Unveiling the hydroesterification of 1,3-butadiene with carbonyl cobalt ionic liquids: Facilitation of cationic protonic hydrogen for active species formation

[Display omitted] •Hydroesterification of 1,3-butadiene under lower pressure catalyzed by carbonyl cobalt ionic liquid.•Formation of the active species HCo(CO)4 through proton exchange between anions and cations in ionic liquids.•Qualitative kinetics for hydroesterification process was established....

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Veröffentlicht in:	Journal of catalysis 2024-06, Vol.434, p.115525, Article 115525
Hauptverfasser:	Wang, Liwen, Zhao, Zhihao, Wang, Saidi, Zhou, Wenxuan, Lu, Xingmei, Yan, Ruiyi, Xin, Jiayu
Format:	Artikel
Sprache:	eng
Schlagworte:	1,3-Butadiene Carbonyl cobalt ionic liquids catalytic activity Cationic protonic hydrogen cations cobalt cost effectiveness dissociation esters Hydroesterification hydrogen nylon Reaction kinetics reaction mechanisms regioselectivity species
Online-Zugang:	Volltext
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