier</creator><general>American Chemical Society</general><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0000-0003-3476-399X</orcidid><orcidid>https://orcid.org/0000-0002-5774-5391</orcidid><orcidid>https://orcid.org/0000-0002-7533-3251</orcidid><orcidid>https://orcid.org/0000-0002-5376-5643</orcidid><orcidid>https://orcid.org/0000-0002-0883-3651</orcidid><orcidid>https://orcid.org/0000-0001-9365-7498</orcidid></search><sort><creationdate>20241108</creationdate><title>BaNb2O6 at Room Temperature by Ball Milling Method: Structural, Optical, Morphology, and Electrochemistry Properties</title><author>Nascimento, José Fábio de Lima ; Leyet Ruiz, Yurimiler ; da Cunha Mendes, Otoniel ; Batista, Francisco Marcos Costa ; Cabot, Andreu ; Matos, José Milton Elias de ; Ferreira, Robson Dantas ; Botelho do Nascimento, Marcus Valério ; Saraiva, Libertalamar Bilhalva ; Quaresma, João Nazareno Nonato ; Nobre, Francisco Xavier</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a197t-d8e22f24fdbd10398a770ebda398b95a9d5abcd69f296954710cf454c87843413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>ambient temperature</topic><topic>Applied Chemistry</topic><topic>barium</topic><topic>capacitance</topic><topic>crystal structure</topic><topic>crystallization</topic><topic>electrochemistry</topic><topic>energy</topic><topic>glassy carbon electrode</topic><topic>potassium</topic><topic>Raman spectroscopy</topic><topic>reflectance spectroscopy</topic><topic>semiconductors</topic><topic>voltammetry</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nascimento, José Fábio de Lima</creatorcontrib><creatorcontrib>Leyet Ruiz, Yurimiler</creatorcontrib><creatorcontrib>da Cunha Mendes, Otoniel</creatorcontrib><creatorcontrib>Batista, Francisco Marcos Costa</creatorcontrib><creatorcontrib>Cabot, Andreu</creatorcontrib><creatorcontrib>Matos, José Milton Elias de</creatorcontrib><creatorcontrib>Ferreira, Robson Dantas</creatorcontrib><creatorcontrib>Botelho do Nascimento, Marcus Valério</creatorcontrib><creatorcontrib>Saraiva, Libertalamar Bilhalva</creatorcontrib><creatorcontrib>Quaresma, João Nazareno Nonato</creatorcontrib><creatorcontrib>Nobre, Francisco Xavier</creatorcontrib><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Industrial & engineering chemistry research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nascimento, José Fábio de Lima</au><au>Leyet Ruiz, Yurimiler</au><au>da Cunha Mendes, Otoniel</au><au>Batista, Francisco Marcos Costa</au><au>Cabot, Andreu</au><au>Matos, José Milton Elias de</au><au>Ferreira, Robson Dantas</au><au>Botelho do Nascimento, Marcus Valério</au><au>Saraiva, Libertalamar Bilhalva</au><au>Quaresma, João Nazareno Nonato</au><au>Nobre, Francisco Xavier</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>BaNb2O6 at Room Temperature by Ball Milling Method: Structural, Optical, Morphology, and Electrochemistry Properties</atitle><jtitle>Industrial & engineering chemistry research</jtitle><addtitle>Ind. Eng. Chem. Res</addtitle><date>2024-11-08</date><risdate>2024</risdate><volume>63</volume><issue>46</issue><spage>20020</spage><epage>20033</epage><pages>20020-20033</pages><issn>0888-5885</issn><issn>1520-5045</issn><eissn>1520-5045</eissn><abstract>Materials that depend on high temperature, pressure, or long periods of crystallization in the obtention of the pure phase have been the focus of several studies due to the economic and ecological aspects. The high-energy ball milling method (HEBM) has been adopted to synthesize different materials using solid-state reactions. In this study, bare barium niobate was efficiently synthesized at room temperature using the HEBM. The materials synthesized at different synthesis times were characterized by X-ray diffraction (XRD) and Rietveld refinement, which confirms the orthorhombic structure for BaNb2O6, with a high crystallinity degree at 3 h (BaNb_3) and 4 h (BaNb_4) of synthesis. The main vibrational modes of the structure were identified by Raman spectroscopy. In contrast, band-gap values between 3.77 and 3.84 eV were obtained by diffuse reflectance spectroscopy for the samples BaNb_3 and BaNb_4, respectively. The electrochemical experiments using the modified glassy carbon electrode (GCE) with BaNb_3 sample as a working electrode show the almost reversible profile for the cyclic voltammetry curves in potassium ferrocyanide in the scanning speed range of 1 to 100 mV s–1. Moreover, the flat band energy (E fb) indicates the p-type semiconductor characteristic for BaNb2O6, and a specific capacitance of 3375.66 mF cm–2, suggesting an interesting material for composition n–p heterojunctions.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.iecr.4c02578</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0003-3476-399X</orcidid><orcidid>https://orcid.org/0000-0002-5774-5391</orcidid><orcidid>https://orcid.org/0000-0002-7533-3251</orcidid><orcidid>https://orcid.org/0000-0002-5376-5643</orcidid><orcidid>https://orcid.org/0000-0002-0883-3651</orcidid><orcidid>https://orcid.org/0000-0001-9365-7498</orcidid><oa>free_for_read</oa></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0888-5885 |
ispartof | Industrial & engineering chemistry research, 2024-11, Vol.63 (46), p.20020-20033 |
issn | 0888-5885 1520-5045 1520-5045 |
language | eng |
recordid | cdi_proquest_miscellaneous_3154179252 |
source | ACS Publications |
subjects | ambient temperature Applied Chemistry barium capacitance crystal structure crystallization electrochemistry energy glassy carbon electrode potassium Raman spectroscopy reflectance spectroscopy semiconductors voltammetry X-ray diffraction |
title | BaNb2O6 at Room Temperature by Ball Milling Method: Structural, Optical, Morphology, and Electrochemistry Properties |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T11%3A53%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_acs_j&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=BaNb2O6%20at%20Room%20Temperature%20by%20Ball%20Milling%20Method:%20Structural,%20Optical,%20Morphology,%20and%20Electrochemistry%20Properties&rft.jtitle=Industrial%20&%20engineering%20chemistry%20research&rft.au=Nascimento,%20Jose%CC%81%20Fa%CC%81bio%20de%20Lima&rft.date=2024-11-08&rft.volume=63&rft.issue=46&rft.spage=20020&rft.epage=20033&rft.pages=20020-20033&rft.issn=0888-5885&rft.eissn=1520-5045&rft_id=info:doi/10.1021/acs.iecr.4c02578&rft_dat=%3Cproquest_acs_j%3E3154179252%3C/proquest_acs_j%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3154179252&rft_id=info:pmid/&rfr_iscdi=true |