Chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with improved mechanical and photo-thermal conversion properties via tuning CuSNPs' morphological structures

Conventional textiles are inadequate for maintaining warmth in extremely cold conditions. Therefore, the development of photo-thermal fibers for personal thermal management textiles has emerged as an urgent need. Herein, novel chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with phot...

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Veröffentlicht in:International journal of biological macromolecules 2023-12, Vol.253, p.127098-127098, Article 127098
Hauptverfasser: Cheng, Chen, Bao, Da, Sun, Shengnan, Zhou, Yongchun, Tian, Linna, Zhang, Bing, Yu, Yue, Guo, Jing, Zhang, Sen
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container_title International journal of biological macromolecules
container_volume 253
creator Cheng, Chen
Bao, Da
Sun, Shengnan
Zhou, Yongchun
Tian, Linna
Zhang, Bing
Yu, Yue
Guo, Jing
Zhang, Sen
description Conventional textiles are inadequate for maintaining warmth in extremely cold conditions. Therefore, the development of photo-thermal fibers for personal thermal management textiles has emerged as an urgent need. Herein, novel chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with photo-thermal function were fabricated successfully. Significantly, our study demonstrated that the tensile and photo-thermal conversation properties of the CS/CuSNPs hybrid fibers could be effectively regulated by altering the CuSNPs` morphological structures. Compared with other CuSNPs (tube-like, sphere-like, and flower-like), the plate-like CuSNPs with smooth surfaces and uniform nanometer size played a significant role by scattering incident light in the fibers as a secondary light source for CuSNPs absorbance. Thus, under IR light irradiation at a power density of 1.0 W/cm2, the surface temperature of CS/0.1 wt% plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C, which was more than 4 times of the pure CS fibers. And the breaking strength and initial modulus of CS/0.1 wt% plate-like CuSNPs hybrid fibers increased by more than 18.37 and 6.88 % compared with the nascent CS fibers. This study develops a novel and effective strategy to tune the photo-thermal and tensile properties of CS hybrid fibers without incorporating more content or additives. •CS/CuSNPs hybrid fibers with photo-thermal function were fabricated successfully.•The photo-thermal conversation properties were enhanced by altering CuSNPs structure.•The plate-like CuSNPs scattered incident light in the fibers for CuSNPs absorbance.•The temperature of CS/plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C.•The breaking strength of CS/plate-like CuSNPs hybrid fibers increased by 18.37 %.
doi_str_mv 10.1016/j.ijbiomac.2023.127098
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Therefore, the development of photo-thermal fibers for personal thermal management textiles has emerged as an urgent need. Herein, novel chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with photo-thermal function were fabricated successfully. Significantly, our study demonstrated that the tensile and photo-thermal conversation properties of the CS/CuSNPs hybrid fibers could be effectively regulated by altering the CuSNPs` morphological structures. Compared with other CuSNPs (tube-like, sphere-like, and flower-like), the plate-like CuSNPs with smooth surfaces and uniform nanometer size played a significant role by scattering incident light in the fibers as a secondary light source for CuSNPs absorbance. Thus, under IR light irradiation at a power density of 1.0 W/cm2, the surface temperature of CS/0.1 wt% plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C, which was more than 4 times of the pure CS fibers. 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This study develops a novel and effective strategy to tune the photo-thermal and tensile properties of CS hybrid fibers without incorporating more content or additives. •CS/CuSNPs hybrid fibers with photo-thermal function were fabricated successfully.•The photo-thermal conversation properties were enhanced by altering CuSNPs structure.•The plate-like CuSNPs scattered incident light in the fibers for CuSNPs absorbance.•The temperature of CS/plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C.•The breaking strength of CS/plate-like CuSNPs hybrid fibers increased by 18.37 %.</description><identifier>ISSN: 0141-8130</identifier><identifier>EISSN: 1879-0003</identifier><identifier>DOI: 10.1016/j.ijbiomac.2023.127098</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>absorbance ; Chitosan ; cold ; Copper sulfide nanoparticles ; irradiation ; nanoparticles ; Photo-thermal conversation ; sulfides ; surface temperature</subject><ispartof>International journal of biological macromolecules, 2023-12, Vol.253, p.127098-127098, Article 127098</ispartof><rights>2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c378t-183805aa96da460aaecb6e0d958514856de94a8bd47bee2bafcab9491c8923703</citedby><cites>FETCH-LOGICAL-c378t-183805aa96da460aaecb6e0d958514856de94a8bd47bee2bafcab9491c8923703</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0141813023039958$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Cheng, Chen</creatorcontrib><creatorcontrib>Bao, Da</creatorcontrib><creatorcontrib>Sun, Shengnan</creatorcontrib><creatorcontrib>Zhou, Yongchun</creatorcontrib><creatorcontrib>Tian, Linna</creatorcontrib><creatorcontrib>Zhang, Bing</creatorcontrib><creatorcontrib>Yu, Yue</creatorcontrib><creatorcontrib>Guo, Jing</creatorcontrib><creatorcontrib>Zhang, Sen</creatorcontrib><title>Chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with improved mechanical and photo-thermal conversion properties via tuning CuSNPs' morphological structures</title><title>International journal of biological macromolecules</title><description>Conventional textiles are inadequate for maintaining warmth in extremely cold conditions. Therefore, the development of photo-thermal fibers for personal thermal management textiles has emerged as an urgent need. Herein, novel chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with photo-thermal function were fabricated successfully. Significantly, our study demonstrated that the tensile and photo-thermal conversation properties of the CS/CuSNPs hybrid fibers could be effectively regulated by altering the CuSNPs` morphological structures. Compared with other CuSNPs (tube-like, sphere-like, and flower-like), the plate-like CuSNPs with smooth surfaces and uniform nanometer size played a significant role by scattering incident light in the fibers as a secondary light source for CuSNPs absorbance. Thus, under IR light irradiation at a power density of 1.0 W/cm2, the surface temperature of CS/0.1 wt% plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C, which was more than 4 times of the pure CS fibers. And the breaking strength and initial modulus of CS/0.1 wt% plate-like CuSNPs hybrid fibers increased by more than 18.37 and 6.88 % compared with the nascent CS fibers. This study develops a novel and effective strategy to tune the photo-thermal and tensile properties of CS hybrid fibers without incorporating more content or additives. •CS/CuSNPs hybrid fibers with photo-thermal function were fabricated successfully.•The photo-thermal conversation properties were enhanced by altering CuSNPs structure.•The plate-like CuSNPs scattered incident light in the fibers for CuSNPs absorbance.•The temperature of CS/plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C.•The breaking strength of CS/plate-like CuSNPs hybrid fibers increased by 18.37 %.</description><subject>absorbance</subject><subject>Chitosan</subject><subject>cold</subject><subject>Copper sulfide nanoparticles</subject><subject>irradiation</subject><subject>nanoparticles</subject><subject>Photo-thermal conversation</subject><subject>sulfides</subject><subject>surface temperature</subject><issn>0141-8130</issn><issn>1879-0003</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNqFkU9v1DAQxSMEEkvhKyDfKIfs2vnr3ECrQitVgFQ4WxN70swqsYPtLOp34kPiEjj3NNLo996b0cuyt4LvBRfN4bSnU09uBr0veFHuRdHyTj7LdkK2Xc45L59nOy4qkUtR8pfZqxBOadvUQu6y38eRogtgD9otC3oW1mkgg8yCdQv4SHrCwC6Pd4fjevflW3jPxofek2ED9egD-0VxZDQv3p3RsBn1CJY0TAysYcvoosvjiH5OG-3sOUnIWZbwFBYpWZ8JWFwt2Xu2Jbxjs_NJObn7v0Yh-lXH1WN4nb0YYAr45t-8yH58uvp-vM5vv36-OX68zXXZypgLWUpeA3SNgarhAKj7BrnpalmLStaNwa4C2Zuq7RGLHgYNfVd1QsuuKFteXmSXm2868-eKIaqZgsZpAotuDaoUdSWauimqJ9FCtonsUmxCmw3V3oXgcVCLpxn8gxJcPTapTup_k-qxSbU1mYQfNiGmn8-EXgVNaDUa8qijMo6esvgDHBiu-g</recordid><startdate>20231231</startdate><enddate>20231231</enddate><creator>Cheng, Chen</creator><creator>Bao, Da</creator><creator>Sun, Shengnan</creator><creator>Zhou, Yongchun</creator><creator>Tian, Linna</creator><creator>Zhang, Bing</creator><creator>Yu, Yue</creator><creator>Guo, Jing</creator><creator>Zhang, Sen</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20231231</creationdate><title>Chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with improved mechanical and photo-thermal conversion properties via tuning CuSNPs' morphological structures</title><author>Cheng, Chen ; Bao, Da ; Sun, Shengnan ; Zhou, Yongchun ; Tian, Linna ; Zhang, Bing ; Yu, Yue ; Guo, Jing ; Zhang, Sen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c378t-183805aa96da460aaecb6e0d958514856de94a8bd47bee2bafcab9491c8923703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>absorbance</topic><topic>Chitosan</topic><topic>cold</topic><topic>Copper sulfide nanoparticles</topic><topic>irradiation</topic><topic>nanoparticles</topic><topic>Photo-thermal conversation</topic><topic>sulfides</topic><topic>surface temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cheng, Chen</creatorcontrib><creatorcontrib>Bao, Da</creatorcontrib><creatorcontrib>Sun, Shengnan</creatorcontrib><creatorcontrib>Zhou, Yongchun</creatorcontrib><creatorcontrib>Tian, Linna</creatorcontrib><creatorcontrib>Zhang, Bing</creatorcontrib><creatorcontrib>Yu, Yue</creatorcontrib><creatorcontrib>Guo, Jing</creatorcontrib><creatorcontrib>Zhang, Sen</creatorcontrib><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>International journal of biological macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cheng, Chen</au><au>Bao, Da</au><au>Sun, Shengnan</au><au>Zhou, Yongchun</au><au>Tian, Linna</au><au>Zhang, Bing</au><au>Yu, Yue</au><au>Guo, Jing</au><au>Zhang, Sen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with improved mechanical and photo-thermal conversion properties via tuning CuSNPs' morphological structures</atitle><jtitle>International journal of biological macromolecules</jtitle><date>2023-12-31</date><risdate>2023</risdate><volume>253</volume><spage>127098</spage><epage>127098</epage><pages>127098-127098</pages><artnum>127098</artnum><issn>0141-8130</issn><eissn>1879-0003</eissn><abstract>Conventional textiles are inadequate for maintaining warmth in extremely cold conditions. Therefore, the development of photo-thermal fibers for personal thermal management textiles has emerged as an urgent need. Herein, novel chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with photo-thermal function were fabricated successfully. Significantly, our study demonstrated that the tensile and photo-thermal conversation properties of the CS/CuSNPs hybrid fibers could be effectively regulated by altering the CuSNPs` morphological structures. Compared with other CuSNPs (tube-like, sphere-like, and flower-like), the plate-like CuSNPs with smooth surfaces and uniform nanometer size played a significant role by scattering incident light in the fibers as a secondary light source for CuSNPs absorbance. Thus, under IR light irradiation at a power density of 1.0 W/cm2, the surface temperature of CS/0.1 wt% plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C, which was more than 4 times of the pure CS fibers. And the breaking strength and initial modulus of CS/0.1 wt% plate-like CuSNPs hybrid fibers increased by more than 18.37 and 6.88 % compared with the nascent CS fibers. This study develops a novel and effective strategy to tune the photo-thermal and tensile properties of CS hybrid fibers without incorporating more content or additives. •CS/CuSNPs hybrid fibers with photo-thermal function were fabricated successfully.•The photo-thermal conversation properties were enhanced by altering CuSNPs structure.•The plate-like CuSNPs scattered incident light in the fibers for CuSNPs absorbance.•The temperature of CS/plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C.•The breaking strength of CS/plate-like CuSNPs hybrid fibers increased by 18.37 %.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.ijbiomac.2023.127098</doi><tpages>1</tpages></addata></record>
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subjects absorbance
Chitosan
cold
Copper sulfide nanoparticles
irradiation
nanoparticles
Photo-thermal conversation
sulfides
surface temperature
title Chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with improved mechanical and photo-thermal conversion properties via tuning CuSNPs' morphological structures
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