Musa acuminata free tepal (MAFT) crop- mediated synthesis of copper oxide nanocatalyst (MAFT-CuO nanocatalyst): Investigation of aerobic oxidation and dye decolourization via eco-friendly approach
Crop development is used to address environmental problems in the industry. Environmental pollutants, particularly humble or toxic chemicals and dyes, are contaminants in industrial wastewater. Recently, green technology has become important for controlling the chemical risks associated with environ...
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description | Crop development is used to address environmental problems in the industry. Environmental pollutants, particularly humble or toxic chemicals and dyes, are contaminants in industrial wastewater. Recently, green technology has become important for controlling the chemical risks associated with environmental issues. This study focused on valuable crop materials to form green catalysts that can be used to control chemical toxicity in industrial wastewater. In this study, Musa acuminata-free tepal (MAFT) crops and musa were used to mediate the formation of copper nanocatalyst for environmental pollution. The synthesised nanocatalyst was analysed by XPS, XRD, TEM, SEM, FT-IR, GC-EI-MS, and TGA-DSC. The production of Cu–O in the 512 cm−1 peak range was verified by FT-IR analysis. The XRD peaks associated with the cubic crystalline structures of copper (110) and (200) were used to confirm the Musa acuminata-free tepal CuO nanocatalyst. The SEM images of the Cu and CuO nanocatalyst in the Musa acuminata free tepal showed that the particles were almost spherical. The size of the synthesised Musa acuminata free tepal CuO nanocatalyst core-shell nanostructures was identified using HR-TEM. GC-MS investigations also verified the aerobic oxidation of the main alcohol to aldehyde, with a retention time of 30.34. The MAFT was 80 % of CBB G250 dye decolourised at 24 h, and the MAFT-CuO nanocatalyst was decolourised the CBB G250 dye at 80 % in 20 min and aerobic oxidation at the same time (dual application). Furthermore, our nanocatalyst could be effectively recycled without significant loss of catalytic activity, and the use of safe, environmentally benign MAFT-Cu and CuO nanocatalyst is considered a green chemistry approach that helps avoid wastewater treatment. MAFT-Cu and CuO nanocatalyst were successfully synthesised using Musa acuminata free tepal extract assisted by reflux sample preparation system instruments as a new, green, eco-friendly, and fast process for nanocatalyst synthesis. In the past, there have been no reported applications of MAFT-Cu and CuO nanocatalyst for decolourisation and aerobic oxidation. Nevertheless, we were able to accomplish these procedures with the help of CuO and MAFT-Cu nanocatalyst. Therefore, the most effective naturally occurring environmental catalysts for aerobic oxidation processes are MAFT-CuO nanocatalyst. They are non-toxic and environmentally benign, exhibit strong aerobic oxidation catalytic performance, and have long-lasting |
doi_str_mv | 10.1016/j.indcrop.2024.118715 |
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[Display omitted]
•Collection of Musa acuminata free tepal crop and Synthesis of Musa acuminata free tepal crop with CuO NPs (MAFT-CuO).•Characterisation of FT-IR, UV-Visible spectroscopy, XRD, XPS, TEM, SEM, GC-MS, and TGA, etc.•Aerobic Oxidation of alcohol dehydration and Dye Decolourization via eco-friendly method.•Musa acuminata free tepal crop used for dye decolouration.•MAFT-CuO used for dual application in dye decolouration and aerobic oxidation.</description><identifier>ISSN: 0926-6690</identifier><identifier>DOI: 10.1016/j.indcrop.2024.118715</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Aerobic oxidation ; alcohols ; aldehydes ; biodegradability ; catalytic activity ; Coomassie Brilliant Blue G250 ; copper ; cupric oxide ; decolorization ; Dye decolourisation ; dyes ; flower tepals ; green chemistry ; industrial wastewater ; industry ; MAFT-Cu and CuO nanocatalyst ; Musa acuminata ; Musa acuminate free tepal ; nanocatalysts ; nanomaterials ; oxidation ; pollution ; Rhodamine B ; sustainable technology ; toxicity ; wastewater treatment ; water quality</subject><ispartof>Industrial crops and products, 2024-09, Vol.216, p.118715, Article 118715</ispartof><rights>2024 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c290t-70b7a15d9a1cbd9877bfe9ce943679e20c04acc2384cf0b7f31f01f57759c08b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0926669024006927$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65534</link.rule.ids></links><search><creatorcontrib>Mani, Arunadevi</creatorcontrib><creatorcontrib>Loganathan, Velmurugan</creatorcontrib><creatorcontrib>Akbar, Idhayadhulla</creatorcontrib><creatorcontrib>Ahamed, Anis</creatorcontrib><creatorcontrib>Alnafisi, Bassam Khalid</creatorcontrib><creatorcontrib>Gurusamy, Raman</creatorcontrib><title>Musa acuminata free tepal (MAFT) crop- mediated synthesis of copper oxide nanocatalyst (MAFT-CuO nanocatalyst): Investigation of aerobic oxidation and dye decolourization via eco-friendly approach</title><title>Industrial crops and products</title><description>Crop development is used to address environmental problems in the industry. Environmental pollutants, particularly humble or toxic chemicals and dyes, are contaminants in industrial wastewater. Recently, green technology has become important for controlling the chemical risks associated with environmental issues. This study focused on valuable crop materials to form green catalysts that can be used to control chemical toxicity in industrial wastewater. In this study, Musa acuminata-free tepal (MAFT) crops and musa were used to mediate the formation of copper nanocatalyst for environmental pollution. The synthesised nanocatalyst was analysed by XPS, XRD, TEM, SEM, FT-IR, GC-EI-MS, and TGA-DSC. The production of Cu–O in the 512 cm−1 peak range was verified by FT-IR analysis. The XRD peaks associated with the cubic crystalline structures of copper (110) and (200) were used to confirm the Musa acuminata-free tepal CuO nanocatalyst. The SEM images of the Cu and CuO nanocatalyst in the Musa acuminata free tepal showed that the particles were almost spherical. The size of the synthesised Musa acuminata free tepal CuO nanocatalyst core-shell nanostructures was identified using HR-TEM. GC-MS investigations also verified the aerobic oxidation of the main alcohol to aldehyde, with a retention time of 30.34. The MAFT was 80 % of CBB G250 dye decolourised at 24 h, and the MAFT-CuO nanocatalyst was decolourised the CBB G250 dye at 80 % in 20 min and aerobic oxidation at the same time (dual application). Furthermore, our nanocatalyst could be effectively recycled without significant loss of catalytic activity, and the use of safe, environmentally benign MAFT-Cu and CuO nanocatalyst is considered a green chemistry approach that helps avoid wastewater treatment. MAFT-Cu and CuO nanocatalyst were successfully synthesised using Musa acuminata free tepal extract assisted by reflux sample preparation system instruments as a new, green, eco-friendly, and fast process for nanocatalyst synthesis. In the past, there have been no reported applications of MAFT-Cu and CuO nanocatalyst for decolourisation and aerobic oxidation. Nevertheless, we were able to accomplish these procedures with the help of CuO and MAFT-Cu nanocatalyst. Therefore, the most effective naturally occurring environmental catalysts for aerobic oxidation processes are MAFT-CuO nanocatalyst. They are non-toxic and environmentally benign, exhibit strong aerobic oxidation catalytic performance, and have long-lasting benefits for water quality. Additionally, they are more recoverable and biodegradable.
[Display omitted]
•Collection of Musa acuminata free tepal crop and Synthesis of Musa acuminata free tepal crop with CuO NPs (MAFT-CuO).•Characterisation of FT-IR, UV-Visible spectroscopy, XRD, XPS, TEM, SEM, GC-MS, and TGA, etc.•Aerobic Oxidation of alcohol dehydration and Dye Decolourization via eco-friendly method.•Musa acuminata free tepal crop used for dye decolouration.•MAFT-CuO used for dual application in dye decolouration and aerobic oxidation.</description><subject>Aerobic oxidation</subject><subject>alcohols</subject><subject>aldehydes</subject><subject>biodegradability</subject><subject>catalytic activity</subject><subject>Coomassie Brilliant Blue G250</subject><subject>copper</subject><subject>cupric oxide</subject><subject>decolorization</subject><subject>Dye decolourisation</subject><subject>dyes</subject><subject>flower tepals</subject><subject>green chemistry</subject><subject>industrial wastewater</subject><subject>industry</subject><subject>MAFT-Cu and CuO nanocatalyst</subject><subject>Musa acuminata</subject><subject>Musa acuminate free tepal</subject><subject>nanocatalysts</subject><subject>nanomaterials</subject><subject>oxidation</subject><subject>pollution</subject><subject>Rhodamine B</subject><subject>sustainable technology</subject><subject>toxicity</subject><subject>wastewater treatment</subject><subject>water quality</subject><issn>0926-6690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkUFP3DAUhHNoJSj0J1TyEQ7Z2skmXnOp0Kq0SCAucLZenp_Bq6yd2smq4ff1h9VLuPTUk6XRzGfNm6L4IvhKcNF-3a2cNxjDsKp4tV4JsZGi-VCcclW1ZdsqflJ8SmnHuZC8kqfFn_spAQOc9s7DCMxGIjbSAD27uL--ebxkR1jJ9mQcjGRYmv34QsklFizDMAwUWfjtDDEPPmBm9HMal3C5nR7-kS-v2K0_UBrdM4wu-CMDKIbO4RtkEcEbZmZihjD0YYruddEPDliWShsdedPPDIYhBsCX8-KjhT7R5_f3rHi6-f64_VnePfy43V7flVgpPpaSdxJEYxQI7IzaSNlZUkhqXbdSUcWRrwGxqjdrtNlra2G5sI2UjUK-6eqz4mLh5m9_TbmG3ruE1PfgKUxJ16Kp26qRXGVrs1jz-VKKZPUQ3R7irAXXx6X0Tr8vpY9L6WWpnPu25Cj3ODiKOmFui_n8kXDUJrj_EP4CmC2lhA</recordid><startdate>20240915</startdate><enddate>20240915</enddate><creator>Mani, Arunadevi</creator><creator>Loganathan, Velmurugan</creator><creator>Akbar, Idhayadhulla</creator><creator>Ahamed, Anis</creator><creator>Alnafisi, Bassam Khalid</creator><creator>Gurusamy, Raman</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20240915</creationdate><title>Musa acuminata free tepal (MAFT) crop- mediated synthesis of copper oxide nanocatalyst (MAFT-CuO nanocatalyst): Investigation of aerobic oxidation and dye decolourization via eco-friendly approach</title><author>Mani, Arunadevi ; Loganathan, Velmurugan ; Akbar, Idhayadhulla ; Ahamed, Anis ; Alnafisi, Bassam Khalid ; Gurusamy, Raman</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c290t-70b7a15d9a1cbd9877bfe9ce943679e20c04acc2384cf0b7f31f01f57759c08b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Aerobic oxidation</topic><topic>alcohols</topic><topic>aldehydes</topic><topic>biodegradability</topic><topic>catalytic activity</topic><topic>Coomassie Brilliant Blue G250</topic><topic>copper</topic><topic>cupric oxide</topic><topic>decolorization</topic><topic>Dye decolourisation</topic><topic>dyes</topic><topic>flower tepals</topic><topic>green chemistry</topic><topic>industrial wastewater</topic><topic>industry</topic><topic>MAFT-Cu and CuO nanocatalyst</topic><topic>Musa acuminata</topic><topic>Musa acuminate free tepal</topic><topic>nanocatalysts</topic><topic>nanomaterials</topic><topic>oxidation</topic><topic>pollution</topic><topic>Rhodamine B</topic><topic>sustainable technology</topic><topic>toxicity</topic><topic>wastewater treatment</topic><topic>water quality</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mani, Arunadevi</creatorcontrib><creatorcontrib>Loganathan, Velmurugan</creatorcontrib><creatorcontrib>Akbar, Idhayadhulla</creatorcontrib><creatorcontrib>Ahamed, Anis</creatorcontrib><creatorcontrib>Alnafisi, Bassam Khalid</creatorcontrib><creatorcontrib>Gurusamy, Raman</creatorcontrib><collection>CrossRef</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Industrial crops and products</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mani, Arunadevi</au><au>Loganathan, Velmurugan</au><au>Akbar, Idhayadhulla</au><au>Ahamed, Anis</au><au>Alnafisi, Bassam Khalid</au><au>Gurusamy, Raman</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Musa acuminata free tepal (MAFT) crop- mediated synthesis of copper oxide nanocatalyst (MAFT-CuO nanocatalyst): Investigation of aerobic oxidation and dye decolourization via eco-friendly approach</atitle><jtitle>Industrial crops and products</jtitle><date>2024-09-15</date><risdate>2024</risdate><volume>216</volume><spage>118715</spage><pages>118715-</pages><artnum>118715</artnum><issn>0926-6690</issn><abstract>Crop development is used to address environmental problems in the industry. Environmental pollutants, particularly humble or toxic chemicals and dyes, are contaminants in industrial wastewater. Recently, green technology has become important for controlling the chemical risks associated with environmental issues. This study focused on valuable crop materials to form green catalysts that can be used to control chemical toxicity in industrial wastewater. In this study, Musa acuminata-free tepal (MAFT) crops and musa were used to mediate the formation of copper nanocatalyst for environmental pollution. The synthesised nanocatalyst was analysed by XPS, XRD, TEM, SEM, FT-IR, GC-EI-MS, and TGA-DSC. The production of Cu–O in the 512 cm−1 peak range was verified by FT-IR analysis. The XRD peaks associated with the cubic crystalline structures of copper (110) and (200) were used to confirm the Musa acuminata-free tepal CuO nanocatalyst. The SEM images of the Cu and CuO nanocatalyst in the Musa acuminata free tepal showed that the particles were almost spherical. The size of the synthesised Musa acuminata free tepal CuO nanocatalyst core-shell nanostructures was identified using HR-TEM. GC-MS investigations also verified the aerobic oxidation of the main alcohol to aldehyde, with a retention time of 30.34. The MAFT was 80 % of CBB G250 dye decolourised at 24 h, and the MAFT-CuO nanocatalyst was decolourised the CBB G250 dye at 80 % in 20 min and aerobic oxidation at the same time (dual application). Furthermore, our nanocatalyst could be effectively recycled without significant loss of catalytic activity, and the use of safe, environmentally benign MAFT-Cu and CuO nanocatalyst is considered a green chemistry approach that helps avoid wastewater treatment. MAFT-Cu and CuO nanocatalyst were successfully synthesised using Musa acuminata free tepal extract assisted by reflux sample preparation system instruments as a new, green, eco-friendly, and fast process for nanocatalyst synthesis. In the past, there have been no reported applications of MAFT-Cu and CuO nanocatalyst for decolourisation and aerobic oxidation. Nevertheless, we were able to accomplish these procedures with the help of CuO and MAFT-Cu nanocatalyst. Therefore, the most effective naturally occurring environmental catalysts for aerobic oxidation processes are MAFT-CuO nanocatalyst. They are non-toxic and environmentally benign, exhibit strong aerobic oxidation catalytic performance, and have long-lasting benefits for water quality. Additionally, they are more recoverable and biodegradable.
[Display omitted]
•Collection of Musa acuminata free tepal crop and Synthesis of Musa acuminata free tepal crop with CuO NPs (MAFT-CuO).•Characterisation of FT-IR, UV-Visible spectroscopy, XRD, XPS, TEM, SEM, GC-MS, and TGA, etc.•Aerobic Oxidation of alcohol dehydration and Dye Decolourization via eco-friendly method.•Musa acuminata free tepal crop used for dye decolouration.•MAFT-CuO used for dual application in dye decolouration and aerobic oxidation.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.indcrop.2024.118715</doi></addata></record> |
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subjects | Aerobic oxidation alcohols aldehydes biodegradability catalytic activity Coomassie Brilliant Blue G250 copper cupric oxide decolorization Dye decolourisation dyes flower tepals green chemistry industrial wastewater industry MAFT-Cu and CuO nanocatalyst Musa acuminata Musa acuminate free tepal nanocatalysts nanomaterials oxidation pollution Rhodamine B sustainable technology toxicity wastewater treatment water quality |
title | Musa acuminata free tepal (MAFT) crop- mediated synthesis of copper oxide nanocatalyst (MAFT-CuO nanocatalyst): Investigation of aerobic oxidation and dye decolourization via eco-friendly approach |
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