Catalyst Editing via Post-Synthetic Functionalization by Phosphonium Generation and Anion Exchange for Nickel-Catalyzed Ethylene/Acrylate Copolymerization

Rapid, efficient development of homogeneous catalysts featuring desired performance is critical to numerous catalytic transformations but remains a key challenge. Typically, this task relies heavily on ligand design that is often based on trial and error. Herein, we demonstrate a “catalyst editing”...

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Veröffentlicht in:	Journal of the American Chemical Society 2024-07, Vol.146 (28), p.18797-18803
Hauptverfasser:	Ghana, Priyabrata, Xiong, Shuoyan, Tekpor, Adjeoda, Bailey, Brad C., Spinney, Heather A., Henderson, Briana S., Agapie, Theodor
Format:	Artikel
Sprache:	eng
Schlagworte:	alkylation anion exchange catalysts copolymerization ethylene Lewis acids ligands phosphine
Online-Zugang:	Volltext
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