Alkaline Earth Metal Superatom of W@Si16: Characterization of Group 6 Metal Encapsulating Si16 Cage on Organic Substrates

Transition metal atom (M)-encapsulating silicon cage nanoclusters (M@Si16) exhibit a superatomic nature, depending on the central M atom owing to the number of valence electrons and charge state on organic substrates. Since M@Si16 superatom featuring group 4 and 5 transition metal atoms exhibit rare...

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Veröffentlicht in:	Journal of the American Chemical Society 2024-04, Vol.146 (14), p.9605-9613
Hauptverfasser:	Terasaka, Kazuya, Kamoshida, Toshiaki, Ichikawa, Takumi, Yokoyama, Takaho, Shibuta, Masahiro, Hatanaka, Miho, Nakajima, Atsushi
Format:	Artikel
Sprache:	eng
Schlagworte:	alkaline earth metals chemical reactions chemical structure nanoparticles oxygen silicon
Online-Zugang:	Volltext
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