Syntheses of diaza[1.1.1] and [1.1.1.1] paracyclophanes by smiles rearrangement

[Display omitted] •Two strained macrocycles, diaza[1.1.1] and [1.1.1.1]paracyclophanes were synthesized.•The synthetic route is short and simple.•The molecular structures of two paracyclophanes were simulated by DFT calculations.•Diaza[1.1.1]paracyclophane is highly distorted.•Intramolecular partial...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Tetrahedron letters 2023-10, Vol.130, p.154762, Article 154762
Hauptverfasser:	Takemura, Hiroyuki, Wakamatsu, Maho, Murakami, Hiroko, Iwanaga, Tetsuo, Sako, Katsuya
Format:	Artikel
Sprache:	eng
Schlagworte:	[1n]paracyclophanes chemical structure Cyclophanes Macrocycles methodology Smiles rearrangement solubility strains
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!