Aromatic Ring-Fused Dipyrrins: Programmed [4 + 2]-Cycloaddition Pathway with Regio-selectivity upon Alkylamino-Substitution

Sulfolenodipyrrins are employed as building blocks to concisely and efficiently construct aromatic rings (e.g., naphthoquinone, anthraquinone, fullerenes, and phthalimide) from fused dipyrrins by programmed [4 + 2]-cycloaddition reactions. Notably, alkylamino-substitution at the α-position not only...

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Veröffentlicht in:Journal of organic chemistry 2023-12, Vol.88 (24), p.17381-17388
Hauptverfasser: Liu, Jiayang, Wang, Yuanyuan, Qiu, Ning, Liu, Xiujun, Li, Qizhao, Li, Yuxin, Wu, Xin-Yan, Li, Chengjie
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Sprache:eng
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