Coupling CO2 Electroreduction to CO with alkyne Alkoxycarbonylation

Coupling CO2 Electroreduction to CO with alkyne Alkoxycarbonylation

The alkyne alkoxycarbonylation to α- or β-substituted acrylates was coupled with the electrocatalytic reduction of CO2 to CO. The CO-enriched gaseous mixture produced from the electrocatalytic reduction of CO2 was collected and directly used in the alkyne alkoxycarbonylation. The CO content was foun...

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Veröffentlicht in:Organic letters 2024-10, Vol.26 (42), p.8982-8987
Hauptverfasser: Shi, Haonan, Jia, Shuaiqiang, Dong, Mengke, Wu, Haihong, Huang, Zheng, Dong, Kaiwu
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acrylates
alkynes
carbon dioxide
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container_end_page 8987
container_issue 42
container_start_page 8982
container_title Organic letters
container_volume 26
creator Shi, Haonan
Jia, Shuaiqiang
Dong, Mengke
Wu, Haihong
Huang, Zheng
Dong, Kaiwu
description The alkyne alkoxycarbonylation to α- or β-substituted acrylates was coupled with the electrocatalytic reduction of CO2 to CO. The CO-enriched gaseous mixture produced from the electrocatalytic reduction of CO2 was collected and directly used in the alkyne alkoxycarbonylation. The CO content was found to be critical to the process of carbonylation, and satisfying results were attained by using the gas mixture containing >15 vol % CO. This method offered an efficient but simple CO source from CO2 electroreduction to the alkoxycarbonylation reaction in two-compartment manner.
doi_str_mv 10.1021/acs.orglett.4c02431
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subjects acrylates
alkynes
carbon dioxide
title Coupling CO2 Electroreduction to CO with alkyne Alkoxycarbonylation
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