Catalytic Degradation of Acid Orange 7 Using CoFe2O4@Biochar Heterogeneous Catalytic Ozonation Process in Aqueous Solutions

The aim of this study is to propose a new catalyst for catalytic ozonation of acid orange 7 (AO7) dye in aqueous solutions. CoFe 2 O 4 @Biochar catalyst was synthesized, prepared, and used in a heterogeneous catalytic ozonation process (COP) for AO7 removal. The characteristics of synthetized nanopa...

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Hauptverfasser: Bazipour, Fatemeh, Jorfi, Sahand, Maleki, Heydar, Babaei, AliAkbar
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container_issue 12
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Jorfi, Sahand
Maleki, Heydar
Babaei, AliAkbar
description The aim of this study is to propose a new catalyst for catalytic ozonation of acid orange 7 (AO7) dye in aqueous solutions. CoFe 2 O 4 @Biochar catalyst was synthesized, prepared, and used in a heterogeneous catalytic ozonation process (COP) for AO7 removal. The characteristics of synthetized nanoparticles were investigated through the following equipment: x-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), fourier transform infrared (FTIR) spectroscopy, vibrating sample magnetometer (VSM), transmission electron microscopy (TEM), Brunauer, Emmett and Teller (BET) and energy dispersive x-ray (EDX) analyses. The results showed that the process offered a sufficient efficiency for removal of 150 and 200 mg/L concentrations of AO7. Moreover, CO 3 2- , NO 3 - , Cl - and PO 4 3- anions had a decreasing effect on the efficiency. The results of the scavenger experiments showed that the hydroxyl radical and ozone oxidants played the primary role for decomposition of the pollutants. The removal efficiency of total organic carbon (TOC) was 99% after 120 min by COP which was 44% more than the Single Ozonation Process (SOP). COP also caused the removal of chemical oxygen demand (COD) by 92% after 360 min. Based on the results, the COP with CoFe 2 O 4 @Biochar catalyst can be an effective and efficient process for treating textile wastewaters.
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The removal efficiency of total organic carbon (TOC) was 99% after 120 min by COP which was 44% more than the Single Ozonation Process (SOP). COP also caused the removal of chemical oxygen demand (COD) by 92% after 360 min. 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CoFe 2 O 4 @Biochar catalyst was synthesized, prepared, and used in a heterogeneous catalytic ozonation process (COP) for AO7 removal. The characteristics of synthetized nanoparticles were investigated through the following equipment: x-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), fourier transform infrared (FTIR) spectroscopy, vibrating sample magnetometer (VSM), transmission electron microscopy (TEM), Brunauer, Emmett and Teller (BET) and energy dispersive x-ray (EDX) analyses. The results showed that the process offered a sufficient efficiency for removal of 150 and 200 mg/L concentrations of AO7. Moreover, CO 3 2- , NO 3 - , Cl - and PO 4 3- anions had a decreasing effect on the efficiency. The results of the scavenger experiments showed that the hydroxyl radical and ozone oxidants played the primary role for decomposition of the pollutants. The removal efficiency of total organic carbon (TOC) was 99% after 120 min by COP which was 44% more than the Single Ozonation Process (SOP). COP also caused the removal of chemical oxygen demand (COD) by 92% after 360 min. Based on the results, the COP with CoFe 2 O 4 @Biochar catalyst can be an effective and efficient process for treating textile wastewaters.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11270-024-07625-0</doi><tpages>1</tpages></addata></record>
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subjects acid orange 7
air
Anions
Aqueous solutions
Atmospheric Protection/Air Quality Control/Air Pollution
Catalysts
Charcoal
Chemical oxygen demand
Chemical synthesis
Climate Change/Climate Change Impacts
Cobalt ferrites
Dyes
Earth and Environmental Science
Efficiency
Electron microscopy
energy-dispersive X-ray analysis
Environment
fabrics
Field emission microscopy
Fourier transform infrared spectroscopy
Fourier transforms
Hydrogeology
Hydroxyl radicals
Microscopy
Nanoparticles
Orange II
Organic carbon
Oxidants
Oxidizing agents
Oxygen requirement
Ozonation
Ozone
Ozonization
Scanning electron microscopy
soil
Soil Science & Conservation
Textile industry wastewaters
Total organic carbon
Transmission electron microscopy
wastewater
water
Water Quality/Water Pollution
X rays
X-ray diffraction
title Catalytic Degradation of Acid Orange 7 Using CoFe2O4@Biochar Heterogeneous Catalytic Ozonation Process in Aqueous Solutions
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