Diels-Alder clickable furan-thiosemicarbazide cellulose for selective ruthenium (III) imprinting
Developing an efficient adsorbent for Ru3+ ions in wastewater is crucial for both environmental protection and resource recovery. This study introduces a novel approach using cellulose-based adsorbents, specifically modified with furan-thiosemicarbazide (FTC), to enhance their selectivity for Ru3+ i...
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| Veröffentlicht in: | International journal of biological macromolecules 2024-04, Vol.263 (Pt 1), p.130255-130255, Article 130255 |
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| container_title | International journal of biological macromolecules |
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| creator | Aljohani, Majed S. Alnoman, Rua B. Alharbi, Hussam Y. Alnawmasi, Jawza Sh Monier, M. |
| description | Developing an efficient adsorbent for Ru3+ ions in wastewater is crucial for both environmental protection and resource recovery. This study introduces a novel approach using cellulose-based adsorbents, specifically modified with furan-thiosemicarbazide (FTC), to enhance their selectivity for Ru3+ ions. By cross-linking the Ru3+/FTC-modified cellulose (FTC-CE) complex with a bis(maleimido)ethane (BME) cross-linker, we created a Ru3+ ion-imprinted sorbent (Ru-II-CE) that exhibits a strong affinity and selectivity for Ru3+ ions. The synthesis process was thoroughly characterized using NMR and FTIR spectroscopy, while the surface morphology of the sorbent particles was examined with scanning electron microscopy. The Ru-II-CE sorbent demonstrated exceptional selectivity for Ru3+ among competing metal cations, achieving optimal adsorption at a pH of 5. Its adsorption capacity was notably high at 215 mg/g, fitting well with the Langmuir isotherm model, and it followed pseudo-second-order kinetics. This study highlights the potential of FTC-CE for targeted Ru3+ removal from wastewater, offering a promising solution for heavy metal decontamination.
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| doi_str_mv | 10.1016/j.ijbiomac.2024.130255 |
| format | Article |
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[Display omitted]</description><identifier>ISSN: 0141-8130</identifier><identifier>EISSN: 1879-0003</identifier><identifier>DOI: 10.1016/j.ijbiomac.2024.130255</identifier><identifier>PMID: 38368988</identifier><language>eng</language><publisher>Netherlands: Elsevier B.V</publisher><subject>adsorbents ; Adsorption ; Cellulose ; Cellulose - chemistry ; crosslinking ; cycloaddition reactions ; decontamination ; electron microscopy ; environmental protection ; ethane ; Fourier transform infrared spectroscopy ; Furan-thiosemicarbazide ; heavy metals ; Hydrogen-Ion Concentration ; Ion-imprinting ; Ions ; Kinetics ; Ruthenium ; Semicarbazides ; sorption isotherms ; Wastewater ; Wastewater Treatment ; Water Pollutants, Chemical - chemistry</subject><ispartof>International journal of biological macromolecules, 2024-04, Vol.263 (Pt 1), p.130255-130255, Article 130255</ispartof><rights>2024 Elsevier B.V.</rights><rights>Copyright © 2024 Elsevier B.V. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c401t-d759c8b23c2af2e3861a98f1fa8513b35171c2e0e9d522e5f106c2356e94495f3</citedby><cites>FETCH-LOGICAL-c401t-d759c8b23c2af2e3861a98f1fa8513b35171c2e0e9d522e5f106c2356e94495f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0141813024010584$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38368988$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Aljohani, Majed S.</creatorcontrib><creatorcontrib>Alnoman, Rua B.</creatorcontrib><creatorcontrib>Alharbi, Hussam Y.</creatorcontrib><creatorcontrib>Alnawmasi, Jawza Sh</creatorcontrib><creatorcontrib>Monier, M.</creatorcontrib><title>Diels-Alder clickable furan-thiosemicarbazide cellulose for selective ruthenium (III) imprinting</title><title>International journal of biological macromolecules</title><addtitle>Int J Biol Macromol</addtitle><description>Developing an efficient adsorbent for Ru3+ ions in wastewater is crucial for both environmental protection and resource recovery. This study introduces a novel approach using cellulose-based adsorbents, specifically modified with furan-thiosemicarbazide (FTC), to enhance their selectivity for Ru3+ ions. By cross-linking the Ru3+/FTC-modified cellulose (FTC-CE) complex with a bis(maleimido)ethane (BME) cross-linker, we created a Ru3+ ion-imprinted sorbent (Ru-II-CE) that exhibits a strong affinity and selectivity for Ru3+ ions. The synthesis process was thoroughly characterized using NMR and FTIR spectroscopy, while the surface morphology of the sorbent particles was examined with scanning electron microscopy. The Ru-II-CE sorbent demonstrated exceptional selectivity for Ru3+ among competing metal cations, achieving optimal adsorption at a pH of 5. Its adsorption capacity was notably high at 215 mg/g, fitting well with the Langmuir isotherm model, and it followed pseudo-second-order kinetics. This study highlights the potential of FTC-CE for targeted Ru3+ removal from wastewater, offering a promising solution for heavy metal decontamination.
[Display omitted]</description><subject>adsorbents</subject><subject>Adsorption</subject><subject>Cellulose</subject><subject>Cellulose - chemistry</subject><subject>crosslinking</subject><subject>cycloaddition reactions</subject><subject>decontamination</subject><subject>electron microscopy</subject><subject>environmental protection</subject><subject>ethane</subject><subject>Fourier transform infrared spectroscopy</subject><subject>Furan-thiosemicarbazide</subject><subject>heavy metals</subject><subject>Hydrogen-Ion Concentration</subject><subject>Ion-imprinting</subject><subject>Ions</subject><subject>Kinetics</subject><subject>Ruthenium</subject><subject>Semicarbazides</subject><subject>sorption isotherms</subject><subject>Wastewater</subject><subject>Wastewater Treatment</subject><subject>Water Pollutants, Chemical - chemistry</subject><issn>0141-8130</issn><issn>1879-0003</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkU1P3DAQhi0Egi3tX0A5wiFbjx079g1EoV0JiQs9u44zLt46CdgJUvvr8WqhV04jzTzz9b6EnAFdAwX5dbsO2y5Mg3VrRlmzBk6ZEAdkBarVNaWUH5IVhQZqVUon5FPO25KVAtQxOeGKS6WVWpFf3wLGXF_FHlPlYnB_bBex8kuyYz0_hinjEJxNnf0XeqwcxrjEkqz8lKqMEd0cXrBKy_yIY1iG6nyz2VxUYXhKYZzD-PszOfI2ZvzyFk_Jz9ubh-sf9d3998311V3tGgpz3bdCO9Ux7pj1DLmSYLXy4K0SwDsuoAXHkKLuBWMoPFDpGBcSddNo4fkpOd_PfUrT84J5NkPIu3PtiNOSDQfBJWubVnyIMs2UULLRUFC5R12ack7oTflrsOmvAWp2RpiteTfC7IwweyNK49nbjqUbsP_f9q58AS73QJEfXwImk13A0WEfUhHV9FP4aMcrHQqcng</recordid><startdate>202404</startdate><enddate>202404</enddate><creator>Aljohani, Majed S.</creator><creator>Alnoman, Rua B.</creator><creator>Alharbi, Hussam Y.</creator><creator>Alnawmasi, Jawza Sh</creator><creator>Monier, M.</creator><general>Elsevier B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>202404</creationdate><title>Diels-Alder clickable furan-thiosemicarbazide cellulose for selective ruthenium (III) imprinting</title><author>Aljohani, Majed S. ; Alnoman, Rua B. ; Alharbi, Hussam Y. ; Alnawmasi, Jawza Sh ; Monier, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c401t-d759c8b23c2af2e3861a98f1fa8513b35171c2e0e9d522e5f106c2356e94495f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>adsorbents</topic><topic>Adsorption</topic><topic>Cellulose</topic><topic>Cellulose - chemistry</topic><topic>crosslinking</topic><topic>cycloaddition reactions</topic><topic>decontamination</topic><topic>electron microscopy</topic><topic>environmental protection</topic><topic>ethane</topic><topic>Fourier transform infrared spectroscopy</topic><topic>Furan-thiosemicarbazide</topic><topic>heavy metals</topic><topic>Hydrogen-Ion Concentration</topic><topic>Ion-imprinting</topic><topic>Ions</topic><topic>Kinetics</topic><topic>Ruthenium</topic><topic>Semicarbazides</topic><topic>sorption isotherms</topic><topic>Wastewater</topic><topic>Wastewater Treatment</topic><topic>Water Pollutants, Chemical - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aljohani, Majed S.</creatorcontrib><creatorcontrib>Alnoman, Rua B.</creatorcontrib><creatorcontrib>Alharbi, Hussam Y.</creatorcontrib><creatorcontrib>Alnawmasi, Jawza Sh</creatorcontrib><creatorcontrib>Monier, M.</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>International journal of biological macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aljohani, Majed S.</au><au>Alnoman, Rua B.</au><au>Alharbi, Hussam Y.</au><au>Alnawmasi, Jawza Sh</au><au>Monier, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Diels-Alder clickable furan-thiosemicarbazide cellulose for selective ruthenium (III) imprinting</atitle><jtitle>International journal of biological macromolecules</jtitle><addtitle>Int J Biol Macromol</addtitle><date>2024-04</date><risdate>2024</risdate><volume>263</volume><issue>Pt 1</issue><spage>130255</spage><epage>130255</epage><pages>130255-130255</pages><artnum>130255</artnum><issn>0141-8130</issn><eissn>1879-0003</eissn><abstract>Developing an efficient adsorbent for Ru3+ ions in wastewater is crucial for both environmental protection and resource recovery. This study introduces a novel approach using cellulose-based adsorbents, specifically modified with furan-thiosemicarbazide (FTC), to enhance their selectivity for Ru3+ ions. By cross-linking the Ru3+/FTC-modified cellulose (FTC-CE) complex with a bis(maleimido)ethane (BME) cross-linker, we created a Ru3+ ion-imprinted sorbent (Ru-II-CE) that exhibits a strong affinity and selectivity for Ru3+ ions. The synthesis process was thoroughly characterized using NMR and FTIR spectroscopy, while the surface morphology of the sorbent particles was examined with scanning electron microscopy. The Ru-II-CE sorbent demonstrated exceptional selectivity for Ru3+ among competing metal cations, achieving optimal adsorption at a pH of 5. Its adsorption capacity was notably high at 215 mg/g, fitting well with the Langmuir isotherm model, and it followed pseudo-second-order kinetics. This study highlights the potential of FTC-CE for targeted Ru3+ removal from wastewater, offering a promising solution for heavy metal decontamination.
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| subjects | adsorbents Adsorption Cellulose Cellulose - chemistry crosslinking cycloaddition reactions decontamination electron microscopy environmental protection ethane Fourier transform infrared spectroscopy Furan-thiosemicarbazide heavy metals Hydrogen-Ion Concentration Ion-imprinting Ions Kinetics Ruthenium Semicarbazides sorption isotherms Wastewater Wastewater Treatment Water Pollutants, Chemical - chemistry |
| title | Diels-Alder clickable furan-thiosemicarbazide cellulose for selective ruthenium (III) imprinting |
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