Exploration on the occurrence state of fluorine in cement hydration products mixed with high fluorine alkali free liquid accelerator

If there was abundant fluorine in shotcrete, it might leach out and pollute the soil or migrate to corrode the reinforcement.Therefore, this research mainly investigated the basic properties of high-fluorine alkali free liquid accelerator (HF-AFA) and its occurrence forms in cement hydration product...

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Veröffentlicht in:Environmental science and pollution research international 2024, Vol.31 (2), p.3105-3122
Hauptverfasser: Yang, Renhe, Zhang, Pengyu, Li, Yang, Wang, Dongmei, Sun, Qian, Mao, Zhiyi, Wang, Wanshen, He, Tingshu
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container_title Environmental science and pollution research international
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creator Yang, Renhe
Zhang, Pengyu
Li, Yang
Wang, Dongmei
Sun, Qian
Mao, Zhiyi
Wang, Wanshen
He, Tingshu
description If there was abundant fluorine in shotcrete, it might leach out and pollute the soil or migrate to corrode the reinforcement.Therefore, this research mainly investigated the basic properties of high-fluorine alkali free liquid accelerator (HF-AFA) and its occurrence forms in cement hydration products.The macro-test results showed that with the increase of HF-AFA dosage, it appeared excellent coagulation promoting property. However, when the HF-AFA dosage exceeded 7.0%, the 1d compressive strength of mortar was lower than 7.0 MPa. In addition, by measuring the early hydration heat of cement, C 3 A, C 3 S, C 2 S and C 4 AF pastes with and without HF-AFA, and combining XRD and SEM micro-analysis, the occurrence forms of fluorine in different clinker minerals were obtained.The final analysis results indicated that fluorine mainly existed in the form of CaF 2 , CaAlF 5 and Ca 2 AlF 7 crystals in C 3 A and C 3 S minerals, while only little CaF 2 crystals appeared in C 2 S and C 4 AF minerals.
doi_str_mv 10.1007/s11356-023-31366-y
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source SpringerLink Journals
subjects Acids
Aluminum
Aquatic Pollution
Atmospheric Protection/Air Quality Control/Air Pollution
Calcium fluoride
Cement
Cement hydration
Clinker
Coagulation
compression strength
Compressive strength
Crystals
Dicalcium silicate
Dosage
Earth and Environmental Science
Ecotoxicology
Environment
Environmental Chemistry
Environmental Health
Environmental science
Experimental methods
Fluorine
heat
Hydration
liquids
Minerals
Pastes
Physical properties
Pollution
Raw materials
Research Article
soil
Soil pollution
Sprayed concrete
Tricalcium aluminum ferrite
Tricalcium silicate
Waste Water Technology
Water Management
Water Pollution Control
title Exploration on the occurrence state of fluorine in cement hydration products mixed with high fluorine alkali free liquid accelerator
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