Chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with improved mechanical and photo-thermal conversion properties via tuning CuSNPs' morphological structures
Conventional textiles are inadequate for maintaining warmth in extremely cold conditions. Therefore, the development of photo-thermal fibers for personal thermal management textiles has emerged as an urgent need. Herein, novel chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with phot...
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Veröffentlicht in: | International journal of biological macromolecules 2023-12, Vol.253, p.127098-127098, Article 127098 |
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container_title | International journal of biological macromolecules |
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creator | Cheng, Chen Bao, Da Sun, Shengnan Zhou, Yongchun Tian, Linna Zhang, Bing Yu, Yue Guo, Jing Zhang, Sen |
description | Conventional textiles are inadequate for maintaining warmth in extremely cold conditions. Therefore, the development of photo-thermal fibers for personal thermal management textiles has emerged as an urgent need. Herein, novel chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with photo-thermal function were fabricated successfully. Significantly, our study demonstrated that the tensile and photo-thermal conversation properties of the CS/CuSNPs hybrid fibers could be effectively regulated by altering the CuSNPs` morphological structures. Compared with other CuSNPs (tube-like, sphere-like, and flower-like), the plate-like CuSNPs with smooth surfaces and uniform nanometer size played a significant role by scattering incident light in the fibers as a secondary light source for CuSNPs absorbance. Thus, under IR light irradiation at a power density of 1.0 W/cm2, the surface temperature of CS/0.1 wt% plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C, which was more than 4 times of the pure CS fibers. And the breaking strength and initial modulus of CS/0.1 wt% plate-like CuSNPs hybrid fibers increased by more than 18.37 and 6.88 % compared with the nascent CS fibers. This study develops a novel and effective strategy to tune the photo-thermal and tensile properties of CS hybrid fibers without incorporating more content or additives.
•CS/CuSNPs hybrid fibers with photo-thermal function were fabricated successfully.•The photo-thermal conversation properties were enhanced by altering CuSNPs structure.•The plate-like CuSNPs scattered incident light in the fibers for CuSNPs absorbance.•The temperature of CS/plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C.•The breaking strength of CS/plate-like CuSNPs hybrid fibers increased by 18.37 %. |
doi_str_mv | 10.1016/j.ijbiomac.2023.127098 |
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•CS/CuSNPs hybrid fibers with photo-thermal function were fabricated successfully.•The photo-thermal conversation properties were enhanced by altering CuSNPs structure.•The plate-like CuSNPs scattered incident light in the fibers for CuSNPs absorbance.•The temperature of CS/plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C.•The breaking strength of CS/plate-like CuSNPs hybrid fibers increased by 18.37 %.</description><identifier>ISSN: 0141-8130</identifier><identifier>EISSN: 1879-0003</identifier><identifier>DOI: 10.1016/j.ijbiomac.2023.127098</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>absorbance ; Chitosan ; cold ; Copper sulfide nanoparticles ; irradiation ; nanoparticles ; Photo-thermal conversation ; sulfides ; surface temperature</subject><ispartof>International journal of biological macromolecules, 2023-12, Vol.253, p.127098-127098, Article 127098</ispartof><rights>2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c378t-183805aa96da460aaecb6e0d958514856de94a8bd47bee2bafcab9491c8923703</citedby><cites>FETCH-LOGICAL-c378t-183805aa96da460aaecb6e0d958514856de94a8bd47bee2bafcab9491c8923703</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0141813023039958$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Cheng, Chen</creatorcontrib><creatorcontrib>Bao, Da</creatorcontrib><creatorcontrib>Sun, Shengnan</creatorcontrib><creatorcontrib>Zhou, Yongchun</creatorcontrib><creatorcontrib>Tian, Linna</creatorcontrib><creatorcontrib>Zhang, Bing</creatorcontrib><creatorcontrib>Yu, Yue</creatorcontrib><creatorcontrib>Guo, Jing</creatorcontrib><creatorcontrib>Zhang, Sen</creatorcontrib><title>Chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with improved mechanical and photo-thermal conversion properties via tuning CuSNPs' morphological structures</title><title>International journal of biological macromolecules</title><description>Conventional textiles are inadequate for maintaining warmth in extremely cold conditions. Therefore, the development of photo-thermal fibers for personal thermal management textiles has emerged as an urgent need. Herein, novel chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with photo-thermal function were fabricated successfully. Significantly, our study demonstrated that the tensile and photo-thermal conversation properties of the CS/CuSNPs hybrid fibers could be effectively regulated by altering the CuSNPs` morphological structures. Compared with other CuSNPs (tube-like, sphere-like, and flower-like), the plate-like CuSNPs with smooth surfaces and uniform nanometer size played a significant role by scattering incident light in the fibers as a secondary light source for CuSNPs absorbance. Thus, under IR light irradiation at a power density of 1.0 W/cm2, the surface temperature of CS/0.1 wt% plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C, which was more than 4 times of the pure CS fibers. And the breaking strength and initial modulus of CS/0.1 wt% plate-like CuSNPs hybrid fibers increased by more than 18.37 and 6.88 % compared with the nascent CS fibers. This study develops a novel and effective strategy to tune the photo-thermal and tensile properties of CS hybrid fibers without incorporating more content or additives.
•CS/CuSNPs hybrid fibers with photo-thermal function were fabricated successfully.•The photo-thermal conversation properties were enhanced by altering CuSNPs structure.•The plate-like CuSNPs scattered incident light in the fibers for CuSNPs absorbance.•The temperature of CS/plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C.•The breaking strength of CS/plate-like CuSNPs hybrid fibers increased by 18.37 %.</description><subject>absorbance</subject><subject>Chitosan</subject><subject>cold</subject><subject>Copper sulfide nanoparticles</subject><subject>irradiation</subject><subject>nanoparticles</subject><subject>Photo-thermal conversation</subject><subject>sulfides</subject><subject>surface temperature</subject><issn>0141-8130</issn><issn>1879-0003</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNqFkU9v1DAQxSMEEkvhKyDfKIfs2vnr3ECrQitVgFQ4WxN70swqsYPtLOp34kPiEjj3NNLo996b0cuyt4LvBRfN4bSnU09uBr0veFHuRdHyTj7LdkK2Xc45L59nOy4qkUtR8pfZqxBOadvUQu6y38eRogtgD9otC3oW1mkgg8yCdQv4SHrCwC6Pd4fjevflW3jPxofek2ED9egD-0VxZDQv3p3RsBn1CJY0TAysYcvoosvjiH5OG-3sOUnIWZbwFBYpWZ8JWFwt2Xu2Jbxjs_NJObn7v0Yh-lXH1WN4nb0YYAr45t-8yH58uvp-vM5vv36-OX68zXXZypgLWUpeA3SNgarhAKj7BrnpalmLStaNwa4C2Zuq7RGLHgYNfVd1QsuuKFteXmSXm2868-eKIaqZgsZpAotuDaoUdSWauimqJ9FCtonsUmxCmw3V3oXgcVCLpxn8gxJcPTapTup_k-qxSbU1mYQfNiGmn8-EXgVNaDUa8qijMo6esvgDHBiu-g</recordid><startdate>20231231</startdate><enddate>20231231</enddate><creator>Cheng, Chen</creator><creator>Bao, Da</creator><creator>Sun, Shengnan</creator><creator>Zhou, Yongchun</creator><creator>Tian, Linna</creator><creator>Zhang, Bing</creator><creator>Yu, Yue</creator><creator>Guo, Jing</creator><creator>Zhang, Sen</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20231231</creationdate><title>Chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with improved mechanical and photo-thermal conversion properties via tuning CuSNPs' morphological structures</title><author>Cheng, Chen ; Bao, Da ; Sun, Shengnan ; Zhou, Yongchun ; Tian, Linna ; Zhang, Bing ; Yu, Yue ; Guo, Jing ; Zhang, Sen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c378t-183805aa96da460aaecb6e0d958514856de94a8bd47bee2bafcab9491c8923703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>absorbance</topic><topic>Chitosan</topic><topic>cold</topic><topic>Copper sulfide nanoparticles</topic><topic>irradiation</topic><topic>nanoparticles</topic><topic>Photo-thermal conversation</topic><topic>sulfides</topic><topic>surface temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cheng, Chen</creatorcontrib><creatorcontrib>Bao, Da</creatorcontrib><creatorcontrib>Sun, Shengnan</creatorcontrib><creatorcontrib>Zhou, Yongchun</creatorcontrib><creatorcontrib>Tian, Linna</creatorcontrib><creatorcontrib>Zhang, Bing</creatorcontrib><creatorcontrib>Yu, Yue</creatorcontrib><creatorcontrib>Guo, Jing</creatorcontrib><creatorcontrib>Zhang, Sen</creatorcontrib><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>International journal of biological macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cheng, Chen</au><au>Bao, Da</au><au>Sun, Shengnan</au><au>Zhou, Yongchun</au><au>Tian, Linna</au><au>Zhang, Bing</au><au>Yu, Yue</au><au>Guo, Jing</au><au>Zhang, Sen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with improved mechanical and photo-thermal conversion properties via tuning CuSNPs' morphological structures</atitle><jtitle>International journal of biological macromolecules</jtitle><date>2023-12-31</date><risdate>2023</risdate><volume>253</volume><spage>127098</spage><epage>127098</epage><pages>127098-127098</pages><artnum>127098</artnum><issn>0141-8130</issn><eissn>1879-0003</eissn><abstract>Conventional textiles are inadequate for maintaining warmth in extremely cold conditions. Therefore, the development of photo-thermal fibers for personal thermal management textiles has emerged as an urgent need. Herein, novel chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with photo-thermal function were fabricated successfully. Significantly, our study demonstrated that the tensile and photo-thermal conversation properties of the CS/CuSNPs hybrid fibers could be effectively regulated by altering the CuSNPs` morphological structures. Compared with other CuSNPs (tube-like, sphere-like, and flower-like), the plate-like CuSNPs with smooth surfaces and uniform nanometer size played a significant role by scattering incident light in the fibers as a secondary light source for CuSNPs absorbance. Thus, under IR light irradiation at a power density of 1.0 W/cm2, the surface temperature of CS/0.1 wt% plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C, which was more than 4 times of the pure CS fibers. And the breaking strength and initial modulus of CS/0.1 wt% plate-like CuSNPs hybrid fibers increased by more than 18.37 and 6.88 % compared with the nascent CS fibers. This study develops a novel and effective strategy to tune the photo-thermal and tensile properties of CS hybrid fibers without incorporating more content or additives.
•CS/CuSNPs hybrid fibers with photo-thermal function were fabricated successfully.•The photo-thermal conversation properties were enhanced by altering CuSNPs structure.•The plate-like CuSNPs scattered incident light in the fibers for CuSNPs absorbance.•The temperature of CS/plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C.•The breaking strength of CS/plate-like CuSNPs hybrid fibers increased by 18.37 %.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.ijbiomac.2023.127098</doi><tpages>1</tpages></addata></record> |
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subjects | absorbance Chitosan cold Copper sulfide nanoparticles irradiation nanoparticles Photo-thermal conversation sulfides surface temperature |
title | Chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with improved mechanical and photo-thermal conversion properties via tuning CuSNPs' morphological structures |
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