Conversion of polycarbosilane to silicon carbide: effect of an active filler and pyrolysis conditions
This paper reports the effect of titanium silicide active filler and the pyrolytic atmosphere (argon and nitrogen) on the ceramic conversion of polycarbosilane. Pyrolysis atmosphere and concentration of titanium silicide active filler was optimized to produce minimum shrinkage polycarbosilane derive...
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| Veröffentlicht in: | Journal of materials science 2023-11, Vol.58 (41), p.16046-16062 |
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| container_title | Journal of materials science |
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| creator | Vijay, V. Vipin Nair, Sandhya G. Devasia, Renjith |
| description | This paper reports the effect of titanium silicide active filler and the pyrolytic atmosphere (argon and nitrogen) on the ceramic conversion of polycarbosilane. Pyrolysis atmosphere and concentration of titanium silicide active filler was optimized to produce minimum shrinkage polycarbosilane derived ceramic. Detailed investigation on the phase evolution and surface morphology of the titanium silicide incorporated polycarbosilane derived ceramic under different pyrolysis atmospheres were carried out. From the results, it was concluded that 40 wt% titanium silicide loaded PCS system heat treated under nitrogen atmosphere was found to be the best precursor to obtain a minimum shrinkage ceramic phase with better properties. Therefore, this system offers the opportunity to expedite the rapid fabrication process of ceramic matrix composites, create flawless ceramic coatings, and produce bulk ceramic materials free from shrinkage. |
| doi_str_mv | 10.1007/s10853-023-09056-4 |
| format | Article |
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Therefore, this system offers the opportunity to expedite the rapid fabrication process of ceramic matrix composites, create flawless ceramic coatings, and produce bulk ceramic materials free from shrinkage.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-023-09056-4</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Argon ; Ceramic coatings ; Ceramic industry ; Ceramic materials ; Ceramic matrix composites ; Ceramics ; Characterization and Evaluation of Materials ; Chemical Routes to Materials ; Chemistry and Materials Science ; Classical Mechanics ; Crystallography and Scattering Methods ; Fillers ; heat ; Heat treatment ; Intermetallic compounds ; Materials Science ; Nitrogen ; Polymer Sciences ; Polymers ; Pyrolysis ; shrinkage ; Silicides ; Silicon ; Silicon carbide ; Solid Mechanics ; Titanium</subject><ispartof>Journal of materials science, 2023-11, Vol.58 (41), p.16046-16062</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. 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From the results, it was concluded that 40 wt% titanium silicide loaded PCS system heat treated under nitrogen atmosphere was found to be the best precursor to obtain a minimum shrinkage ceramic phase with better properties. 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Vipin</au><au>Nair, Sandhya G.</au><au>Devasia, Renjith</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Conversion of polycarbosilane to silicon carbide: effect of an active filler and pyrolysis conditions</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2023-11-01</date><risdate>2023</risdate><volume>58</volume><issue>41</issue><spage>16046</spage><epage>16062</epage><pages>16046-16062</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>This paper reports the effect of titanium silicide active filler and the pyrolytic atmosphere (argon and nitrogen) on the ceramic conversion of polycarbosilane. Pyrolysis atmosphere and concentration of titanium silicide active filler was optimized to produce minimum shrinkage polycarbosilane derived ceramic. 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| subjects | Argon Ceramic coatings Ceramic industry Ceramic materials Ceramic matrix composites Ceramics Characterization and Evaluation of Materials Chemical Routes to Materials Chemistry and Materials Science Classical Mechanics Crystallography and Scattering Methods Fillers heat Heat treatment Intermetallic compounds Materials Science Nitrogen Polymer Sciences Polymers Pyrolysis shrinkage Silicides Silicon Silicon carbide Solid Mechanics Titanium |
| title | Conversion of polycarbosilane to silicon carbide: effect of an active filler and pyrolysis conditions |
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