A sterol database: GC/MS data and occurrence of 150 sterols in seventy-four oils
Comprehensive data on the occurrence of sterols in plant oils is currently hardly available since only a few sterols are obtainable as standard compounds. Accordingly, many peaks are rarely labeled in gas chromatograms due to missing or outdated information. This lack of information hampers the prog...
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description | Comprehensive data on the occurrence of sterols in plant oils is currently hardly available since only a few sterols are obtainable as standard compounds. Accordingly, many peaks are rarely labeled in gas chromatograms due to missing or outdated information. This lack of information hampers the progress in sterol research. For this reason, gas chromatography with mass spectrometry in selected ion monitoring mode (GC/MS-SIM) was used to create a database that summarizes the occurrence and semi-quantitative levels of 150 sterols with 27–32 carbon atoms and 0–4 double bonds in 66 different vegetable oils and eight other matrices. The highest number of sterols was detected in rice bran and tamanu oil (40 sterols), eggplant (39 sterols), moringa, chili seed, and amaranth oil (37 sterols). Several sterols were detected in >60 of the 74 matrices. This detailed information in the database will serve users working in food authentication and the biosynthesis of sterols.
•A database reports semi-quantitative data of 150 sterols in 74 sample matrices.•GC/MS-SIM enabled the detection of 11 to 40 sterols per sample matrix.•The highest sterol number was detected in rice bran oil, tamanu oil, and eggplant.•15 different sterols contributed 25% to the sterol pattern of one or more samples.•Ten sterols were detected in >66 of the 74 sample matrices. |
doi_str_mv | 10.1016/j.foodchem.2024.140778 |
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•A database reports semi-quantitative data of 150 sterols in 74 sample matrices.•GC/MS-SIM enabled the detection of 11 to 40 sterols per sample matrix.•The highest sterol number was detected in rice bran oil, tamanu oil, and eggplant.•15 different sterols contributed 25% to the sterol pattern of one or more samples.•Ten sterols were detected in >66 of the 74 sample matrices.</description><identifier>ISSN: 0308-8146</identifier><identifier>ISSN: 1873-7072</identifier><identifier>EISSN: 1873-7072</identifier><identifier>DOI: 10.1016/j.foodchem.2024.140778</identifier><identifier>PMID: 39142207</identifier><language>eng</language><publisher>England: Elsevier Ltd</publisher><subject>biosynthesis ; Calophyllum inophyllum ; carbon ; Databases, Factual ; eggplants ; food chemistry ; gas chromatography ; Gas Chromatography-Mass Spectrometry ; GC/MS ; Hydrogenation ; mass spectrometry ; Moringa ; oils ; Phytosterol ; Plant Oils - chemistry ; product authenticity ; rice bran ; sterols ; Sterols - analysis ; Sterols - chemistry ; Triterpenol ; Vegetable oil</subject><ispartof>Food chemistry, 2024-12, Vol.460 (Pt 3), p.140778, Article 140778</ispartof><rights>2024</rights><rights>Copyright © 2024. Published by Elsevier Ltd.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c326t-db601f8aedd2806335cb105459a2644f9ca5c47d66f620ffa30ac49ed4f294f43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0308814624024282$$EHTML$$P50$$Gelsevier$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39142207$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Schlag, Sarah</creatorcontrib><creatorcontrib>Schäfer, Sabrina</creatorcontrib><creatorcontrib>Sommer, Katrin</creatorcontrib><creatorcontrib>Vetter, Walter</creatorcontrib><title>A sterol database: GC/MS data and occurrence of 150 sterols in seventy-four oils</title><title>Food chemistry</title><addtitle>Food Chem</addtitle><description>Comprehensive data on the occurrence of sterols in plant oils is currently hardly available since only a few sterols are obtainable as standard compounds. Accordingly, many peaks are rarely labeled in gas chromatograms due to missing or outdated information. This lack of information hampers the progress in sterol research. For this reason, gas chromatography with mass spectrometry in selected ion monitoring mode (GC/MS-SIM) was used to create a database that summarizes the occurrence and semi-quantitative levels of 150 sterols with 27–32 carbon atoms and 0–4 double bonds in 66 different vegetable oils and eight other matrices. The highest number of sterols was detected in rice bran and tamanu oil (40 sterols), eggplant (39 sterols), moringa, chili seed, and amaranth oil (37 sterols). Several sterols were detected in >60 of the 74 matrices. This detailed information in the database will serve users working in food authentication and the biosynthesis of sterols.
•A database reports semi-quantitative data of 150 sterols in 74 sample matrices.•GC/MS-SIM enabled the detection of 11 to 40 sterols per sample matrix.•The highest sterol number was detected in rice bran oil, tamanu oil, and eggplant.•15 different sterols contributed 25% to the sterol pattern of one or more samples.•Ten sterols were detected in >66 of the 74 sample matrices.</description><subject>biosynthesis</subject><subject>Calophyllum inophyllum</subject><subject>carbon</subject><subject>Databases, Factual</subject><subject>eggplants</subject><subject>food chemistry</subject><subject>gas chromatography</subject><subject>Gas Chromatography-Mass Spectrometry</subject><subject>GC/MS</subject><subject>Hydrogenation</subject><subject>mass spectrometry</subject><subject>Moringa</subject><subject>oils</subject><subject>Phytosterol</subject><subject>Plant Oils - chemistry</subject><subject>product authenticity</subject><subject>rice bran</subject><subject>sterols</subject><subject>Sterols - analysis</subject><subject>Sterols - chemistry</subject><subject>Triterpenol</subject><subject>Vegetable oil</subject><issn>0308-8146</issn><issn>1873-7072</issn><issn>1873-7072</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkEtrGzEUhUVoiJ3HXwhadjPO1XumqxiTpIWUBNKuhSxd0THjkSPNBPLvY9dOtl5dLnznHPgIuWYwY8D0zWoWUwr-H65nHLicMQnG1CdkymojKgOGfyNTEFBXNZN6Qs5LWQEAB1afkYlomOQczJQ8z2kZMKeOBje4pSv4gz4sbn6__P-p6wNN3o85Y--RpkiZgkOi0LanBd-wH96rmMZMU9uVS3IaXVfw6nAvyN_7uz-Ln9Xj08Ovxfyx8oLroQpLDSzWDkPgNWghlF8yUFI1jmspY-Od8tIEraPmEKMT4LxsMMjIGxmluCDf972bnF5HLINdt8Vj17ke01isYEoypRppjqPQCGYYl2qL6j3qcyolY7Sb3K5dfrcM7E68XdlP8XYn3u7Fb4PXh41xucbwFfs0vQVu9wBupby1mG3x7U5qaDP6wYbUHtv4AGGolUk</recordid><startdate>20241201</startdate><enddate>20241201</enddate><creator>Schlag, Sarah</creator><creator>Schäfer, Sabrina</creator><creator>Sommer, Katrin</creator><creator>Vetter, Walter</creator><general>Elsevier Ltd</general><scope>6I.</scope><scope>AAFTH</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20241201</creationdate><title>A sterol database: GC/MS data and occurrence of 150 sterols in seventy-four oils</title><author>Schlag, Sarah ; Schäfer, Sabrina ; Sommer, Katrin ; Vetter, Walter</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c326t-db601f8aedd2806335cb105459a2644f9ca5c47d66f620ffa30ac49ed4f294f43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>biosynthesis</topic><topic>Calophyllum inophyllum</topic><topic>carbon</topic><topic>Databases, Factual</topic><topic>eggplants</topic><topic>food chemistry</topic><topic>gas chromatography</topic><topic>Gas Chromatography-Mass Spectrometry</topic><topic>GC/MS</topic><topic>Hydrogenation</topic><topic>mass spectrometry</topic><topic>Moringa</topic><topic>oils</topic><topic>Phytosterol</topic><topic>Plant Oils - chemistry</topic><topic>product authenticity</topic><topic>rice bran</topic><topic>sterols</topic><topic>Sterols - analysis</topic><topic>Sterols - chemistry</topic><topic>Triterpenol</topic><topic>Vegetable oil</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schlag, Sarah</creatorcontrib><creatorcontrib>Schäfer, Sabrina</creatorcontrib><creatorcontrib>Sommer, Katrin</creatorcontrib><creatorcontrib>Vetter, Walter</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Food chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schlag, Sarah</au><au>Schäfer, Sabrina</au><au>Sommer, Katrin</au><au>Vetter, Walter</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A sterol database: GC/MS data and occurrence of 150 sterols in seventy-four oils</atitle><jtitle>Food chemistry</jtitle><addtitle>Food Chem</addtitle><date>2024-12-01</date><risdate>2024</risdate><volume>460</volume><issue>Pt 3</issue><spage>140778</spage><pages>140778-</pages><artnum>140778</artnum><issn>0308-8146</issn><issn>1873-7072</issn><eissn>1873-7072</eissn><abstract>Comprehensive data on the occurrence of sterols in plant oils is currently hardly available since only a few sterols are obtainable as standard compounds. Accordingly, many peaks are rarely labeled in gas chromatograms due to missing or outdated information. This lack of information hampers the progress in sterol research. For this reason, gas chromatography with mass spectrometry in selected ion monitoring mode (GC/MS-SIM) was used to create a database that summarizes the occurrence and semi-quantitative levels of 150 sterols with 27–32 carbon atoms and 0–4 double bonds in 66 different vegetable oils and eight other matrices. The highest number of sterols was detected in rice bran and tamanu oil (40 sterols), eggplant (39 sterols), moringa, chili seed, and amaranth oil (37 sterols). Several sterols were detected in >60 of the 74 matrices. This detailed information in the database will serve users working in food authentication and the biosynthesis of sterols.
•A database reports semi-quantitative data of 150 sterols in 74 sample matrices.•GC/MS-SIM enabled the detection of 11 to 40 sterols per sample matrix.•The highest sterol number was detected in rice bran oil, tamanu oil, and eggplant.•15 different sterols contributed 25% to the sterol pattern of one or more samples.•Ten sterols were detected in >66 of the 74 sample matrices.</abstract><cop>England</cop><pub>Elsevier Ltd</pub><pmid>39142207</pmid><doi>10.1016/j.foodchem.2024.140778</doi><oa>free_for_read</oa></addata></record> |
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subjects | biosynthesis Calophyllum inophyllum carbon Databases, Factual eggplants food chemistry gas chromatography Gas Chromatography-Mass Spectrometry GC/MS Hydrogenation mass spectrometry Moringa oils Phytosterol Plant Oils - chemistry product authenticity rice bran sterols Sterols - analysis Sterols - chemistry Triterpenol Vegetable oil |
title | A sterol database: GC/MS data and occurrence of 150 sterols in seventy-four oils |
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