Multi-component volatile organic compounds (VOCs) treatment nexus: High-performance of activated carbon derived from residual agroforestry biomass
Epilobium montanum, agroforestry residue biomass, produced low-cost activated carbon using the acidic chemical activating agent. The aim of this study is to explore the changes that occur in E. montanum during activation with H 3 PO 4 . The microstructures of the formed phosphoric acid-treated fibro...
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description | Epilobium montanum,
agroforestry residue biomass, produced low-cost activated carbon using the acidic chemical activating agent. The aim of this study is to explore the changes that occur in
E. montanum
during activation with H
3
PO
4
. The microstructures of the formed phosphoric acid-treated fibrous lignocellulosic-derived activated carbon (EM38-AC) are determined by Brunauer, Emmett and Teller, X-ray diffraction analysis, thermogravimetric analysis, scanning electron microscope, and Fourier transformed infrared spectroscopy methods. The EM38-AC with maximum surface area and total pore volume of 835 m
2
/g and 0.48 cm
3
as environmentally friendly material were prepared at 700 °C, activation time of 150 min, and H
3
PO
4
impregnation ratio of 3:1. The EM38-ACs have tested BTEX adsorption and the equilibrium capacities of benzene, toluene, ethylbenzene, and xylene at 20 °C and 30% RH were 112, 126, 119, and 84 mg/g for multi-system. Multi-component BTEX adsorption capacity decreased significantly with the increasing temperature and humidity. The adsorption of the BTEX mixture on EM38-ACs decreased by 28.5–35.4%, compared to the relative humidity of 30 and 90%. Also, the reusability of EM38-ACs showed good thermal regeneration and fell to 84.55% after seven cycles. Here the direct result revealed that EM38-ACs showed the largest BET surface area and the best adsorption capacity. Finally, utilizing these renewable feedstocks presents us with the avenues to realize sustainable synthesis through the green process and the purpose of a sustainable future in indoor air quality.
Graphical abstract |
doi_str_mv | 10.1007/s13762-023-05202-2 |
format | Article |
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agroforestry residue biomass, produced low-cost activated carbon using the acidic chemical activating agent. The aim of this study is to explore the changes that occur in
E. montanum
during activation with H
3
PO
4
. The microstructures of the formed phosphoric acid-treated fibrous lignocellulosic-derived activated carbon (EM38-AC) are determined by Brunauer, Emmett and Teller, X-ray diffraction analysis, thermogravimetric analysis, scanning electron microscope, and Fourier transformed infrared spectroscopy methods. The EM38-AC with maximum surface area and total pore volume of 835 m
2
/g and 0.48 cm
3
as environmentally friendly material were prepared at 700 °C, activation time of 150 min, and H
3
PO
4
impregnation ratio of 3:1. The EM38-ACs have tested BTEX adsorption and the equilibrium capacities of benzene, toluene, ethylbenzene, and xylene at 20 °C and 30% RH were 112, 126, 119, and 84 mg/g for multi-system. Multi-component BTEX adsorption capacity decreased significantly with the increasing temperature and humidity. The adsorption of the BTEX mixture on EM38-ACs decreased by 28.5–35.4%, compared to the relative humidity of 30 and 90%. Also, the reusability of EM38-ACs showed good thermal regeneration and fell to 84.55% after seven cycles. Here the direct result revealed that EM38-ACs showed the largest BET surface area and the best adsorption capacity. Finally, utilizing these renewable feedstocks presents us with the avenues to realize sustainable synthesis through the green process and the purpose of a sustainable future in indoor air quality.
Graphical abstract</description><identifier>ISSN: 1735-1472</identifier><identifier>EISSN: 1735-2630</identifier><identifier>DOI: 10.1007/s13762-023-05202-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>activated carbon ; adsorption ; agroforestry ; air quality ; Aquatic Pollution ; benzene ; biomass ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Science and Engineering ; Epilobium ; ethylbenzene ; feedstocks ; Original Paper ; relative humidity ; Soil Science & Conservation ; surface area ; temperature ; thermogravimetry ; toluene ; volatile organic compounds ; Waste Water Technology ; Water Management ; Water Pollution Control ; X-ray diffraction ; xylene</subject><ispartof>International journal of environmental science and technology (Tehran), 2024, Vol.21 (1), p.925-938</ispartof><rights>The Author(s) under exclusive licence to Iranian Society of Environmentalists (IRSEN) and Science and Research Branch, Islamic Azad University 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c324t-9a0374579e463ad1ae7f14f5532cbed65f583e99a3ec752731102dac43a3b63f3</citedby><cites>FETCH-LOGICAL-c324t-9a0374579e463ad1ae7f14f5532cbed65f583e99a3ec752731102dac43a3b63f3</cites><orcidid>0000-0003-1850-7515</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13762-023-05202-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13762-023-05202-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27911,27912,41475,42544,51306</link.rule.ids></links><search><creatorcontrib>Isinkaralar, K.</creatorcontrib><title>Multi-component volatile organic compounds (VOCs) treatment nexus: High-performance of activated carbon derived from residual agroforestry biomass</title><title>International journal of environmental science and technology (Tehran)</title><addtitle>Int. J. Environ. Sci. Technol</addtitle><description>Epilobium montanum,
agroforestry residue biomass, produced low-cost activated carbon using the acidic chemical activating agent. The aim of this study is to explore the changes that occur in
E. montanum
during activation with H
3
PO
4
. The microstructures of the formed phosphoric acid-treated fibrous lignocellulosic-derived activated carbon (EM38-AC) are determined by Brunauer, Emmett and Teller, X-ray diffraction analysis, thermogravimetric analysis, scanning electron microscope, and Fourier transformed infrared spectroscopy methods. The EM38-AC with maximum surface area and total pore volume of 835 m
2
/g and 0.48 cm
3
as environmentally friendly material were prepared at 700 °C, activation time of 150 min, and H
3
PO
4
impregnation ratio of 3:1. The EM38-ACs have tested BTEX adsorption and the equilibrium capacities of benzene, toluene, ethylbenzene, and xylene at 20 °C and 30% RH were 112, 126, 119, and 84 mg/g for multi-system. Multi-component BTEX adsorption capacity decreased significantly with the increasing temperature and humidity. The adsorption of the BTEX mixture on EM38-ACs decreased by 28.5–35.4%, compared to the relative humidity of 30 and 90%. Also, the reusability of EM38-ACs showed good thermal regeneration and fell to 84.55% after seven cycles. Here the direct result revealed that EM38-ACs showed the largest BET surface area and the best adsorption capacity. Finally, utilizing these renewable feedstocks presents us with the avenues to realize sustainable synthesis through the green process and the purpose of a sustainable future in indoor air quality.
Graphical abstract</description><subject>activated carbon</subject><subject>adsorption</subject><subject>agroforestry</subject><subject>air quality</subject><subject>Aquatic Pollution</subject><subject>benzene</subject><subject>biomass</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Science and Engineering</subject><subject>Epilobium</subject><subject>ethylbenzene</subject><subject>feedstocks</subject><subject>Original Paper</subject><subject>relative humidity</subject><subject>Soil Science & Conservation</subject><subject>surface area</subject><subject>temperature</subject><subject>thermogravimetry</subject><subject>toluene</subject><subject>volatile organic compounds</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><subject>X-ray diffraction</subject><subject>xylene</subject><issn>1735-1472</issn><issn>1735-2630</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kUFuFDEQRVsIJELCBVh5GRYmtstuZ9ihESFIQdmQbK0ad_XgqNsebPcoOQcXyFk4GU4ma1Yuq94rVel33QcpPkkh7FmRYHvFhQIujBKKq1fdkbRguOpBvH6ppbbqbfeulDshdK-1POr-_FimGrhP8y5FipXt04Q1TMRS3mIMnj23ljgUdnp7vS4fWc2EdX5iI90v5TO7DNtffEd5THnG6Js6_n1EX8MeKw3MY96kyAbKYd--Y04zy1TCsODEcJtT86jU_MA2Ic1Yykn3ZsSp0PuX97i7ufj6c33Jr66_fV9_ueIelK58hQKsNnZFugccJJIdpR6NAeU3NPRmNOdAqxUCeWuUBSmFGtBrQNj0MMJxd3qYu8vp99JWcHMonqYJI6WlOJAGrDjvjW6oOqA-p1IyjW6Xw4z5wUnhnhJwhwRcS8A9J-BUk-AglQbHLWV3l5Yc20n_s_4BnlONXA</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Isinkaralar, K.</creator><general>Springer Berlin Heidelberg</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0000-0003-1850-7515</orcidid></search><sort><creationdate>2024</creationdate><title>Multi-component volatile organic compounds (VOCs) treatment nexus: High-performance of activated carbon derived from residual agroforestry biomass</title><author>Isinkaralar, K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c324t-9a0374579e463ad1ae7f14f5532cbed65f583e99a3ec752731102dac43a3b63f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>activated carbon</topic><topic>adsorption</topic><topic>agroforestry</topic><topic>air quality</topic><topic>Aquatic Pollution</topic><topic>benzene</topic><topic>biomass</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Science and Engineering</topic><topic>Epilobium</topic><topic>ethylbenzene</topic><topic>feedstocks</topic><topic>Original Paper</topic><topic>relative humidity</topic><topic>Soil Science & Conservation</topic><topic>surface area</topic><topic>temperature</topic><topic>thermogravimetry</topic><topic>toluene</topic><topic>volatile organic compounds</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><topic>X-ray diffraction</topic><topic>xylene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Isinkaralar, K.</creatorcontrib><collection>CrossRef</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>International journal of environmental science and technology (Tehran)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Isinkaralar, K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Multi-component volatile organic compounds (VOCs) treatment nexus: High-performance of activated carbon derived from residual agroforestry biomass</atitle><jtitle>International journal of environmental science and technology (Tehran)</jtitle><stitle>Int. J. Environ. Sci. Technol</stitle><date>2024</date><risdate>2024</risdate><volume>21</volume><issue>1</issue><spage>925</spage><epage>938</epage><pages>925-938</pages><issn>1735-1472</issn><eissn>1735-2630</eissn><abstract>Epilobium montanum,
agroforestry residue biomass, produced low-cost activated carbon using the acidic chemical activating agent. The aim of this study is to explore the changes that occur in
E. montanum
during activation with H
3
PO
4
. The microstructures of the formed phosphoric acid-treated fibrous lignocellulosic-derived activated carbon (EM38-AC) are determined by Brunauer, Emmett and Teller, X-ray diffraction analysis, thermogravimetric analysis, scanning electron microscope, and Fourier transformed infrared spectroscopy methods. The EM38-AC with maximum surface area and total pore volume of 835 m
2
/g and 0.48 cm
3
as environmentally friendly material were prepared at 700 °C, activation time of 150 min, and H
3
PO
4
impregnation ratio of 3:1. The EM38-ACs have tested BTEX adsorption and the equilibrium capacities of benzene, toluene, ethylbenzene, and xylene at 20 °C and 30% RH were 112, 126, 119, and 84 mg/g for multi-system. Multi-component BTEX adsorption capacity decreased significantly with the increasing temperature and humidity. The adsorption of the BTEX mixture on EM38-ACs decreased by 28.5–35.4%, compared to the relative humidity of 30 and 90%. Also, the reusability of EM38-ACs showed good thermal regeneration and fell to 84.55% after seven cycles. Here the direct result revealed that EM38-ACs showed the largest BET surface area and the best adsorption capacity. Finally, utilizing these renewable feedstocks presents us with the avenues to realize sustainable synthesis through the green process and the purpose of a sustainable future in indoor air quality.
Graphical abstract</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13762-023-05202-2</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0003-1850-7515</orcidid></addata></record> |
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subjects | activated carbon adsorption agroforestry air quality Aquatic Pollution benzene biomass Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Science and Engineering Epilobium ethylbenzene feedstocks Original Paper relative humidity Soil Science & Conservation surface area temperature thermogravimetry toluene volatile organic compounds Waste Water Technology Water Management Water Pollution Control X-ray diffraction xylene |
title | Multi-component volatile organic compounds (VOCs) treatment nexus: High-performance of activated carbon derived from residual agroforestry biomass |
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