Differences in thermal decomposition and crystallinity of dark organic laminae and light mineral laminae in same stromatolite
•Dark organic laminae shows higher crystallinity and activation energy than light mineral laminae.•The FWHM value for crystal plane (104) of dark organic laminae was lower than light mineral laminae.•The higher activation energy suggests a higher thermal stability.•Thermochemical analysis technique...
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| creator | Zhuang, Dingxiang Yang, Fan Xiang, Qing Wei, Qiang Jiang, Wei Zhao, Jingyu Guo, Yan |
| description | •Dark organic laminae shows higher crystallinity and activation energy than light mineral laminae.•The FWHM value for crystal plane (104) of dark organic laminae was lower than light mineral laminae.•The higher activation energy suggests a higher thermal stability.•Thermochemical analysis technique can provide powerful tool to analyze the geological samples.
Stromatolite was a typical representative of microbial carbonate rocks, and also a unique microbial sedimentary structure in carbonate rocks. Previous studies on the characteristics of dark organic laminae and light mineral laminae in same stromatolite have carried out a lot of work, but there was less research in thermal decomposition and crystallinity. Here, X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) were used to determine the mineral composition and organic components of stromatolite and micrite. In addition, TG, DTG and were used to analyze their thermochemical characteristics and the non-isothermal decomposition of stromatolite and micrite at multi-heating rates of 5, 10, 20 and 30 °C min−1 in nitrogen atmospheres. Moreover, kinetic model function, kinetic parameters of apparent activation energy (E), and pre-exponential factor (A) were calculated by Popescu, Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS). The results showed that the mineral composition of two laminae structures was calcite, but there were organic matter and organic functional groups in the dark laminae. In addition, the results of thermal analysis showed that the crystallinity and thermal stability were significantly different, that was, crystallinity and thermal stability of dark laminae were significantly higher than that of light laminae. Moreover, the kinetic calculation results showed that the activation energy of dark laminae was also higher. These results provided an important reference for analyzing the thermochemical characteristics of stromatolite, especially the differences in dark organic laminae and light mineral laminae of the stromatolite. |
| doi_str_mv | 10.1016/j.tca.2023.179576 |
| format | Article |
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Stromatolite was a typical representative of microbial carbonate rocks, and also a unique microbial sedimentary structure in carbonate rocks. Previous studies on the characteristics of dark organic laminae and light mineral laminae in same stromatolite have carried out a lot of work, but there was less research in thermal decomposition and crystallinity. Here, X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) were used to determine the mineral composition and organic components of stromatolite and micrite. In addition, TG, DTG and were used to analyze their thermochemical characteristics and the non-isothermal decomposition of stromatolite and micrite at multi-heating rates of 5, 10, 20 and 30 °C min−1 in nitrogen atmospheres. Moreover, kinetic model function, kinetic parameters of apparent activation energy (E), and pre-exponential factor (A) were calculated by Popescu, Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS). The results showed that the mineral composition of two laminae structures was calcite, but there were organic matter and organic functional groups in the dark laminae. In addition, the results of thermal analysis showed that the crystallinity and thermal stability were significantly different, that was, crystallinity and thermal stability of dark laminae were significantly higher than that of light laminae. Moreover, the kinetic calculation results showed that the activation energy of dark laminae was also higher. These results provided an important reference for analyzing the thermochemical characteristics of stromatolite, especially the differences in dark organic laminae and light mineral laminae of the stromatolite.</description><identifier>ISSN: 0040-6031</identifier><identifier>EISSN: 1872-762X</identifier><identifier>DOI: 10.1016/j.tca.2023.179576</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Activation energy ; calcite ; carbonates ; crystal structure ; Crystallinity ; Dark laminae ; Fourier transform infrared spectroscopy ; kinetics ; Light laminae TG–DTG ; mineral content ; nitrogen ; organic matter ; thermal analysis ; Thermal decomposition ; thermal degradation ; thermal stability ; X-ray diffraction</subject><ispartof>Thermochimica acta, 2023-10, Vol.728, p.179576, Article 179576</ispartof><rights>2023 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c282t-365f73609291a0ceb61edd6456e8583e51b94f2bcdb9a447b1292c7d1e17f4c43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0040603123001454$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Zhuang, Dingxiang</creatorcontrib><creatorcontrib>Yang, Fan</creatorcontrib><creatorcontrib>Xiang, Qing</creatorcontrib><creatorcontrib>Wei, Qiang</creatorcontrib><creatorcontrib>Jiang, Wei</creatorcontrib><creatorcontrib>Zhao, Jingyu</creatorcontrib><creatorcontrib>Guo, Yan</creatorcontrib><title>Differences in thermal decomposition and crystallinity of dark organic laminae and light mineral laminae in same stromatolite</title><title>Thermochimica acta</title><description>•Dark organic laminae shows higher crystallinity and activation energy than light mineral laminae.•The FWHM value for crystal plane (104) of dark organic laminae was lower than light mineral laminae.•The higher activation energy suggests a higher thermal stability.•Thermochemical analysis technique can provide powerful tool to analyze the geological samples.
Stromatolite was a typical representative of microbial carbonate rocks, and also a unique microbial sedimentary structure in carbonate rocks. Previous studies on the characteristics of dark organic laminae and light mineral laminae in same stromatolite have carried out a lot of work, but there was less research in thermal decomposition and crystallinity. Here, X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) were used to determine the mineral composition and organic components of stromatolite and micrite. In addition, TG, DTG and were used to analyze their thermochemical characteristics and the non-isothermal decomposition of stromatolite and micrite at multi-heating rates of 5, 10, 20 and 30 °C min−1 in nitrogen atmospheres. Moreover, kinetic model function, kinetic parameters of apparent activation energy (E), and pre-exponential factor (A) were calculated by Popescu, Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS). The results showed that the mineral composition of two laminae structures was calcite, but there were organic matter and organic functional groups in the dark laminae. In addition, the results of thermal analysis showed that the crystallinity and thermal stability were significantly different, that was, crystallinity and thermal stability of dark laminae were significantly higher than that of light laminae. Moreover, the kinetic calculation results showed that the activation energy of dark laminae was also higher. These results provided an important reference for analyzing the thermochemical characteristics of stromatolite, especially the differences in dark organic laminae and light mineral laminae of the stromatolite.</description><subject>Activation energy</subject><subject>calcite</subject><subject>carbonates</subject><subject>crystal structure</subject><subject>Crystallinity</subject><subject>Dark laminae</subject><subject>Fourier transform infrared spectroscopy</subject><subject>kinetics</subject><subject>Light laminae TG–DTG</subject><subject>mineral content</subject><subject>nitrogen</subject><subject>organic matter</subject><subject>thermal analysis</subject><subject>Thermal decomposition</subject><subject>thermal degradation</subject><subject>thermal stability</subject><subject>X-ray diffraction</subject><issn>0040-6031</issn><issn>1872-762X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kD1PwzAQhi0EEqXwA9g8sqT4nMRJxITKp1SJBSQ2y7EvrYsTF9sgdeC_k1JYmU6ne59XuoeQc2AzYCAu17Ok1Ywzns-gaspKHJAJ1BXPKsFfD8mEsYJlguVwTE5iXDPGgNdsQr5ubNdhwEFjpHagaYWhV44a1L7f-GiT9QNVg6E6bGNSztnBpi31HTUqvFEflmqwmjrV20HhT9LZ5SrRcccwNv1dxvKoeqQxBd-r5J1NeEqOOuUinv3OKXm5u32eP2SLp_vH-fUi07zmKctF2VW5YA1vQDGNrQA0RhSlwLqscyyhbYqOt9q0jSqKqgXecF0ZQKi6Qhf5lFzsezfBv39gTLK3UaNzakD_EWUOZQGiFqO-KYF9VAcfY8BOboLtVdhKYHKnWq7lqFruVMu96pG52jM4_vBpMcio7U6psQF1ksbbf-hvyr6JGA</recordid><startdate>202310</startdate><enddate>202310</enddate><creator>Zhuang, Dingxiang</creator><creator>Yang, Fan</creator><creator>Xiang, Qing</creator><creator>Wei, Qiang</creator><creator>Jiang, Wei</creator><creator>Zhao, Jingyu</creator><creator>Guo, Yan</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>202310</creationdate><title>Differences in thermal decomposition and crystallinity of dark organic laminae and light mineral laminae in same stromatolite</title><author>Zhuang, Dingxiang ; Yang, Fan ; Xiang, Qing ; Wei, Qiang ; Jiang, Wei ; Zhao, Jingyu ; Guo, Yan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c282t-365f73609291a0ceb61edd6456e8583e51b94f2bcdb9a447b1292c7d1e17f4c43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Activation energy</topic><topic>calcite</topic><topic>carbonates</topic><topic>crystal structure</topic><topic>Crystallinity</topic><topic>Dark laminae</topic><topic>Fourier transform infrared spectroscopy</topic><topic>kinetics</topic><topic>Light laminae TG–DTG</topic><topic>mineral content</topic><topic>nitrogen</topic><topic>organic matter</topic><topic>thermal analysis</topic><topic>Thermal decomposition</topic><topic>thermal degradation</topic><topic>thermal stability</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhuang, Dingxiang</creatorcontrib><creatorcontrib>Yang, Fan</creatorcontrib><creatorcontrib>Xiang, Qing</creatorcontrib><creatorcontrib>Wei, Qiang</creatorcontrib><creatorcontrib>Jiang, Wei</creatorcontrib><creatorcontrib>Zhao, Jingyu</creatorcontrib><creatorcontrib>Guo, Yan</creatorcontrib><collection>CrossRef</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Thermochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhuang, Dingxiang</au><au>Yang, Fan</au><au>Xiang, Qing</au><au>Wei, Qiang</au><au>Jiang, Wei</au><au>Zhao, Jingyu</au><au>Guo, Yan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Differences in thermal decomposition and crystallinity of dark organic laminae and light mineral laminae in same stromatolite</atitle><jtitle>Thermochimica acta</jtitle><date>2023-10</date><risdate>2023</risdate><volume>728</volume><spage>179576</spage><pages>179576-</pages><artnum>179576</artnum><issn>0040-6031</issn><eissn>1872-762X</eissn><abstract>•Dark organic laminae shows higher crystallinity and activation energy than light mineral laminae.•The FWHM value for crystal plane (104) of dark organic laminae was lower than light mineral laminae.•The higher activation energy suggests a higher thermal stability.•Thermochemical analysis technique can provide powerful tool to analyze the geological samples.
Stromatolite was a typical representative of microbial carbonate rocks, and also a unique microbial sedimentary structure in carbonate rocks. Previous studies on the characteristics of dark organic laminae and light mineral laminae in same stromatolite have carried out a lot of work, but there was less research in thermal decomposition and crystallinity. Here, X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) were used to determine the mineral composition and organic components of stromatolite and micrite. In addition, TG, DTG and were used to analyze their thermochemical characteristics and the non-isothermal decomposition of stromatolite and micrite at multi-heating rates of 5, 10, 20 and 30 °C min−1 in nitrogen atmospheres. Moreover, kinetic model function, kinetic parameters of apparent activation energy (E), and pre-exponential factor (A) were calculated by Popescu, Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS). The results showed that the mineral composition of two laminae structures was calcite, but there were organic matter and organic functional groups in the dark laminae. In addition, the results of thermal analysis showed that the crystallinity and thermal stability were significantly different, that was, crystallinity and thermal stability of dark laminae were significantly higher than that of light laminae. Moreover, the kinetic calculation results showed that the activation energy of dark laminae was also higher. These results provided an important reference for analyzing the thermochemical characteristics of stromatolite, especially the differences in dark organic laminae and light mineral laminae of the stromatolite.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.tca.2023.179576</doi></addata></record> |
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| subjects | Activation energy calcite carbonates crystal structure Crystallinity Dark laminae Fourier transform infrared spectroscopy kinetics Light laminae TG–DTG mineral content nitrogen organic matter thermal analysis Thermal decomposition thermal degradation thermal stability X-ray diffraction |
| title | Differences in thermal decomposition and crystallinity of dark organic laminae and light mineral laminae in same stromatolite |
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