Occurrence of BTX and PAHs in underground drinking water of coking contaminated sites: Linkage with altitude and health risk assessment by boiling-modified models

The safety of underground drinking water has received widespread attention. However, few studies have focused on the occurrence and health risks of pollutants in underground drinking water of coking contaminated sites. In this study, the distribution characteristics, sources, and human health risks of benzene, toluene, xylene (BTX) and polycyclic aromatic hydrocarbons (PAHs) in underground drinking water from a typical coking contaminated site in Shanxi of China were investigated. The average concentrations of BTX and PAHs in coking plant (CP) were 5.1 and 4.8 times higher than those in residential area (RA), respectively. Toluene and Benzene were the main BTX, while Acenaphthene, Fluorene, and Pyrene were the main PAHs. Concentrations of BTX/PAHs were negatively correlated with altitude, revealing altitude might be an important geological factor influencing spatial distribution of BTX/PAHs. PMF model demonstrated that the BTX/PAHs pollution in RA mainly originated from coking industrial activities. Health risk assessments were conducted by a modified US EPA-based model, in which environmental concentrations were replaced by residual concentrations after boiling. Residual ratios of different BTX/PAHs were determined by boiling experiments to be 9.4–93.8 %. The average total carcinogenic risks after boiling were decreased from 2.6 × 10−6 to 1.4 × 10−6 for adults, and from 4.3 × 10−6 to 2.1 × 10−6 for children, suggesting boiling was an effective strategy to reduce the carcinogenic risks from BTX/PAHs, especially for ingestion pathway. Monte Carlo simulation results matched well with the calculated results, suggesting the uncertainty was acceptable and the risk assessment results were reliable. This study provided useful information for revealing the spatial distribution of BTX/PAHs in underground drinking water of coking contaminated sites, understanding their linkage with altitude, and also helped to more accurately evaluate the health risks by using the newly established boiling-modified models. [Display omitted] •PhMe, BEN, ACE, FLU and PYR dominated in groundwater of coking contaminated sites.•Concentrations of BTX and PAHs were negatively correlated with altitude.•Source of BTX/PAHs in residential area originated from coking industrial activities.•Residual ratios after boiling were determined and used to modify risk assessment model.•Boiling was an effective strategy to reduce the carcinogenic risks from BTX/PAHs.