Synthesis of New A-Seco-Derivatives of Methyl Glycyrrhetinate

New A-seco-derivatives of methyl glycyrrhetinate (MeGLC) were synthesized. Cleavage of ring A of the 2-hydroxymethylene-3-oxo-derivative of MeGLC by H 2 O 2 (30%) in the presence of NaOMe (28%) in MeOH led to the 2,3-seco-2,3-diacid, which was isolated as the dimethyl ester. Ozonolysis of the 2-hydr...

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Veröffentlicht in:	Chemistry of natural compounds 2024-07, Vol.60 (4), p.657-661
Hauptverfasser:	Karimova, E. R., Baltina, L. A., Nugumanov, T. R., Medvedeva, N. I., Spirikhin, L. V., Kukovinets, O. S.
Format:	Artikel
Sprache:	eng
Schlagworte:	acids Chemistry Chemistry and Materials Science Chemistry/Food Science Esters Hydrogen peroxide Organic Chemistry ozonolysis Plant Sciences
Online-Zugang:	Volltext
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