Trapping of a Terminal Intermediate in the Boron-Mediated Dinitrogen Reduction: Mono‑, Tri‑, and Tetrafunctionalized Hydrazines in Two Steps from N
The addition of chlorotrimethylsilane to a boron-mediated, transition-metal-free N₂ activation reaction leads to the isolation of multiple potassium boryl(silyl)hydrazido species, likely trapping products of a terminal dinitrogen complex of boron. One of these silylated N₂ species can be protonate...
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| Veröffentlicht in: | Journal of the American Chemical Society 2024-04, Vol.146 (16 p.11048-11053), p.11048-11053 |
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| container_end_page | 11053 |
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| container_issue | 16 p.11048-11053 |
| container_start_page | 11048 |
| container_title | Journal of the American Chemical Society |
| container_volume | 146 |
| creator | Rang, Maximilian Heinz, Myron Halkić, Anel Weber, Marco Dewhurst, Rian D. Rempel, Anna Härterich, Marcel Holthausen, Max C. Braunschweig, Holger |
| description | The addition of chlorotrimethylsilane to a boron-mediated, transition-metal-free N₂ activation reaction leads to the isolation of multiple potassium boryl(silyl)hydrazido species, likely trapping products of a terminal dinitrogen complex of boron. One of these silylated N₂ species can be protonated or methylated, providing access to mono- to tetrafunctionalized hydrazines in two steps from N₂ and in the absence of transition metals. |
| doi_str_mv | 10.1021/jacs.4c01818 |
| format | Article |
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| identifier | ISSN: 1520-5126 |
| ispartof | Journal of the American Chemical Society, 2024-04, Vol.146 (16 p.11048-11053), p.11048-11053 |
| issn | 1520-5126 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_3153549552 |
| source | ACS Publications |
| subjects | boron methylation nitrogen potassium |
| title | Trapping of a Terminal Intermediate in the Boron-Mediated Dinitrogen Reduction: Mono‑, Tri‑, and Tetrafunctionalized Hydrazines in Two Steps from N |
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