Composite biopolymer foams fabricated from natural aldehyde functionalized chitosan-whey protein amyloid fibrils: Application for removal of phthalate esters from water
In this work, composite biopolymer foams from chitosan and whey isolate protein amyloid fibrils were prepared for the removal of phthalate esters from water. Natural aldehyde functionalization enhanced the affinity for dibutyl phthalate (DBP), with citral being the most effective. The citral-grafted...
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| Veröffentlicht in: | Carbohydrate polymers 2025-01, Vol.348 (Pt A), p.122789, Article 122789 |
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| creator | Wang, Jilong Lin, Qianzhu Qiu, Chao McClements, David Julian Ji, Hangyan Jin, Zhengyu |
| description | In this work, composite biopolymer foams from chitosan and whey isolate protein amyloid fibrils were prepared for the removal of phthalate esters from water. Natural aldehyde functionalization enhanced the affinity for dibutyl phthalate (DBP), with citral being the most effective. The citral-grafted foams (WCGC) had tunable hydrophobicity, strong mechanical properties, and good water stability. WCGC1.5 foam exhibited a high removal efficiency (96.06 %) of DBP. The adsorption process reached adsorption equilibrium rapidly within 8 h and could be described by pseudo-second-order kinetic and Freundlich isotherm models, indicating a non-homogeneous and chemisorptive sorption process. The maximum adsorption capacity for DBP reached 332.42 mg/g. Moreover, DBP adsorption could be enhanced in alkaline environment and the removal efficiency increased to 98.27 % at pH 10. The removal efficiency of DBP by WCGC1.5 remained above 85 % after the five adsorption-desorption cycles. WCGC1.5 also showed broad-spectrum adsorption behavior, with strong affinity and removal efficiency for six common plasticizers, including DIBP (85.97 %), DPP (91.7 %), DHXP (99.1 %), DEHP (99.09 %), DNOP (91.6 %) and BBP (89.88 %).
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| doi_str_mv | 10.1016/j.carbpol.2024.122789 |
| format | Article |
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[Display omitted]</description><identifier>ISSN: 0144-8617</identifier><identifier>ISSN: 1879-1344</identifier><identifier>EISSN: 1879-1344</identifier><identifier>DOI: 10.1016/j.carbpol.2024.122789</identifier><identifier>PMID: 39562067</identifier><language>eng</language><publisher>England: Elsevier Ltd</publisher><subject>Adsorption ; Aldehydes - chemistry ; amyloid ; Amyloid - chemistry ; Biopolymer foams ; biopolymers ; Biopolymers - chemistry ; chitosan ; Chitosan - chemistry ; citral ; dibutyl phthalate ; Dibutyl Phthalate - chemistry ; Esters - chemistry ; foams ; Hydrogen-Ion Concentration ; hydrophobicity ; Kinetics ; Nature-derived adsorbents ; Phthalate esters ; Phthalic Acids - chemistry ; Pollutants ; sorption isotherms ; Water - chemistry ; Water Pollutants, Chemical - chemistry ; Water Pollutants, Chemical - isolation & purification ; Water Purification - methods ; Water remediation ; whey ; Whey Proteins - chemistry</subject><ispartof>Carbohydrate polymers, 2025-01, Vol.348 (Pt A), p.122789, Article 122789</ispartof><rights>2024</rights><rights>Copyright © 2024. Published by Elsevier Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c276t-ec67d0e0684823d7a600a495f87b533e5306e5d1501fffc001f8ef05e15063a53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0144861724010154$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39562067$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Jilong</creatorcontrib><creatorcontrib>Lin, Qianzhu</creatorcontrib><creatorcontrib>Qiu, Chao</creatorcontrib><creatorcontrib>McClements, David Julian</creatorcontrib><creatorcontrib>Ji, Hangyan</creatorcontrib><creatorcontrib>Jin, Zhengyu</creatorcontrib><title>Composite biopolymer foams fabricated from natural aldehyde functionalized chitosan-whey protein amyloid fibrils: Application for removal of phthalate esters from water</title><title>Carbohydrate polymers</title><addtitle>Carbohydr Polym</addtitle><description>In this work, composite biopolymer foams from chitosan and whey isolate protein amyloid fibrils were prepared for the removal of phthalate esters from water. Natural aldehyde functionalization enhanced the affinity for dibutyl phthalate (DBP), with citral being the most effective. The citral-grafted foams (WCGC) had tunable hydrophobicity, strong mechanical properties, and good water stability. WCGC1.5 foam exhibited a high removal efficiency (96.06 %) of DBP. The adsorption process reached adsorption equilibrium rapidly within 8 h and could be described by pseudo-second-order kinetic and Freundlich isotherm models, indicating a non-homogeneous and chemisorptive sorption process. The maximum adsorption capacity for DBP reached 332.42 mg/g. Moreover, DBP adsorption could be enhanced in alkaline environment and the removal efficiency increased to 98.27 % at pH 10. The removal efficiency of DBP by WCGC1.5 remained above 85 % after the five adsorption-desorption cycles. WCGC1.5 also showed broad-spectrum adsorption behavior, with strong affinity and removal efficiency for six common plasticizers, including DIBP (85.97 %), DPP (91.7 %), DHXP (99.1 %), DEHP (99.09 %), DNOP (91.6 %) and BBP (89.88 %).
[Display omitted]</description><subject>Adsorption</subject><subject>Aldehydes - chemistry</subject><subject>amyloid</subject><subject>Amyloid - chemistry</subject><subject>Biopolymer foams</subject><subject>biopolymers</subject><subject>Biopolymers - chemistry</subject><subject>chitosan</subject><subject>Chitosan - chemistry</subject><subject>citral</subject><subject>dibutyl phthalate</subject><subject>Dibutyl Phthalate - chemistry</subject><subject>Esters - chemistry</subject><subject>foams</subject><subject>Hydrogen-Ion Concentration</subject><subject>hydrophobicity</subject><subject>Kinetics</subject><subject>Nature-derived adsorbents</subject><subject>Phthalate esters</subject><subject>Phthalic Acids - chemistry</subject><subject>Pollutants</subject><subject>sorption isotherms</subject><subject>Water - chemistry</subject><subject>Water Pollutants, Chemical - chemistry</subject><subject>Water Pollutants, Chemical - isolation & purification</subject><subject>Water Purification - methods</subject><subject>Water remediation</subject><subject>whey</subject><subject>Whey Proteins - chemistry</subject><issn>0144-8617</issn><issn>1879-1344</issn><issn>1879-1344</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2025</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkUGP1SAUhYnROG9Gf4KGpZs-oVBK3ZjJizomk7jRNaH0kvJCSwXeTDq_yJ8pL326VTY3ufnOOTcchN5QsqeEivfHvdGxX4Lf16Tme1rXreyeoR2VbVdRxvlztCOU80oK2l6h65SOpDxByUt0xbpG1ES0O_TrEKYlJJcB9y4Uu3WCiG3QU8JW99EZnWHANoYJzzqfovZY-wHGdQBsT7PJLszau6cCmdHlkPRcPY6w4iWGDG7Gelp9cMXCFTefPuDbZfFn2yIsQRFHmMJDsQ0WL2MetS-JGFKGmLbcx7KIr9ALq32C15d5g358_vT9cFfdf_vy9XB7X5m6FbkCI9qBABGSy5oNrRaEaN41VrZ9wxg0jAhoBtoQaq01pAwJljRQNoLpht2gd5tvuf_nqZyhJpcMeK9nCKekGG2YrHnN2X-gjMi67bgsaLOhJoaUIli1RDfpuCpK1LlPdVSXPtW5T7X1WXRvLxGnfoLhr-pPgQX4uAFQ_uTBQVTJOJgNDC6CyWoI7h8RvwGdZ7f5</recordid><startdate>20250115</startdate><enddate>20250115</enddate><creator>Wang, Jilong</creator><creator>Lin, Qianzhu</creator><creator>Qiu, Chao</creator><creator>McClements, David Julian</creator><creator>Ji, Hangyan</creator><creator>Jin, Zhengyu</creator><general>Elsevier Ltd</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20250115</creationdate><title>Composite biopolymer foams fabricated from natural aldehyde functionalized chitosan-whey protein amyloid fibrils: Application for removal of phthalate esters from water</title><author>Wang, Jilong ; Lin, Qianzhu ; Qiu, Chao ; McClements, David Julian ; Ji, Hangyan ; Jin, Zhengyu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c276t-ec67d0e0684823d7a600a495f87b533e5306e5d1501fffc001f8ef05e15063a53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2025</creationdate><topic>Adsorption</topic><topic>Aldehydes - chemistry</topic><topic>amyloid</topic><topic>Amyloid - chemistry</topic><topic>Biopolymer foams</topic><topic>biopolymers</topic><topic>Biopolymers - chemistry</topic><topic>chitosan</topic><topic>Chitosan - chemistry</topic><topic>citral</topic><topic>dibutyl phthalate</topic><topic>Dibutyl Phthalate - chemistry</topic><topic>Esters - chemistry</topic><topic>foams</topic><topic>Hydrogen-Ion Concentration</topic><topic>hydrophobicity</topic><topic>Kinetics</topic><topic>Nature-derived adsorbents</topic><topic>Phthalate esters</topic><topic>Phthalic Acids - chemistry</topic><topic>Pollutants</topic><topic>sorption isotherms</topic><topic>Water - chemistry</topic><topic>Water Pollutants, Chemical - chemistry</topic><topic>Water Pollutants, Chemical - isolation & purification</topic><topic>Water Purification - methods</topic><topic>Water remediation</topic><topic>whey</topic><topic>Whey Proteins - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Jilong</creatorcontrib><creatorcontrib>Lin, Qianzhu</creatorcontrib><creatorcontrib>Qiu, Chao</creatorcontrib><creatorcontrib>McClements, David Julian</creatorcontrib><creatorcontrib>Ji, Hangyan</creatorcontrib><creatorcontrib>Jin, Zhengyu</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Carbohydrate polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Jilong</au><au>Lin, Qianzhu</au><au>Qiu, Chao</au><au>McClements, David Julian</au><au>Ji, Hangyan</au><au>Jin, Zhengyu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Composite biopolymer foams fabricated from natural aldehyde functionalized chitosan-whey protein amyloid fibrils: Application for removal of phthalate esters from water</atitle><jtitle>Carbohydrate polymers</jtitle><addtitle>Carbohydr Polym</addtitle><date>2025-01-15</date><risdate>2025</risdate><volume>348</volume><issue>Pt A</issue><spage>122789</spage><pages>122789-</pages><artnum>122789</artnum><issn>0144-8617</issn><issn>1879-1344</issn><eissn>1879-1344</eissn><abstract>In this work, composite biopolymer foams from chitosan and whey isolate protein amyloid fibrils were prepared for the removal of phthalate esters from water. Natural aldehyde functionalization enhanced the affinity for dibutyl phthalate (DBP), with citral being the most effective. The citral-grafted foams (WCGC) had tunable hydrophobicity, strong mechanical properties, and good water stability. WCGC1.5 foam exhibited a high removal efficiency (96.06 %) of DBP. The adsorption process reached adsorption equilibrium rapidly within 8 h and could be described by pseudo-second-order kinetic and Freundlich isotherm models, indicating a non-homogeneous and chemisorptive sorption process. The maximum adsorption capacity for DBP reached 332.42 mg/g. Moreover, DBP adsorption could be enhanced in alkaline environment and the removal efficiency increased to 98.27 % at pH 10. The removal efficiency of DBP by WCGC1.5 remained above 85 % after the five adsorption-desorption cycles. WCGC1.5 also showed broad-spectrum adsorption behavior, with strong affinity and removal efficiency for six common plasticizers, including DIBP (85.97 %), DPP (91.7 %), DHXP (99.1 %), DEHP (99.09 %), DNOP (91.6 %) and BBP (89.88 %).
[Display omitted]</abstract><cop>England</cop><pub>Elsevier Ltd</pub><pmid>39562067</pmid><doi>10.1016/j.carbpol.2024.122789</doi></addata></record> |
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| subjects | Adsorption Aldehydes - chemistry amyloid Amyloid - chemistry Biopolymer foams biopolymers Biopolymers - chemistry chitosan Chitosan - chemistry citral dibutyl phthalate Dibutyl Phthalate - chemistry Esters - chemistry foams Hydrogen-Ion Concentration hydrophobicity Kinetics Nature-derived adsorbents Phthalate esters Phthalic Acids - chemistry Pollutants sorption isotherms Water - chemistry Water Pollutants, Chemical - chemistry Water Pollutants, Chemical - isolation & purification Water Purification - methods Water remediation whey Whey Proteins - chemistry |
| title | Composite biopolymer foams fabricated from natural aldehyde functionalized chitosan-whey protein amyloid fibrils: Application for removal of phthalate esters from water |
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