A Sodium Germanosilicide with Unusual Network Topology

The germanosilicide Na4– x Ge y Si16–y (0.4 ≤ x ≤ 1.1, 4.7 ≤ y ≤ 9.3) was synthesized under high-pressure, high-temperature conditions. The novel guest–host compound comprises a unique tetrel framework with dual channels housing sodium and smaller, empty (Si,Ge)9 units. The arrangement represents a...

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Veröffentlicht in:	Journal of the American Chemical Society 2024-07, Vol.146 (30), p.20544-20549
Hauptverfasser:	Hübner, Julia-Maria, Shiell, Thomas B., Guńka, Piotr A., Tao, Shuo, Zhu, Li, Hansen, Mads Fonager, Bullock, Emma S., Chariton, Stella, Prakapenka, Vitali B., Fei, Yingwei, Blatov, Vladislav A., Proserpio, Davide M., Strobel, Timothy A.
Format:	Artikel
Sprache:	eng
Schlagworte:	cages carbon sodium topology
Online-Zugang:	Volltext
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