Buffering Donor Shuttles in Proton-Coupled Electron Transfer Kinetics for Electrochemical Hydrogenation of Hydroxyacetone to Propylene Glycol

Electrochemical hydrogenation reactions demand rapid proton-coupled electron transfer at the electrode surface, the kinetics of which depend closely on pH. Buffer electrolytes are extensively employed to regulate pH over a wide range. However, the specific role of buffer species should be taken into...

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Veröffentlicht in:	Journal of the American Chemical Society 2024-08, Vol.146 (33), p.23194-23204
Hauptverfasser:	Ma, Guoquan, Jiang, Na, Zhang, Yu, Song, Dandan, Qiao, Bo, Xu, Zheng, Zhao, Suling, Liang, Zhiqin
Format:	Artikel
Sprache:	eng
Schlagworte:	borates citrates electrochemistry electrodes electron transfer feedstocks glycerol hydrogenation phosphates propylene glycol species
Online-Zugang:	Volltext
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