Synthesis of Thiourea and Thioamide S‑Oxides via SO Transfer from a Thiirane S‑Oxide onto N‑Heterocyclic Carbenes

Thiourea S-oxides are labile compounds that suffer from a quick overoxidation when directly prepared from thioureas. Therefore, we have developed an alternative route on the basis of the SO transfer from a thiirane S-oxide onto sterically encumbered N-heterocyclic carbenes, including imidazole- and...

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Veröffentlicht in:	Organic letters 2024-07, Vol.26 (27), p.5868-5872
Hauptverfasser:	Medvedko, Serhii, Ströbele, Markus, Fechter, Maike, Fischer, Antonia, Hettiger, Theresa, Idzko, Paul, Scheele, Marcus, Wagner, J. Philipp
Format:	Artikel
Sprache:	eng
Schlagworte:	carbenes heterocyclic nitrogen compounds Lewis bases thiourea
Online-Zugang:	Volltext
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