Adsorption and Co-adsorption of 2,4-Difluoroaniline and Copper (II) Using Nickel-Manganese Ferrite Magnetic Biochar Derived from Orange Peel
The adsorption process is regarded as a promising technology for removing organics and heavy metals. In this study, we used orange peels as biomass feedstock and used nickel-manganese ferrite (Ni 1-x Mn x Fe 2 O 4 ) as the precursor solution to prepare magnetic mesoporous biochar (MBC). Using a Box-...
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| Veröffentlicht in: | Water, air, and soil pollution air, and soil pollution, 2023-07, Vol.234 (7), p.427-427, Article 427 |
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| creator | Zhao, Zhi-Qing Shen, Xiao-Li Gao, Long-Ji Jin, Xin Li, Yan-Mei |
| description | The adsorption process is regarded as a promising technology for removing organics and heavy metals. In this study, we used orange peels as biomass feedstock and used nickel-manganese ferrite (Ni
1-x
Mn
x
Fe
2
O
4
) as the precursor solution to prepare magnetic mesoporous biochar (MBC). Using a Box-Behnken design response, we investigated the adsorption of 2,4-difluoroaniline (2,4-DFA), as well as the influence of four preparation parameters (activation temperature, the molar mass of Mn in Ni
1-x
Mn
x
Fe
2
O
4
, activation time, and impregnation ratio). Based on the adsorption rate of 2,4-DFA, we obtained the following optimal preparation parameters of MBC: a temperature of 180 °C, a molar mass of Ni
0.75
Mn
0.25
Fe
2
O
4
, an activation time of 8 h, and an impregnation ratio of 3. Then, we investigated the adsorption capacity of MBC and the mutual effect of 2,4-DFA and copper (II) [Cu(II)] through single and binary systems. The adsorption processes of 2,4-DFA and Cu(II) could be satisfactorily fitted to a pseudo-second-order kinetic model. The adsorption amount of 2,4-DFA was comparable in both single and binary systems. However, the adsorption of Cu(II) in the binary system was inhibited, with the adsorption capacity decreasing by 19.55%. The adsorption isotherms of 2,4-DFA and Cu(II) to MBC fitted the Freundlich model. The maximum adsorption capacity of 2,4-DFA and Cu(II) could reach 66.30 mg/g and 10.44 mg/g at 313 K, respectively. MBC exhibited good regeneration performance through the combination of 90% ethanol and 1 M NaOH solution. The adsorption mechanism mainly included electrostatic interactions, hydrogen bonds, ion exchange, and π-π interactions. |
| doi_str_mv | 10.1007/s11270-023-06445-y |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_miscellaneous_3153184920</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A754967565</galeid><sourcerecordid>A754967565</sourcerecordid><originalsourceid>FETCH-LOGICAL-c391t-53272b2740d5dcc14422a8e73d6bb62e9a345d567fb128230a53333fb99d1eee3</originalsourceid><addsrcrecordid>eNp9kc9u1DAQhy0EEkvhBThZ4lKkuvhvHB-XLaUrtZQDPVuOM1lcsnaws0j7Djw0hlSqxKHjg6XR941G80PoLaPnjFL9oTDGNSWUC0IbKRU5PkMrprQg3Aj-HK0olYY0RpuX6FUp97SWafUK_V73JeVpDiliF3u8ScQ9dtKA-ZkkF2EYDyknF8MYIjyA0wQZn2637_FdCXGHvwT_A0Zy4-LORSiALyHnMAO-cbsIc_D4Y0j-u8v4AnL4BT0ectrj21wFwF8BxtfoxeDGAm8e_hN0d_np2-aKXN9-3m7W18QLw2aiBNe841rSXvXeMyk5dy1o0Tdd13AwTkjVq0YPHeMtF9QpUWvojOkZAIgTdLrMnXL6eYAy230oHsax7p0OxQqmBGul4bSi7_5D79Mhx7qdraONMbI1rFLnC7VzI9gQhzRn5-vrYR98ijCE2l9rJU2jVaOqwBfB51RKhsFOOexdPlpG7d9E7ZKorYnaf4naY5XEIpUK15vlx12esP4AJ4KjCA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2829994891</pqid></control><display><type>article</type><title>Adsorption and Co-adsorption of 2,4-Difluoroaniline and Copper (II) Using Nickel-Manganese Ferrite Magnetic Biochar Derived from Orange Peel</title><source>SpringerLink Journals</source><creator>Zhao, Zhi-Qing ; Shen, Xiao-Li ; Gao, Long-Ji ; Jin, Xin ; Li, Yan-Mei</creator><creatorcontrib>Zhao, Zhi-Qing ; Shen, Xiao-Li ; Gao, Long-Ji ; Jin, Xin ; Li, Yan-Mei</creatorcontrib><description>The adsorption process is regarded as a promising technology for removing organics and heavy metals. In this study, we used orange peels as biomass feedstock and used nickel-manganese ferrite (Ni
1-x
Mn
x
Fe
2
O
4
) as the precursor solution to prepare magnetic mesoporous biochar (MBC). Using a Box-Behnken design response, we investigated the adsorption of 2,4-difluoroaniline (2,4-DFA), as well as the influence of four preparation parameters (activation temperature, the molar mass of Mn in Ni
1-x
Mn
x
Fe
2
O
4
, activation time, and impregnation ratio). Based on the adsorption rate of 2,4-DFA, we obtained the following optimal preparation parameters of MBC: a temperature of 180 °C, a molar mass of Ni
0.75
Mn
0.25
Fe
2
O
4
, an activation time of 8 h, and an impregnation ratio of 3. Then, we investigated the adsorption capacity of MBC and the mutual effect of 2,4-DFA and copper (II) [Cu(II)] through single and binary systems. The adsorption processes of 2,4-DFA and Cu(II) could be satisfactorily fitted to a pseudo-second-order kinetic model. The adsorption amount of 2,4-DFA was comparable in both single and binary systems. However, the adsorption of Cu(II) in the binary system was inhibited, with the adsorption capacity decreasing by 19.55%. The adsorption isotherms of 2,4-DFA and Cu(II) to MBC fitted the Freundlich model. The maximum adsorption capacity of 2,4-DFA and Cu(II) could reach 66.30 mg/g and 10.44 mg/g at 313 K, respectively. MBC exhibited good regeneration performance through the combination of 90% ethanol and 1 M NaOH solution. The adsorption mechanism mainly included electrostatic interactions, hydrogen bonds, ion exchange, and π-π interactions.</description><identifier>ISSN: 0049-6979</identifier><identifier>EISSN: 1573-2932</identifier><identifier>DOI: 10.1007/s11270-023-06445-y</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Adsorption ; air ; Atmospheric Protection/Air Quality Control/Air Pollution ; Binary systems ; biochar ; biomass ; Capacity ; Charcoal ; Chemical bonds ; Climate Change/Climate Change Impacts ; Copper ; Copper compounds ; Earth and Environmental Science ; Electrostatic properties ; Environment ; Environmental monitoring ; Ethanol ; experimental design ; feedstocks ; ferrimagnetic materials ; Ferrites ; Heavy metals ; hydrogen ; Hydrogen bonding ; Hydrogen bonds ; Hydrogeology ; Ion exchange ; Iron compounds ; kinetics ; magnetism ; Manganese ; Mathematical models ; Metals ; molecular weight ; Nickel ; orange peels ; Parameters ; porous media ; Sodium hydroxide ; soil ; Soil Science & Conservation ; sorption isotherms ; Technology application ; Temperature ; water ; Water Quality/Water Pollution</subject><ispartof>Water, air, and soil pollution, 2023-07, Vol.234 (7), p.427-427, Article 427</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>COPYRIGHT 2023 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c391t-53272b2740d5dcc14422a8e73d6bb62e9a345d567fb128230a53333fb99d1eee3</citedby><cites>FETCH-LOGICAL-c391t-53272b2740d5dcc14422a8e73d6bb62e9a345d567fb128230a53333fb99d1eee3</cites><orcidid>0000-0001-5441-0193</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11270-023-06445-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11270-023-06445-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Zhao, Zhi-Qing</creatorcontrib><creatorcontrib>Shen, Xiao-Li</creatorcontrib><creatorcontrib>Gao, Long-Ji</creatorcontrib><creatorcontrib>Jin, Xin</creatorcontrib><creatorcontrib>Li, Yan-Mei</creatorcontrib><title>Adsorption and Co-adsorption of 2,4-Difluoroaniline and Copper (II) Using Nickel-Manganese Ferrite Magnetic Biochar Derived from Orange Peel</title><title>Water, air, and soil pollution</title><addtitle>Water Air Soil Pollut</addtitle><description>The adsorption process is regarded as a promising technology for removing organics and heavy metals. In this study, we used orange peels as biomass feedstock and used nickel-manganese ferrite (Ni
1-x
Mn
x
Fe
2
O
4
) as the precursor solution to prepare magnetic mesoporous biochar (MBC). Using a Box-Behnken design response, we investigated the adsorption of 2,4-difluoroaniline (2,4-DFA), as well as the influence of four preparation parameters (activation temperature, the molar mass of Mn in Ni
1-x
Mn
x
Fe
2
O
4
, activation time, and impregnation ratio). Based on the adsorption rate of 2,4-DFA, we obtained the following optimal preparation parameters of MBC: a temperature of 180 °C, a molar mass of Ni
0.75
Mn
0.25
Fe
2
O
4
, an activation time of 8 h, and an impregnation ratio of 3. Then, we investigated the adsorption capacity of MBC and the mutual effect of 2,4-DFA and copper (II) [Cu(II)] through single and binary systems. The adsorption processes of 2,4-DFA and Cu(II) could be satisfactorily fitted to a pseudo-second-order kinetic model. The adsorption amount of 2,4-DFA was comparable in both single and binary systems. However, the adsorption of Cu(II) in the binary system was inhibited, with the adsorption capacity decreasing by 19.55%. The adsorption isotherms of 2,4-DFA and Cu(II) to MBC fitted the Freundlich model. The maximum adsorption capacity of 2,4-DFA and Cu(II) could reach 66.30 mg/g and 10.44 mg/g at 313 K, respectively. MBC exhibited good regeneration performance through the combination of 90% ethanol and 1 M NaOH solution. The adsorption mechanism mainly included electrostatic interactions, hydrogen bonds, ion exchange, and π-π interactions.</description><subject>Adsorption</subject><subject>air</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Binary systems</subject><subject>biochar</subject><subject>biomass</subject><subject>Capacity</subject><subject>Charcoal</subject><subject>Chemical bonds</subject><subject>Climate Change/Climate Change Impacts</subject><subject>Copper</subject><subject>Copper compounds</subject><subject>Earth and Environmental Science</subject><subject>Electrostatic properties</subject><subject>Environment</subject><subject>Environmental monitoring</subject><subject>Ethanol</subject><subject>experimental design</subject><subject>feedstocks</subject><subject>ferrimagnetic materials</subject><subject>Ferrites</subject><subject>Heavy metals</subject><subject>hydrogen</subject><subject>Hydrogen bonding</subject><subject>Hydrogen bonds</subject><subject>Hydrogeology</subject><subject>Ion exchange</subject><subject>Iron compounds</subject><subject>kinetics</subject><subject>magnetism</subject><subject>Manganese</subject><subject>Mathematical models</subject><subject>Metals</subject><subject>molecular weight</subject><subject>Nickel</subject><subject>orange peels</subject><subject>Parameters</subject><subject>porous media</subject><subject>Sodium hydroxide</subject><subject>soil</subject><subject>Soil Science & Conservation</subject><subject>sorption isotherms</subject><subject>Technology application</subject><subject>Temperature</subject><subject>water</subject><subject>Water Quality/Water 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and Co-adsorption of 2,4-Difluoroaniline and Copper (II) Using Nickel-Manganese Ferrite Magnetic Biochar Derived from Orange Peel</title><author>Zhao, Zhi-Qing ; Shen, Xiao-Li ; Gao, Long-Ji ; Jin, Xin ; Li, Yan-Mei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c391t-53272b2740d5dcc14422a8e73d6bb62e9a345d567fb128230a53333fb99d1eee3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Adsorption</topic><topic>air</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Binary systems</topic><topic>biochar</topic><topic>biomass</topic><topic>Capacity</topic><topic>Charcoal</topic><topic>Chemical bonds</topic><topic>Climate Change/Climate Change Impacts</topic><topic>Copper</topic><topic>Copper compounds</topic><topic>Earth and Environmental Science</topic><topic>Electrostatic properties</topic><topic>Environment</topic><topic>Environmental monitoring</topic><topic>Ethanol</topic><topic>experimental design</topic><topic>feedstocks</topic><topic>ferrimagnetic materials</topic><topic>Ferrites</topic><topic>Heavy metals</topic><topic>hydrogen</topic><topic>Hydrogen bonding</topic><topic>Hydrogen bonds</topic><topic>Hydrogeology</topic><topic>Ion exchange</topic><topic>Iron compounds</topic><topic>kinetics</topic><topic>magnetism</topic><topic>Manganese</topic><topic>Mathematical models</topic><topic>Metals</topic><topic>molecular weight</topic><topic>Nickel</topic><topic>orange peels</topic><topic>Parameters</topic><topic>porous media</topic><topic>Sodium hydroxide</topic><topic>soil</topic><topic>Soil Science & Conservation</topic><topic>sorption isotherms</topic><topic>Technology application</topic><topic>Temperature</topic><topic>water</topic><topic>Water Quality/Water Pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Zhi-Qing</creatorcontrib><creatorcontrib>Shen, Xiao-Li</creatorcontrib><creatorcontrib>Gao, Long-Ji</creatorcontrib><creatorcontrib>Jin, Xin</creatorcontrib><creatorcontrib>Li, Yan-Mei</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Aqualine</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Water Resources Abstracts</collection><collection>ABI/INFORM Collection</collection><collection>ABI/INFORM Global (PDF only)</collection><collection>Agricultural Science Collection</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Global (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni 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Collection</collection><collection>ProQuest Central Basic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Water, air, and soil pollution</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Zhi-Qing</au><au>Shen, Xiao-Li</au><au>Gao, Long-Ji</au><au>Jin, Xin</au><au>Li, Yan-Mei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption and Co-adsorption of 2,4-Difluoroaniline and Copper (II) Using Nickel-Manganese Ferrite Magnetic Biochar Derived from Orange Peel</atitle><jtitle>Water, air, and soil pollution</jtitle><stitle>Water Air Soil Pollut</stitle><date>2023-07-01</date><risdate>2023</risdate><volume>234</volume><issue>7</issue><spage>427</spage><epage>427</epage><pages>427-427</pages><artnum>427</artnum><issn>0049-6979</issn><eissn>1573-2932</eissn><abstract>The adsorption process is regarded as a promising technology for removing organics and heavy metals. In this study, we used orange peels as biomass feedstock and used nickel-manganese ferrite (Ni
1-x
Mn
x
Fe
2
O
4
) as the precursor solution to prepare magnetic mesoporous biochar (MBC). Using a Box-Behnken design response, we investigated the adsorption of 2,4-difluoroaniline (2,4-DFA), as well as the influence of four preparation parameters (activation temperature, the molar mass of Mn in Ni
1-x
Mn
x
Fe
2
O
4
, activation time, and impregnation ratio). Based on the adsorption rate of 2,4-DFA, we obtained the following optimal preparation parameters of MBC: a temperature of 180 °C, a molar mass of Ni
0.75
Mn
0.25
Fe
2
O
4
, an activation time of 8 h, and an impregnation ratio of 3. Then, we investigated the adsorption capacity of MBC and the mutual effect of 2,4-DFA and copper (II) [Cu(II)] through single and binary systems. The adsorption processes of 2,4-DFA and Cu(II) could be satisfactorily fitted to a pseudo-second-order kinetic model. The adsorption amount of 2,4-DFA was comparable in both single and binary systems. However, the adsorption of Cu(II) in the binary system was inhibited, with the adsorption capacity decreasing by 19.55%. The adsorption isotherms of 2,4-DFA and Cu(II) to MBC fitted the Freundlich model. The maximum adsorption capacity of 2,4-DFA and Cu(II) could reach 66.30 mg/g and 10.44 mg/g at 313 K, respectively. MBC exhibited good regeneration performance through the combination of 90% ethanol and 1 M NaOH solution. The adsorption mechanism mainly included electrostatic interactions, hydrogen bonds, ion exchange, and π-π interactions.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11270-023-06445-y</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0001-5441-0193</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | Water, air, and soil pollution, 2023-07, Vol.234 (7), p.427-427, Article 427 |
| issn | 0049-6979 1573-2932 |
| language | eng |
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| source | SpringerLink Journals |
| subjects | Adsorption air Atmospheric Protection/Air Quality Control/Air Pollution Binary systems biochar biomass Capacity Charcoal Chemical bonds Climate Change/Climate Change Impacts Copper Copper compounds Earth and Environmental Science Electrostatic properties Environment Environmental monitoring Ethanol experimental design feedstocks ferrimagnetic materials Ferrites Heavy metals hydrogen Hydrogen bonding Hydrogen bonds Hydrogeology Ion exchange Iron compounds kinetics magnetism Manganese Mathematical models Metals molecular weight Nickel orange peels Parameters porous media Sodium hydroxide soil Soil Science & Conservation sorption isotherms Technology application Temperature water Water Quality/Water Pollution |
| title | Adsorption and Co-adsorption of 2,4-Difluoroaniline and Copper (II) Using Nickel-Manganese Ferrite Magnetic Biochar Derived from Orange Peel |
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