Optical and electrical properties of ZnO/NiO heterojunctions obtained by the spray-pyrolysis method

In this work, the effect of thermal annealing on the phase composition, surface morphology, and structural, substructural, optical, and electrical properties of multilayer structures based on p -NiO/ n -ZnO heterojunctions obtained by spraying molecular solutions (spray-pyrolysis) is determined. Aft...

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Veröffentlicht in:Journal of materials science 2024-09, Vol.59 (33), p.15738-15751
Hauptverfasser: Yermakov, Maksym, Pshenychnyi, Roman, Opanasyuk, Anatoliy, Klymov, Oleksii, Muñoz-Sanjosé, Vicente
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container_end_page 15751
container_issue 33
container_start_page 15738
container_title Journal of materials science
container_volume 59
creator Yermakov, Maksym
Pshenychnyi, Roman
Opanasyuk, Anatoliy
Klymov, Oleksii
Muñoz-Sanjosé, Vicente
description In this work, the effect of thermal annealing on the phase composition, surface morphology, and structural, substructural, optical, and electrical properties of multilayer structures based on p -NiO/ n -ZnO heterojunctions obtained by spraying molecular solutions (spray-pyrolysis) is determined. After deposition, the samples were annealed in vacuum at temperatures of 300, 400, 500 °C during 60 min. The multilayer structure was studied using X-ray diffraction analysis, scanning electron microscopy, Hall effect, and optical spectroscopy. The dark current–voltage characteristics of the heterojunctions were also measured. These studies made it possible to determine the main structural, morphological, electrical, and optical properties of the films, such as crystal lattice parameters, dimensions of the coherent scattering regions, microdeformation level, density of dislocations, and band gap width depending on the annealing temperature. The energy band diagram of heterojunctions was constructed from the Anderson and Van Ruyven models.
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subjects Annealing
Characterization and Evaluation of Materials
Chemistry and Materials Science
Classical Mechanics
Coherent scattering
Composition effects
Crystal dislocations
Crystal lattices
Crystallography and Scattering Methods
Current voltage characteristics
Dark current
Deformation
Dislocation density
Electrical properties
electron microscopy
Electronic Materials
energy
Energy bands
Energy gap
Glass substrates
Hall effect
Heterojunctions
Indium
Lattice parameters
Materials Science
Methods
Morphology
Multilayers
nickel oxide
Nickel oxides
Optical properties
Phase composition
Point defects
Polymer Sciences
Pyrolysis
Radiation
Solid Mechanics
spectroscopy
Spraying
Temperature
X-ray diffraction
Zinc oxide
Zinc oxides
title Optical and electrical properties of ZnO/NiO heterojunctions obtained by the spray-pyrolysis method
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