A holistic approach to the recovery of valuable substances from the treatment sludge formed from chemical precipitation of fruit processing industry wastewater
In this study, recovery of phenolic substances with Soxhlet extraction, (SE) ultrasound-assisted extraction (UAS), and supercritical CO2 (SC-CO2) extraction methods from chemical sludge obtained with chemical precipitation (FeCl3/PACS, Ca(OH)2/PACS, perlite/PACS, FeCl3/cationic polyelectrolyte) of l...
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description | In this study, recovery of phenolic substances with Soxhlet extraction, (SE) ultrasound-assisted extraction (UAS), and supercritical CO2 (SC-CO2) extraction methods from chemical sludge obtained with chemical precipitation (FeCl3/PACS, Ca(OH)2/PACS, perlite/PACS, FeCl3/cationic polyelectrolyte) of lemon processing wastewater was investigated. The effect of used coagulants/flocculants and pH on COD and total phenolic substance content (TPC) removal was researched. Recovered phenolic substance profiles were also determined with HPLC-DAD. Additionally, response surface methodology was used to determine optimum treatment conditions. ANOVA analysis showed that pH is a more important variable than coagulant/flocculant doses for all chemical precipitation experimental sets. The highest removal efficiencies for COD and TPC was obtained in FeCl3/PACS (COD: 72.0 %, TPC: 93.7 %). Optimum dose values were determined as pH: 4, FeCl3: 3000 mg/L, PACS: 400 mg/L for FeCl3/PACS, pH: 6.5, Ca(OH)2: 1500 mg/L, PACS: 300 mg/L for Ca(OH)2/PACS, pH: 5.5, PACS: 7000 mg/L, perlite: 50 g/L for perlite/PACS, pH: 4.5, FeCl3: 500 mg/L, polyelectrolyte: 4 mg/L for FeCl3/polyelectrolyte. TPC removal efficiencies were determined as 55 %, 35 %, 57 % and 58 % in these conditions, respectively. Maximum TPC in extracts was determined as 39.03 mg GAE/g extract, 8.81 mg GAE/g extract, and 4.34 mg GAE/g extract for SE, UAS, and SC-CO2, respectively. TPC recovery efficiencies (RTPC) for all chemical sludge were SE > UAS > SC-CO2. Additionally, the TPC profile has shown a difference depending on the extraction method.
According to the results of this study, it was concluded that the coagulation-flocculation process may be a suitable alternative for fruit juice processing industry wastewater in terms of both reducing environmental pollution and recovering polyphenolics from formed sludge. Consequently, this study presented a different perspective on the recovery from wastes with valuable substance recovery from chemical sludge.
[Display omitted]
•The highest removal efficiencies for COD and TPC were obtained in FeCl3/PACS.•pH was an important variable in four different coagulant/flocculant combinations.•Chemical sludge type is crucial in recovery of functional substances.•The highest recovery efficiency was obtained from Ca(OH)2/PACS sludge.•Since perlite cannot desorbed functional substances, recovery was difficult.•Using co-solvent in SC-CO2 method increased recovery efficiencies of TPC. |
doi_str_mv | 10.1016/j.scitotenv.2024.170372 |
format | Article |
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According to the results of this study, it was concluded that the coagulation-flocculation process may be a suitable alternative for fruit juice processing industry wastewater in terms of both reducing environmental pollution and recovering polyphenolics from formed sludge. Consequently, this study presented a different perspective on the recovery from wastes with valuable substance recovery from chemical sludge.
[Display omitted]
•The highest removal efficiencies for COD and TPC were obtained in FeCl3/PACS.•pH was an important variable in four different coagulant/flocculant combinations.•Chemical sludge type is crucial in recovery of functional substances.•The highest recovery efficiency was obtained from Ca(OH)2/PACS sludge.•Since perlite cannot desorbed functional substances, recovery was difficult.•Using co-solvent in SC-CO2 method increased recovery efficiencies of TPC.</description><identifier>ISSN: 0048-9697</identifier><identifier>EISSN: 1879-1026</identifier><identifier>DOI: 10.1016/j.scitotenv.2024.170372</identifier><identifier>PMID: 38280603</identifier><language>eng</language><publisher>Netherlands: Elsevier B.V</publisher><subject>Aluminum Oxide ; Bioactive compounds ; Carbon Dioxide ; Chemical Precipitation ; Chemical precipitation conditions ; Chlorides ; coagulants ; electrolytes ; environment ; Ferric Compounds ; flocculants ; Flocculation ; Fruit ; Fruit juice industry wastewater ; fruit juices ; fruits ; industrial wastewater ; lemons ; perlite ; Plant Extracts ; pollution ; Polyelectrolytes ; polyphenols ; Recovery ; response surface methodology ; Sewage - chemistry ; Silicon Dioxide ; sludge ; solid phase extraction ; Soxhlet extraction ; Supercritical CO2 extraction ; ultrasonic treatment ; Ultrasound assisted extraction ; Valorization ; Waste Disposal, Fluid - methods ; Wastewater</subject><ispartof>The Science of the total environment, 2024-03, Vol.917, p.170372-170372, Article 170372</ispartof><rights>2024 Elsevier B.V.</rights><rights>Copyright © 2024 Elsevier B.V. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c404t-6e3c2eebb69443065563cd95a4c36d23aee37bf27fa3334e3f95e11654edd9843</citedby><cites>FETCH-LOGICAL-c404t-6e3c2eebb69443065563cd95a4c36d23aee37bf27fa3334e3f95e11654edd9843</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0048969724005072$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38280603$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Güven, Hatice Merve</creatorcontrib><creatorcontrib>Ateş, Havva</creatorcontrib><title>A holistic approach to the recovery of valuable substances from the treatment sludge formed from chemical precipitation of fruit processing industry wastewater</title><title>The Science of the total environment</title><addtitle>Sci Total Environ</addtitle><description>In this study, recovery of phenolic substances with Soxhlet extraction, (SE) ultrasound-assisted extraction (UAS), and supercritical CO2 (SC-CO2) extraction methods from chemical sludge obtained with chemical precipitation (FeCl3/PACS, Ca(OH)2/PACS, perlite/PACS, FeCl3/cationic polyelectrolyte) of lemon processing wastewater was investigated. The effect of used coagulants/flocculants and pH on COD and total phenolic substance content (TPC) removal was researched. Recovered phenolic substance profiles were also determined with HPLC-DAD. Additionally, response surface methodology was used to determine optimum treatment conditions. ANOVA analysis showed that pH is a more important variable than coagulant/flocculant doses for all chemical precipitation experimental sets. The highest removal efficiencies for COD and TPC was obtained in FeCl3/PACS (COD: 72.0 %, TPC: 93.7 %). Optimum dose values were determined as pH: 4, FeCl3: 3000 mg/L, PACS: 400 mg/L for FeCl3/PACS, pH: 6.5, Ca(OH)2: 1500 mg/L, PACS: 300 mg/L for Ca(OH)2/PACS, pH: 5.5, PACS: 7000 mg/L, perlite: 50 g/L for perlite/PACS, pH: 4.5, FeCl3: 500 mg/L, polyelectrolyte: 4 mg/L for FeCl3/polyelectrolyte. TPC removal efficiencies were determined as 55 %, 35 %, 57 % and 58 % in these conditions, respectively. Maximum TPC in extracts was determined as 39.03 mg GAE/g extract, 8.81 mg GAE/g extract, and 4.34 mg GAE/g extract for SE, UAS, and SC-CO2, respectively. TPC recovery efficiencies (RTPC) for all chemical sludge were SE > UAS > SC-CO2. Additionally, the TPC profile has shown a difference depending on the extraction method.
According to the results of this study, it was concluded that the coagulation-flocculation process may be a suitable alternative for fruit juice processing industry wastewater in terms of both reducing environmental pollution and recovering polyphenolics from formed sludge. Consequently, this study presented a different perspective on the recovery from wastes with valuable substance recovery from chemical sludge.
[Display omitted]
•The highest removal efficiencies for COD and TPC were obtained in FeCl3/PACS.•pH was an important variable in four different coagulant/flocculant combinations.•Chemical sludge type is crucial in recovery of functional substances.•The highest recovery efficiency was obtained from Ca(OH)2/PACS sludge.•Since perlite cannot desorbed functional substances, recovery was difficult.•Using co-solvent in SC-CO2 method increased recovery efficiencies of TPC.</description><subject>Aluminum Oxide</subject><subject>Bioactive compounds</subject><subject>Carbon Dioxide</subject><subject>Chemical Precipitation</subject><subject>Chemical precipitation conditions</subject><subject>Chlorides</subject><subject>coagulants</subject><subject>electrolytes</subject><subject>environment</subject><subject>Ferric Compounds</subject><subject>flocculants</subject><subject>Flocculation</subject><subject>Fruit</subject><subject>Fruit juice industry wastewater</subject><subject>fruit juices</subject><subject>fruits</subject><subject>industrial wastewater</subject><subject>lemons</subject><subject>perlite</subject><subject>Plant Extracts</subject><subject>pollution</subject><subject>Polyelectrolytes</subject><subject>polyphenols</subject><subject>Recovery</subject><subject>response surface methodology</subject><subject>Sewage - chemistry</subject><subject>Silicon Dioxide</subject><subject>sludge</subject><subject>solid phase extraction</subject><subject>Soxhlet extraction</subject><subject>Supercritical CO2 extraction</subject><subject>ultrasonic treatment</subject><subject>Ultrasound assisted extraction</subject><subject>Valorization</subject><subject>Waste Disposal, Fluid - methods</subject><subject>Wastewater</subject><issn>0048-9697</issn><issn>1879-1026</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkctu3CAUhlHVqpmmfYWWZTeecjM2y1HUmxSpm3aNMBwyjGzjAp4oT9NXLVOn2YYNEvrOf9D_IfSBkj0lVH467bMNJRaYz3tGmNjTjvCOvUA72neqoYTJl2hHiOgbJVV3hd7kfCL1dD19ja54z3oiCd-hPwd8jGPIJVhsliVFY4-4RFyOgBPYeIb0gKPHZzOuZhgB53XIxcwWMvYpTv_AksCUCeaC87i6O8A-pgncBtgjTMGaES81LyyhmBLifMn0aQ2lPscalsN8h8Ps1lzqwnuTC9ybAukteuXNmOHd432Nfn35_PPmW3P74-v3m8NtYwURpZHALQMYBqmE4ES2reTWqdYIy6Vj3ADwbvCs84ZzLoB71QKlshXgnOoFv0Yft9z6nd8r5KKnkC2Mo5khrllz2nLaE6XIsyhTjCtKBVUV7TbUpphzAq-XFCaTHjQl-iJSn_STSH0RqTeRdfL945J1qFU-zf03V4HDBkBt5RwgXYKgenGh9ly0i-HZJX8Bga234g</recordid><startdate>20240320</startdate><enddate>20240320</enddate><creator>Güven, Hatice Merve</creator><creator>Ateş, Havva</creator><general>Elsevier B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20240320</creationdate><title>A holistic approach to the recovery of valuable substances from the treatment sludge formed from chemical precipitation of fruit processing industry wastewater</title><author>Güven, Hatice Merve ; Ateş, Havva</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c404t-6e3c2eebb69443065563cd95a4c36d23aee37bf27fa3334e3f95e11654edd9843</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Aluminum Oxide</topic><topic>Bioactive compounds</topic><topic>Carbon Dioxide</topic><topic>Chemical Precipitation</topic><topic>Chemical precipitation conditions</topic><topic>Chlorides</topic><topic>coagulants</topic><topic>electrolytes</topic><topic>environment</topic><topic>Ferric Compounds</topic><topic>flocculants</topic><topic>Flocculation</topic><topic>Fruit</topic><topic>Fruit juice industry wastewater</topic><topic>fruit juices</topic><topic>fruits</topic><topic>industrial wastewater</topic><topic>lemons</topic><topic>perlite</topic><topic>Plant Extracts</topic><topic>pollution</topic><topic>Polyelectrolytes</topic><topic>polyphenols</topic><topic>Recovery</topic><topic>response surface methodology</topic><topic>Sewage - chemistry</topic><topic>Silicon Dioxide</topic><topic>sludge</topic><topic>solid phase extraction</topic><topic>Soxhlet extraction</topic><topic>Supercritical CO2 extraction</topic><topic>ultrasonic treatment</topic><topic>Ultrasound assisted extraction</topic><topic>Valorization</topic><topic>Waste Disposal, Fluid - methods</topic><topic>Wastewater</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Güven, Hatice Merve</creatorcontrib><creatorcontrib>Ateş, Havva</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>The Science of the total environment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Güven, Hatice Merve</au><au>Ateş, Havva</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A holistic approach to the recovery of valuable substances from the treatment sludge formed from chemical precipitation of fruit processing industry wastewater</atitle><jtitle>The Science of the total environment</jtitle><addtitle>Sci Total Environ</addtitle><date>2024-03-20</date><risdate>2024</risdate><volume>917</volume><spage>170372</spage><epage>170372</epage><pages>170372-170372</pages><artnum>170372</artnum><issn>0048-9697</issn><eissn>1879-1026</eissn><abstract>In this study, recovery of phenolic substances with Soxhlet extraction, (SE) ultrasound-assisted extraction (UAS), and supercritical CO2 (SC-CO2) extraction methods from chemical sludge obtained with chemical precipitation (FeCl3/PACS, Ca(OH)2/PACS, perlite/PACS, FeCl3/cationic polyelectrolyte) of lemon processing wastewater was investigated. The effect of used coagulants/flocculants and pH on COD and total phenolic substance content (TPC) removal was researched. Recovered phenolic substance profiles were also determined with HPLC-DAD. Additionally, response surface methodology was used to determine optimum treatment conditions. ANOVA analysis showed that pH is a more important variable than coagulant/flocculant doses for all chemical precipitation experimental sets. The highest removal efficiencies for COD and TPC was obtained in FeCl3/PACS (COD: 72.0 %, TPC: 93.7 %). Optimum dose values were determined as pH: 4, FeCl3: 3000 mg/L, PACS: 400 mg/L for FeCl3/PACS, pH: 6.5, Ca(OH)2: 1500 mg/L, PACS: 300 mg/L for Ca(OH)2/PACS, pH: 5.5, PACS: 7000 mg/L, perlite: 50 g/L for perlite/PACS, pH: 4.5, FeCl3: 500 mg/L, polyelectrolyte: 4 mg/L for FeCl3/polyelectrolyte. TPC removal efficiencies were determined as 55 %, 35 %, 57 % and 58 % in these conditions, respectively. Maximum TPC in extracts was determined as 39.03 mg GAE/g extract, 8.81 mg GAE/g extract, and 4.34 mg GAE/g extract for SE, UAS, and SC-CO2, respectively. TPC recovery efficiencies (RTPC) for all chemical sludge were SE > UAS > SC-CO2. Additionally, the TPC profile has shown a difference depending on the extraction method.
According to the results of this study, it was concluded that the coagulation-flocculation process may be a suitable alternative for fruit juice processing industry wastewater in terms of both reducing environmental pollution and recovering polyphenolics from formed sludge. Consequently, this study presented a different perspective on the recovery from wastes with valuable substance recovery from chemical sludge.
[Display omitted]
•The highest removal efficiencies for COD and TPC were obtained in FeCl3/PACS.•pH was an important variable in four different coagulant/flocculant combinations.•Chemical sludge type is crucial in recovery of functional substances.•The highest recovery efficiency was obtained from Ca(OH)2/PACS sludge.•Since perlite cannot desorbed functional substances, recovery was difficult.•Using co-solvent in SC-CO2 method increased recovery efficiencies of TPC.</abstract><cop>Netherlands</cop><pub>Elsevier B.V</pub><pmid>38280603</pmid><doi>10.1016/j.scitotenv.2024.170372</doi><tpages>1</tpages></addata></record> |
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subjects | Aluminum Oxide Bioactive compounds Carbon Dioxide Chemical Precipitation Chemical precipitation conditions Chlorides coagulants electrolytes environment Ferric Compounds flocculants Flocculation Fruit Fruit juice industry wastewater fruit juices fruits industrial wastewater lemons perlite Plant Extracts pollution Polyelectrolytes polyphenols Recovery response surface methodology Sewage - chemistry Silicon Dioxide sludge solid phase extraction Soxhlet extraction Supercritical CO2 extraction ultrasonic treatment Ultrasound assisted extraction Valorization Waste Disposal, Fluid - methods Wastewater |
title | A holistic approach to the recovery of valuable substances from the treatment sludge formed from chemical precipitation of fruit processing industry wastewater |
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