Magnetic graphene derivates for efficient herbicide removal from aqueous solution through adsorption
2,4-Dichlorophenoxyacetic acid (2,4-D) is an herbicide and is among the most widely distributed pollutant in the environment and wastewater. Herein is presented a complete comparison of adsorption performance between two different magnetic carbon nanomaterials: graphene oxide (GO) and its reduced fo...
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| creator | da Rosa Salles, Theodoro Zancanaro, Leonardo Vidal da Silva Bruckmann, Franciele Garcia, Wagner Jesus de Oliveira, Artur Harres Baumann, Luiza Rhoden, Daniele Soares Basso Muller, Edson Irineu Martinez, Diego Stefani Teodoro Mortari, Sergio Roberto Rhoden, Cristiano Rodrigo Bohn |
| description | 2,4-Dichlorophenoxyacetic acid (2,4-D) is an herbicide and is among the most widely distributed pollutant in the environment and wastewater. Herein is presented a complete comparison of adsorption performance between two different magnetic carbon nanomaterials: graphene oxide (GO) and its reduced form (rGO). Magnetic functionalization was performed employing a coprecipitation method, using only one source of Fe
2+
, requiring low energy, and potentially allowing the control of the amount of incorporated magnetite. For the first time in literature, a green reduction approach for GO with and without Fe
3
O
4
, maintaining the magnetic behavior after the reaction, and an adsorption performance comparison between both carbon nanomaterials are demonstrated. The nanoadsorbents were characterized by FTIR, XRD, Raman, VSM, XPS, and SEM analyses, which demonstrates the successful synthesis of graphene derivate, with different amounts of incorporate magnetite, resulting in distinct magnetization values. The reduction was confirmed by XPS and FTIR techniques. The type of adsorbent reveals that the amount of magnetite on nanomaterial surfaces has significant influence on adsorption capacity and removal efficiency. The procedure demonstrated that the best performance, for magnetic nanocomposites, was obtained by GO∙Fe
3
O
4
1:1 and rGO∙Fe
3
O
4
1:1, presenting values of removal percentage of 70.49 and 91.19%, respectively. The highest adsorption capacity was reached at pH 2.0 for GO∙Fe
3
O
4
1:1 (69.98 mg g
−1
) and rGO∙Fe
3
O
4
1:1 (89.27 mg g
−1
), through different interactions: π-π, cation-π, and hydrogen bonds. The adsorption phenomenon exhibited a high dependence on pH, initial concentration of adsorbate, and coexisting ions. Sips and PSO models demonstrate the best adjustment for experimental data, suggesting a heterogeneous surface and different energy sites, respectively. The thermodynamic parameters showed that the process was spontaneous and exothermic. Finally, the nanoadsorbents demonstrated a high efficiency in 2,4-D adsorption even after five adsorption/desorption cycles.
Graphical Abstract |
| doi_str_mv | 10.1007/s11356-024-32845-6 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_3153624942</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3040142645</sourcerecordid><originalsourceid>FETCH-LOGICAL-c359t-38329308d6a04f7b1faa87faeb72a4fb6558128dcf6c499dff242ace546590af3</originalsourceid><addsrcrecordid>eNqFkctKxDAUhoMozjj6Ai4k4MZNNfe0SxFvoLjRdUjbk5lK24xJK_j2Zpzxggtd5ZB85885fAgdUnJKCdFnkVIuVUaYyDjLhczUFppSRUWmRVFs_6gnaC_GZ0IYKZjeRROeC82k5lNU39t5D0NT4XmwywX0gGsIzasdIGLnAwbnmqqBfsALCGUqa8ABOv9qW-yC77B9GcGPEUffjkPjezwsgh_nC2zr6MNydbWPdpxtIxxszhl6urp8vLjJ7h6uby_O77KKy2LIeM5ZwUleK0uE0yV11ubaWSg1s8KVSsqcsryunKrSUrVzTDBbgRRKFsQ6PkMn69xl8GmqOJiuiRW0re1XIxpOJVdMFIL9i7JCKpVTSXVCj3-hz34MfVrEcCIIFUwJmSi2pqrgYwzgzDI0nQ1vhhKz0mXWukzSZT50GZWajjbRY9lB_dXy6ScBfA3E9NTPIXz__UfsOy7toTA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3040142645</pqid></control><display><type>article</type><title>Magnetic graphene derivates for efficient herbicide removal from aqueous solution through adsorption</title><source>Springer Nature - Complete Springer Journals</source><creator>da Rosa Salles, Theodoro ; Zancanaro, Leonardo Vidal ; da Silva Bruckmann, Franciele ; Garcia, Wagner Jesus ; de Oliveira, Artur Harres ; Baumann, Luiza ; Rhoden, Daniele Soares Basso ; Muller, Edson Irineu ; Martinez, Diego Stefani Teodoro ; Mortari, Sergio Roberto ; Rhoden, Cristiano Rodrigo Bohn</creator><creatorcontrib>da Rosa Salles, Theodoro ; Zancanaro, Leonardo Vidal ; da Silva Bruckmann, Franciele ; Garcia, Wagner Jesus ; de Oliveira, Artur Harres ; Baumann, Luiza ; Rhoden, Daniele Soares Basso ; Muller, Edson Irineu ; Martinez, Diego Stefani Teodoro ; Mortari, Sergio Roberto ; Rhoden, Cristiano Rodrigo Bohn</creatorcontrib><description>2,4-Dichlorophenoxyacetic acid (2,4-D) is an herbicide and is among the most widely distributed pollutant in the environment and wastewater. Herein is presented a complete comparison of adsorption performance between two different magnetic carbon nanomaterials: graphene oxide (GO) and its reduced form (rGO). Magnetic functionalization was performed employing a coprecipitation method, using only one source of Fe
2+
, requiring low energy, and potentially allowing the control of the amount of incorporated magnetite. For the first time in literature, a green reduction approach for GO with and without Fe
3
O
4
, maintaining the magnetic behavior after the reaction, and an adsorption performance comparison between both carbon nanomaterials are demonstrated. The nanoadsorbents were characterized by FTIR, XRD, Raman, VSM, XPS, and SEM analyses, which demonstrates the successful synthesis of graphene derivate, with different amounts of incorporate magnetite, resulting in distinct magnetization values. The reduction was confirmed by XPS and FTIR techniques. The type of adsorbent reveals that the amount of magnetite on nanomaterial surfaces has significant influence on adsorption capacity and removal efficiency. The procedure demonstrated that the best performance, for magnetic nanocomposites, was obtained by GO∙Fe
3
O
4
1:1 and rGO∙Fe
3
O
4
1:1, presenting values of removal percentage of 70.49 and 91.19%, respectively. The highest adsorption capacity was reached at pH 2.0 for GO∙Fe
3
O
4
1:1 (69.98 mg g
−1
) and rGO∙Fe
3
O
4
1:1 (89.27 mg g
−1
), through different interactions: π-π, cation-π, and hydrogen bonds. The adsorption phenomenon exhibited a high dependence on pH, initial concentration of adsorbate, and coexisting ions. Sips and PSO models demonstrate the best adjustment for experimental data, suggesting a heterogeneous surface and different energy sites, respectively. The thermodynamic parameters showed that the process was spontaneous and exothermic. Finally, the nanoadsorbents demonstrated a high efficiency in 2,4-D adsorption even after five adsorption/desorption cycles.
Graphical Abstract</description><identifier>ISSN: 1614-7499</identifier><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-024-32845-6</identifier><identifier>PMID: 38472573</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>2,4-D ; adsorbents ; Adsorption ; Aquatic Pollution ; Aqueous solutions ; Atmospheric Protection/Air Quality Control/Air Pollution ; Carbon ; coprecipitation ; desorption ; Dichlorophenoxyacetic acid ; Earth and Environmental Science ; Ecotoxicology ; energy ; Environment ; Environmental Chemistry ; Environmental Health ; Exothermic reactions ; Graphene ; graphene oxide ; heat production ; Herbicides ; hydrogen ; Hydrogen bonding ; Hydrogen bonds ; Iron oxides ; Magnetic properties ; magnetism ; Magnetite ; Nanocomposites ; Nanomaterials ; Nanotechnology ; pollutants ; Reduction ; Research Article ; Surface chemistry ; Waste Water Technology ; wastewater ; Water Management ; Water Pollution Control ; X ray photoelectron spectroscopy</subject><ispartof>Environmental science and pollution research international, 2024-04, Vol.31 (17), p.25437-25453</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c359t-38329308d6a04f7b1faa87faeb72a4fb6558128dcf6c499dff242ace546590af3</cites><orcidid>0000-0001-6171-4224</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-024-32845-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-024-32845-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27911,27912,41475,42544,51306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38472573$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>da Rosa Salles, Theodoro</creatorcontrib><creatorcontrib>Zancanaro, Leonardo Vidal</creatorcontrib><creatorcontrib>da Silva Bruckmann, Franciele</creatorcontrib><creatorcontrib>Garcia, Wagner Jesus</creatorcontrib><creatorcontrib>de Oliveira, Artur Harres</creatorcontrib><creatorcontrib>Baumann, Luiza</creatorcontrib><creatorcontrib>Rhoden, Daniele Soares Basso</creatorcontrib><creatorcontrib>Muller, Edson Irineu</creatorcontrib><creatorcontrib>Martinez, Diego Stefani Teodoro</creatorcontrib><creatorcontrib>Mortari, Sergio Roberto</creatorcontrib><creatorcontrib>Rhoden, Cristiano Rodrigo Bohn</creatorcontrib><title>Magnetic graphene derivates for efficient herbicide removal from aqueous solution through adsorption</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>2,4-Dichlorophenoxyacetic acid (2,4-D) is an herbicide and is among the most widely distributed pollutant in the environment and wastewater. Herein is presented a complete comparison of adsorption performance between two different magnetic carbon nanomaterials: graphene oxide (GO) and its reduced form (rGO). Magnetic functionalization was performed employing a coprecipitation method, using only one source of Fe
2+
, requiring low energy, and potentially allowing the control of the amount of incorporated magnetite. For the first time in literature, a green reduction approach for GO with and without Fe
3
O
4
, maintaining the magnetic behavior after the reaction, and an adsorption performance comparison between both carbon nanomaterials are demonstrated. The nanoadsorbents were characterized by FTIR, XRD, Raman, VSM, XPS, and SEM analyses, which demonstrates the successful synthesis of graphene derivate, with different amounts of incorporate magnetite, resulting in distinct magnetization values. The reduction was confirmed by XPS and FTIR techniques. The type of adsorbent reveals that the amount of magnetite on nanomaterial surfaces has significant influence on adsorption capacity and removal efficiency. The procedure demonstrated that the best performance, for magnetic nanocomposites, was obtained by GO∙Fe
3
O
4
1:1 and rGO∙Fe
3
O
4
1:1, presenting values of removal percentage of 70.49 and 91.19%, respectively. The highest adsorption capacity was reached at pH 2.0 for GO∙Fe
3
O
4
1:1 (69.98 mg g
−1
) and rGO∙Fe
3
O
4
1:1 (89.27 mg g
−1
), through different interactions: π-π, cation-π, and hydrogen bonds. The adsorption phenomenon exhibited a high dependence on pH, initial concentration of adsorbate, and coexisting ions. Sips and PSO models demonstrate the best adjustment for experimental data, suggesting a heterogeneous surface and different energy sites, respectively. The thermodynamic parameters showed that the process was spontaneous and exothermic. Finally, the nanoadsorbents demonstrated a high efficiency in 2,4-D adsorption even after five adsorption/desorption cycles.
Graphical Abstract</description><subject>2,4-D</subject><subject>adsorbents</subject><subject>Adsorption</subject><subject>Aquatic Pollution</subject><subject>Aqueous solutions</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Carbon</subject><subject>coprecipitation</subject><subject>desorption</subject><subject>Dichlorophenoxyacetic acid</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>energy</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Exothermic reactions</subject><subject>Graphene</subject><subject>graphene oxide</subject><subject>heat production</subject><subject>Herbicides</subject><subject>hydrogen</subject><subject>Hydrogen bonding</subject><subject>Hydrogen bonds</subject><subject>Iron oxides</subject><subject>Magnetic properties</subject><subject>magnetism</subject><subject>Magnetite</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanotechnology</subject><subject>pollutants</subject><subject>Reduction</subject><subject>Research Article</subject><subject>Surface chemistry</subject><subject>Waste Water Technology</subject><subject>wastewater</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><subject>X ray photoelectron spectroscopy</subject><issn>1614-7499</issn><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkctKxDAUhoMozjj6Ai4k4MZNNfe0SxFvoLjRdUjbk5lK24xJK_j2Zpzxggtd5ZB85885fAgdUnJKCdFnkVIuVUaYyDjLhczUFppSRUWmRVFs_6gnaC_GZ0IYKZjeRROeC82k5lNU39t5D0NT4XmwywX0gGsIzasdIGLnAwbnmqqBfsALCGUqa8ABOv9qW-yC77B9GcGPEUffjkPjezwsgh_nC2zr6MNydbWPdpxtIxxszhl6urp8vLjJ7h6uby_O77KKy2LIeM5ZwUleK0uE0yV11ubaWSg1s8KVSsqcsryunKrSUrVzTDBbgRRKFsQ6PkMn69xl8GmqOJiuiRW0re1XIxpOJVdMFIL9i7JCKpVTSXVCj3-hz34MfVrEcCIIFUwJmSi2pqrgYwzgzDI0nQ1vhhKz0mXWukzSZT50GZWajjbRY9lB_dXy6ScBfA3E9NTPIXz__UfsOy7toTA</recordid><startdate>20240401</startdate><enddate>20240401</enddate><creator>da Rosa Salles, Theodoro</creator><creator>Zancanaro, Leonardo Vidal</creator><creator>da Silva Bruckmann, Franciele</creator><creator>Garcia, Wagner Jesus</creator><creator>de Oliveira, Artur Harres</creator><creator>Baumann, Luiza</creator><creator>Rhoden, Daniele Soares Basso</creator><creator>Muller, Edson Irineu</creator><creator>Martinez, Diego Stefani Teodoro</creator><creator>Mortari, Sergio Roberto</creator><creator>Rhoden, Cristiano Rodrigo Bohn</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QL</scope><scope>7SN</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>K9.</scope><scope>M7N</scope><scope>P64</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0000-0001-6171-4224</orcidid></search><sort><creationdate>20240401</creationdate><title>Magnetic graphene derivates for efficient herbicide removal from aqueous solution through adsorption</title><author>da Rosa Salles, Theodoro ; Zancanaro, Leonardo Vidal ; da Silva Bruckmann, Franciele ; Garcia, Wagner Jesus ; de Oliveira, Artur Harres ; Baumann, Luiza ; Rhoden, Daniele Soares Basso ; Muller, Edson Irineu ; Martinez, Diego Stefani Teodoro ; Mortari, Sergio Roberto ; Rhoden, Cristiano Rodrigo Bohn</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-38329308d6a04f7b1faa87faeb72a4fb6558128dcf6c499dff242ace546590af3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>2,4-D</topic><topic>adsorbents</topic><topic>Adsorption</topic><topic>Aquatic Pollution</topic><topic>Aqueous solutions</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Carbon</topic><topic>coprecipitation</topic><topic>desorption</topic><topic>Dichlorophenoxyacetic acid</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>energy</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Exothermic reactions</topic><topic>Graphene</topic><topic>graphene oxide</topic><topic>heat production</topic><topic>Herbicides</topic><topic>hydrogen</topic><topic>Hydrogen bonding</topic><topic>Hydrogen bonds</topic><topic>Iron oxides</topic><topic>Magnetic properties</topic><topic>magnetism</topic><topic>Magnetite</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanotechnology</topic><topic>pollutants</topic><topic>Reduction</topic><topic>Research Article</topic><topic>Surface chemistry</topic><topic>Waste Water Technology</topic><topic>wastewater</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>da Rosa Salles, Theodoro</creatorcontrib><creatorcontrib>Zancanaro, Leonardo Vidal</creatorcontrib><creatorcontrib>da Silva Bruckmann, Franciele</creatorcontrib><creatorcontrib>Garcia, Wagner Jesus</creatorcontrib><creatorcontrib>de Oliveira, Artur Harres</creatorcontrib><creatorcontrib>Baumann, Luiza</creatorcontrib><creatorcontrib>Rhoden, Daniele Soares Basso</creatorcontrib><creatorcontrib>Muller, Edson Irineu</creatorcontrib><creatorcontrib>Martinez, Diego Stefani Teodoro</creatorcontrib><creatorcontrib>Mortari, Sergio Roberto</creatorcontrib><creatorcontrib>Rhoden, Cristiano Rodrigo Bohn</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ecology Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>da Rosa Salles, Theodoro</au><au>Zancanaro, Leonardo Vidal</au><au>da Silva Bruckmann, Franciele</au><au>Garcia, Wagner Jesus</au><au>de Oliveira, Artur Harres</au><au>Baumann, Luiza</au><au>Rhoden, Daniele Soares Basso</au><au>Muller, Edson Irineu</au><au>Martinez, Diego Stefani Teodoro</au><au>Mortari, Sergio Roberto</au><au>Rhoden, Cristiano Rodrigo Bohn</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Magnetic graphene derivates for efficient herbicide removal from aqueous solution through adsorption</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2024-04-01</date><risdate>2024</risdate><volume>31</volume><issue>17</issue><spage>25437</spage><epage>25453</epage><pages>25437-25453</pages><issn>1614-7499</issn><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>2,4-Dichlorophenoxyacetic acid (2,4-D) is an herbicide and is among the most widely distributed pollutant in the environment and wastewater. Herein is presented a complete comparison of adsorption performance between two different magnetic carbon nanomaterials: graphene oxide (GO) and its reduced form (rGO). Magnetic functionalization was performed employing a coprecipitation method, using only one source of Fe
2+
, requiring low energy, and potentially allowing the control of the amount of incorporated magnetite. For the first time in literature, a green reduction approach for GO with and without Fe
3
O
4
, maintaining the magnetic behavior after the reaction, and an adsorption performance comparison between both carbon nanomaterials are demonstrated. The nanoadsorbents were characterized by FTIR, XRD, Raman, VSM, XPS, and SEM analyses, which demonstrates the successful synthesis of graphene derivate, with different amounts of incorporate magnetite, resulting in distinct magnetization values. The reduction was confirmed by XPS and FTIR techniques. The type of adsorbent reveals that the amount of magnetite on nanomaterial surfaces has significant influence on adsorption capacity and removal efficiency. The procedure demonstrated that the best performance, for magnetic nanocomposites, was obtained by GO∙Fe
3
O
4
1:1 and rGO∙Fe
3
O
4
1:1, presenting values of removal percentage of 70.49 and 91.19%, respectively. The highest adsorption capacity was reached at pH 2.0 for GO∙Fe
3
O
4
1:1 (69.98 mg g
−1
) and rGO∙Fe
3
O
4
1:1 (89.27 mg g
−1
), through different interactions: π-π, cation-π, and hydrogen bonds. The adsorption phenomenon exhibited a high dependence on pH, initial concentration of adsorbate, and coexisting ions. Sips and PSO models demonstrate the best adjustment for experimental data, suggesting a heterogeneous surface and different energy sites, respectively. The thermodynamic parameters showed that the process was spontaneous and exothermic. Finally, the nanoadsorbents demonstrated a high efficiency in 2,4-D adsorption even after five adsorption/desorption cycles.
Graphical Abstract</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>38472573</pmid><doi>10.1007/s11356-024-32845-6</doi><tpages>17</tpages><orcidid>https://orcid.org/0000-0001-6171-4224</orcidid></addata></record> |
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| ispartof | Environmental science and pollution research international, 2024-04, Vol.31 (17), p.25437-25453 |
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| source | Springer Nature - Complete Springer Journals |
| subjects | 2,4-D adsorbents Adsorption Aquatic Pollution Aqueous solutions Atmospheric Protection/Air Quality Control/Air Pollution Carbon coprecipitation desorption Dichlorophenoxyacetic acid Earth and Environmental Science Ecotoxicology energy Environment Environmental Chemistry Environmental Health Exothermic reactions Graphene graphene oxide heat production Herbicides hydrogen Hydrogen bonding Hydrogen bonds Iron oxides Magnetic properties magnetism Magnetite Nanocomposites Nanomaterials Nanotechnology pollutants Reduction Research Article Surface chemistry Waste Water Technology wastewater Water Management Water Pollution Control X ray photoelectron spectroscopy |
| title | Magnetic graphene derivates for efficient herbicide removal from aqueous solution through adsorption |
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