Production and Characterization of Activated Carbon from Pomegranate Peel for Pharmaceutical Waste (Paracetamol) Removal: Response Surface Methodology Application
In this study, the goal was to utilize activated carbon (designated as PPAC) derived from pomegranate peel (PP) for the removal of paracetamol (PCM). The distinctive structure of PPAC activated with KOH at 800 C was characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Fourier tran...
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| container_title | Water, air, and soil pollution |
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| creator | Solmaz, Alper Sari, Zeynel Abidin Karta, Mesut Turna, Talip Yücel, Ayşegül Depci, Tolga |
| description | In this study, the goal was to utilize activated carbon (designated as PPAC) derived from pomegranate peel (PP) for the removal of paracetamol (PCM). The distinctive structure of PPAC activated with KOH at 800 C was characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Fourier transform infrared spectroscopy (FTIR), and Scanning Electron Microscope (SEM), revealing a surface area of 692.07 m
2
/g and a pore diameter of 0.429 cm
3
/g. Response surface methodology (RSM) was used to determine the relationship between input parameters such as PCM concentration, PPAC amount, time, pH and temperature parameters and the resulting PCM concentration output. Eight kinetic models and seven isotherm models were examined and compared. As a result, a PCM removal capacity of 214 mg/g was attained, with the most fitting kinetic model being Pseudo Second-Order (
R
2
: 0.997) and the most suitable isotherm model being Redlich–Peterson (
R
2
: 0.999). According to the Response Surface Methodology (RSM) results, the most effective parameters are time, PPAC amount, initial PCM concentration and pH, respectively. This investigation provides substantial evidence for the viability of utilizing PPAC as an economical and efficient adsorbent in PCM removal processes.
Graphical Abstract |
| doi_str_mv | 10.1007/s11270-023-06641-w |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_miscellaneous_3153568898</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A767933186</galeid><sourcerecordid>A767933186</sourcerecordid><originalsourceid>FETCH-LOGICAL-c419t-5b209eb2ef6a667875b6f3c4618d7a8a5cf9c0c79692bde4e5679d5108b8abfa3</originalsourceid><addsrcrecordid>eNp9Uktv1DAQjhBILIU_wMkSl3JIsePED26rVXlIRax4iKM1ccbbVEm82Emr8nP4pcx2EQiEsA8ezffwaPQVxVPBzwTn-kUWotK85JUsuVK1KG_uFSvRaFlWVlb3ixXntS2V1fZh8SjnK07HGr0qvm9T7BY_93FiMHVscwkJ_Iyp_wZ3zRjYmuBrmJFQSC31Qooj28YRdwkmAtgWcWAhJrYl-Qgel7n3MLAvkAk93R48cYYxDs_ZBxzjNQwvqcj7OGVkH5cUCGfvcL6MXRzi7pat9_uBLA4jPC4eBBgyPvn5nhSfX51_2rwpL96_frtZX5S-FnYum7biFtsKgwKltNFNq4L0tRKm02Cg8cF67rVVtmo7rLFR2naN4KY10AaQJ8Xp0Xef4tcF8-zGPnscBpgwLtlJ0chGGWMNUZ_9Rb2KS5poOlcZLTlxaO-_WDsY0PVTiDPt4WDq1po-l1IYRayzf7Dodjj2Pk4Yeur_IaiOAp9izgmD26d-hHTrBHeHNLhjGhylwd2lwd2QSB5FmcjTDtPvif-j-gFvgLnr</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2873089829</pqid></control><display><type>article</type><title>Production and Characterization of Activated Carbon from Pomegranate Peel for Pharmaceutical Waste (Paracetamol) Removal: Response Surface Methodology Application</title><source>SpringerLink Journals</source><creator>Solmaz, Alper ; Sari, Zeynel Abidin ; Karta, Mesut ; Turna, Talip ; Yücel, Ayşegül ; Depci, Tolga</creator><creatorcontrib>Solmaz, Alper ; Sari, Zeynel Abidin ; Karta, Mesut ; Turna, Talip ; Yücel, Ayşegül ; Depci, Tolga</creatorcontrib><description>In this study, the goal was to utilize activated carbon (designated as PPAC) derived from pomegranate peel (PP) for the removal of paracetamol (PCM). The distinctive structure of PPAC activated with KOH at 800 C was characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Fourier transform infrared spectroscopy (FTIR), and Scanning Electron Microscope (SEM), revealing a surface area of 692.07 m
2
/g and a pore diameter of 0.429 cm
3
/g. Response surface methodology (RSM) was used to determine the relationship between input parameters such as PCM concentration, PPAC amount, time, pH and temperature parameters and the resulting PCM concentration output. Eight kinetic models and seven isotherm models were examined and compared. As a result, a PCM removal capacity of 214 mg/g was attained, with the most fitting kinetic model being Pseudo Second-Order (
R
2
: 0.997) and the most suitable isotherm model being Redlich–Peterson (
R
2
: 0.999). According to the Response Surface Methodology (RSM) results, the most effective parameters are time, PPAC amount, initial PCM concentration and pH, respectively. This investigation provides substantial evidence for the viability of utilizing PPAC as an economical and efficient adsorbent in PCM removal processes.
Graphical Abstract</description><identifier>ISSN: 0049-6979</identifier><identifier>EISSN: 1573-2932</identifier><identifier>DOI: 10.1007/s11270-023-06641-w</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Acetaminophen ; Activated carbon ; adsorbents ; air ; Analgesics ; Analytical methods ; Atmospheric Protection/Air Quality Control/Air Pollution ; Climate Change/Climate Change Impacts ; Diffraction ; Earth and Environmental Science ; Electron microscopes ; Environment ; Environmental monitoring ; Fourier transform infrared spectroscopy ; Fourier transforms ; Hydrogeology ; Infrared spectroscopy ; Isotherms ; kinetics ; Mathematical models ; Medical wastes ; Methods ; Paracetamol ; Parameters ; Pharmaceutical industry wastes ; pomegranates ; Removal ; Response surface methodology ; Scanning electron microscopy ; soil ; Soil Science & Conservation ; sorption isotherms ; surface area ; temperature ; viability ; wastes ; water ; Water Quality/Water Pollution ; X-ray diffraction ; X-rays</subject><ispartof>Water, air, and soil pollution, 2023-10, Vol.234 (10), p.645-645, Article 645</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>COPYRIGHT 2023 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c419t-5b209eb2ef6a667875b6f3c4618d7a8a5cf9c0c79692bde4e5679d5108b8abfa3</citedby><cites>FETCH-LOGICAL-c419t-5b209eb2ef6a667875b6f3c4618d7a8a5cf9c0c79692bde4e5679d5108b8abfa3</cites><orcidid>0000-0001-6928-3289</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11270-023-06641-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11270-023-06641-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Solmaz, Alper</creatorcontrib><creatorcontrib>Sari, Zeynel Abidin</creatorcontrib><creatorcontrib>Karta, Mesut</creatorcontrib><creatorcontrib>Turna, Talip</creatorcontrib><creatorcontrib>Yücel, Ayşegül</creatorcontrib><creatorcontrib>Depci, Tolga</creatorcontrib><title>Production and Characterization of Activated Carbon from Pomegranate Peel for Pharmaceutical Waste (Paracetamol) Removal: Response Surface Methodology Application</title><title>Water, air, and soil pollution</title><addtitle>Water Air Soil Pollut</addtitle><description>In this study, the goal was to utilize activated carbon (designated as PPAC) derived from pomegranate peel (PP) for the removal of paracetamol (PCM). The distinctive structure of PPAC activated with KOH at 800 C was characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Fourier transform infrared spectroscopy (FTIR), and Scanning Electron Microscope (SEM), revealing a surface area of 692.07 m
2
/g and a pore diameter of 0.429 cm
3
/g. Response surface methodology (RSM) was used to determine the relationship between input parameters such as PCM concentration, PPAC amount, time, pH and temperature parameters and the resulting PCM concentration output. Eight kinetic models and seven isotherm models were examined and compared. As a result, a PCM removal capacity of 214 mg/g was attained, with the most fitting kinetic model being Pseudo Second-Order (
R
2
: 0.997) and the most suitable isotherm model being Redlich–Peterson (
R
2
: 0.999). According to the Response Surface Methodology (RSM) results, the most effective parameters are time, PPAC amount, initial PCM concentration and pH, respectively. This investigation provides substantial evidence for the viability of utilizing PPAC as an economical and efficient adsorbent in PCM removal processes.
Graphical Abstract</description><subject>Acetaminophen</subject><subject>Activated carbon</subject><subject>adsorbents</subject><subject>air</subject><subject>Analgesics</subject><subject>Analytical methods</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Climate Change/Climate Change Impacts</subject><subject>Diffraction</subject><subject>Earth and Environmental Science</subject><subject>Electron microscopes</subject><subject>Environment</subject><subject>Environmental monitoring</subject><subject>Fourier transform infrared spectroscopy</subject><subject>Fourier transforms</subject><subject>Hydrogeology</subject><subject>Infrared spectroscopy</subject><subject>Isotherms</subject><subject>kinetics</subject><subject>Mathematical models</subject><subject>Medical wastes</subject><subject>Methods</subject><subject>Paracetamol</subject><subject>Parameters</subject><subject>Pharmaceutical industry wastes</subject><subject>pomegranates</subject><subject>Removal</subject><subject>Response surface methodology</subject><subject>Scanning electron microscopy</subject><subject>soil</subject><subject>Soil Science & Conservation</subject><subject>sorption isotherms</subject><subject>surface area</subject><subject>temperature</subject><subject>viability</subject><subject>wastes</subject><subject>water</subject><subject>Water Quality/Water Pollution</subject><subject>X-ray diffraction</subject><subject>X-rays</subject><issn>0049-6979</issn><issn>1573-2932</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9Uktv1DAQjhBILIU_wMkSl3JIsePED26rVXlIRax4iKM1ccbbVEm82Emr8nP4pcx2EQiEsA8ezffwaPQVxVPBzwTn-kUWotK85JUsuVK1KG_uFSvRaFlWVlb3ixXntS2V1fZh8SjnK07HGr0qvm9T7BY_93FiMHVscwkJ_Iyp_wZ3zRjYmuBrmJFQSC31Qooj28YRdwkmAtgWcWAhJrYl-Qgel7n3MLAvkAk93R48cYYxDs_ZBxzjNQwvqcj7OGVkH5cUCGfvcL6MXRzi7pat9_uBLA4jPC4eBBgyPvn5nhSfX51_2rwpL96_frtZX5S-FnYum7biFtsKgwKltNFNq4L0tRKm02Cg8cF67rVVtmo7rLFR2naN4KY10AaQJ8Xp0Xef4tcF8-zGPnscBpgwLtlJ0chGGWMNUZ_9Rb2KS5poOlcZLTlxaO-_WDsY0PVTiDPt4WDq1po-l1IYRayzf7Dodjj2Pk4Yeur_IaiOAp9izgmD26d-hHTrBHeHNLhjGhylwd2lwd2QSB5FmcjTDtPvif-j-gFvgLnr</recordid><startdate>20231001</startdate><enddate>20231001</enddate><creator>Solmaz, Alper</creator><creator>Sari, Zeynel Abidin</creator><creator>Karta, Mesut</creator><creator>Turna, 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and Characterization of Activated Carbon from Pomegranate Peel for Pharmaceutical Waste (Paracetamol) Removal: Response Surface Methodology Application</title><author>Solmaz, Alper ; Sari, Zeynel Abidin ; Karta, Mesut ; Turna, Talip ; Yücel, Ayşegül ; Depci, Tolga</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c419t-5b209eb2ef6a667875b6f3c4618d7a8a5cf9c0c79692bde4e5679d5108b8abfa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Acetaminophen</topic><topic>Activated carbon</topic><topic>adsorbents</topic><topic>air</topic><topic>Analgesics</topic><topic>Analytical methods</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Climate Change/Climate Change Impacts</topic><topic>Diffraction</topic><topic>Earth and Environmental Science</topic><topic>Electron microscopes</topic><topic>Environment</topic><topic>Environmental monitoring</topic><topic>Fourier transform infrared spectroscopy</topic><topic>Fourier transforms</topic><topic>Hydrogeology</topic><topic>Infrared spectroscopy</topic><topic>Isotherms</topic><topic>kinetics</topic><topic>Mathematical models</topic><topic>Medical wastes</topic><topic>Methods</topic><topic>Paracetamol</topic><topic>Parameters</topic><topic>Pharmaceutical industry wastes</topic><topic>pomegranates</topic><topic>Removal</topic><topic>Response surface methodology</topic><topic>Scanning electron microscopy</topic><topic>soil</topic><topic>Soil Science & Conservation</topic><topic>sorption isotherms</topic><topic>surface area</topic><topic>temperature</topic><topic>viability</topic><topic>wastes</topic><topic>water</topic><topic>Water Quality/Water Pollution</topic><topic>X-ray diffraction</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Solmaz, Alper</creatorcontrib><creatorcontrib>Sari, Zeynel 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this study, the goal was to utilize activated carbon (designated as PPAC) derived from pomegranate peel (PP) for the removal of paracetamol (PCM). The distinctive structure of PPAC activated with KOH at 800 C was characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Fourier transform infrared spectroscopy (FTIR), and Scanning Electron Microscope (SEM), revealing a surface area of 692.07 m
2
/g and a pore diameter of 0.429 cm
3
/g. Response surface methodology (RSM) was used to determine the relationship between input parameters such as PCM concentration, PPAC amount, time, pH and temperature parameters and the resulting PCM concentration output. Eight kinetic models and seven isotherm models were examined and compared. As a result, a PCM removal capacity of 214 mg/g was attained, with the most fitting kinetic model being Pseudo Second-Order (
R
2
: 0.997) and the most suitable isotherm model being Redlich–Peterson (
R
2
: 0.999). According to the Response Surface Methodology (RSM) results, the most effective parameters are time, PPAC amount, initial PCM concentration and pH, respectively. This investigation provides substantial evidence for the viability of utilizing PPAC as an economical and efficient adsorbent in PCM removal processes.
Graphical Abstract</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11270-023-06641-w</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0001-6928-3289</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0049-6979 |
| ispartof | Water, air, and soil pollution, 2023-10, Vol.234 (10), p.645-645, Article 645 |
| issn | 0049-6979 1573-2932 |
| language | eng |
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| source | SpringerLink Journals |
| subjects | Acetaminophen Activated carbon adsorbents air Analgesics Analytical methods Atmospheric Protection/Air Quality Control/Air Pollution Climate Change/Climate Change Impacts Diffraction Earth and Environmental Science Electron microscopes Environment Environmental monitoring Fourier transform infrared spectroscopy Fourier transforms Hydrogeology Infrared spectroscopy Isotherms kinetics Mathematical models Medical wastes Methods Paracetamol Parameters Pharmaceutical industry wastes pomegranates Removal Response surface methodology Scanning electron microscopy soil Soil Science & Conservation sorption isotherms surface area temperature viability wastes water Water Quality/Water Pollution X-ray diffraction X-rays |
| title | Production and Characterization of Activated Carbon from Pomegranate Peel for Pharmaceutical Waste (Paracetamol) Removal: Response Surface Methodology Application |
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